Reaction of Np, Am, and Cm ions with CO2 and O2 in a reaction cell in triple quadrupole inductively coupled plasma mass spectrometry
Ultratrace analysis is crucial for understanding fuel debris in a nuclear reactor core after severe accidents. Triple quadrupole inductively coupled plasma mass spectrometry measured the ion–molecule reactions of actinides (237Np, 241Am, and 244Cm) in a reaction cell. These nuclides were included in...
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| Veröffentlicht in: | Journal of analytical atomic spectrometry 2023-08, Vol.38 (8), p.1676-1681 |
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| container_title | Journal of analytical atomic spectrometry |
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| creator | Kazama, Hiroyuki Konashi, Kenji Suzuki, Tatsuya Koyama, Shin-ichi Maeda, Koji Sekio, Yoshihiro Onishi, Takashi Abe, Chikage Shikamori, Yasuyuki Nagai, Yasuyoshi |
| description | Ultratrace analysis is crucial for understanding fuel debris in a nuclear reactor core after severe accidents. Triple quadrupole inductively coupled plasma mass spectrometry measured the ion–molecule reactions of actinides (237Np, 241Am, and 244Cm) in a reaction cell. These nuclides were included in the fuel debris. A gas-phase ion–molecule reaction model has been developed to simulate the gas-phase reactions in the reaction cell. The model simulation results correlate well with the flow rate dependence of experimental data accurately. Reaction constants derived from the model were compared with those reported values by Fourier transform ion-cyclotron resonance mass spectrometry to evaluate the performance of the model. The similarity between the two reaction constants was found. |
| doi_str_mv | 10.1039/d3ja00136a |
| format | Article |
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Triple quadrupole inductively coupled plasma mass spectrometry measured the ion–molecule reactions of actinides (237Np, 241Am, and 244Cm) in a reaction cell. These nuclides were included in the fuel debris. A gas-phase ion–molecule reaction model has been developed to simulate the gas-phase reactions in the reaction cell. The model simulation results correlate well with the flow rate dependence of experimental data accurately. Reaction constants derived from the model were compared with those reported values by Fourier transform ion-cyclotron resonance mass spectrometry to evaluate the performance of the model. The similarity between the two reaction constants was found.</description><identifier>ISSN: 0267-9477</identifier><identifier>EISSN: 1364-5544</identifier><identifier>DOI: 10.1039/d3ja00136a</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Actinides ; Coupling (molecular) ; Cyclotron resonance ; Debris ; Fourier transforms ; Fuels ; Inductively coupled plasma mass spectrometry ; Mass spectrometry ; Nuclear reactors ; Nuclides ; Quadrupoles ; Reactor cores</subject><ispartof>Journal of analytical atomic spectrometry, 2023-08, Vol.38 (8), p.1676-1681</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Kazama, Hiroyuki</creatorcontrib><creatorcontrib>Konashi, Kenji</creatorcontrib><creatorcontrib>Suzuki, Tatsuya</creatorcontrib><creatorcontrib>Koyama, Shin-ichi</creatorcontrib><creatorcontrib>Maeda, Koji</creatorcontrib><creatorcontrib>Sekio, Yoshihiro</creatorcontrib><creatorcontrib>Onishi, Takashi</creatorcontrib><creatorcontrib>Abe, Chikage</creatorcontrib><creatorcontrib>Shikamori, Yasuyuki</creatorcontrib><creatorcontrib>Nagai, Yasuyoshi</creatorcontrib><title>Reaction of Np, Am, and Cm ions with CO2 and O2 in a reaction cell in triple quadrupole inductively coupled plasma mass spectrometry</title><title>Journal of analytical atomic spectrometry</title><description>Ultratrace analysis is crucial for understanding fuel debris in a nuclear reactor core after severe accidents. Triple quadrupole inductively coupled plasma mass spectrometry measured the ion–molecule reactions of actinides (237Np, 241Am, and 244Cm) in a reaction cell. These nuclides were included in the fuel debris. A gas-phase ion–molecule reaction model has been developed to simulate the gas-phase reactions in the reaction cell. The model simulation results correlate well with the flow rate dependence of experimental data accurately. Reaction constants derived from the model were compared with those reported values by Fourier transform ion-cyclotron resonance mass spectrometry to evaluate the performance of the model. The similarity between the two reaction constants was found.</description><subject>Actinides</subject><subject>Coupling (molecular)</subject><subject>Cyclotron resonance</subject><subject>Debris</subject><subject>Fourier transforms</subject><subject>Fuels</subject><subject>Inductively coupled plasma mass spectrometry</subject><subject>Mass spectrometry</subject><subject>Nuclear reactors</subject><subject>Nuclides</subject><subject>Quadrupoles</subject><subject>Reactor cores</subject><issn>0267-9477</issn><issn>1364-5544</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo1jctKxDAUhoMoOI5ufIIDbqeae9LlULzB4IDoekjTFFt6myRVZu-DG2-r7-c75z8HoUuCrwlm-U3FWoMxYdIcoUUCz4Tg_BgtMJUqy7lSp-gshBZjzAUVC_T57IyNzTjAWMPTtIJ1vwIzVFD0kGyAjya-QbGlPzKhGcCA_y9Z13XfKvpm6hzsZ1P5eRpTbIZqTjvvrjuAHec0rWDqTOgN9CYECJOz0Y-9i_5wjk5q0wV38ccler27fSkess32_rFYb7KJaBYzq6XBxGrq6pwxJ6WtMSspI8q5HAvLXWlNmRvJS6lIXmtW1pXSRGBXU4EZW6Kr37uTH_ezC3HXjrMf0ssd1ZwLRbXm7AsNFWJC</recordid><startdate>20230802</startdate><enddate>20230802</enddate><creator>Kazama, Hiroyuki</creator><creator>Konashi, Kenji</creator><creator>Suzuki, Tatsuya</creator><creator>Koyama, Shin-ichi</creator><creator>Maeda, Koji</creator><creator>Sekio, Yoshihiro</creator><creator>Onishi, Takashi</creator><creator>Abe, Chikage</creator><creator>Shikamori, Yasuyuki</creator><creator>Nagai, Yasuyoshi</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20230802</creationdate><title>Reaction of Np, Am, and Cm ions with CO2 and O2 in a reaction cell in triple quadrupole inductively coupled plasma mass spectrometry</title><author>Kazama, Hiroyuki ; Konashi, Kenji ; Suzuki, Tatsuya ; Koyama, Shin-ichi ; Maeda, Koji ; Sekio, Yoshihiro ; Onishi, Takashi ; Abe, Chikage ; Shikamori, Yasuyuki ; Nagai, Yasuyoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p183t-c86a01c82ef933e66cf03b2317ee905c4ebcab9a64b6719f83bfd78150ef25033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Actinides</topic><topic>Coupling (molecular)</topic><topic>Cyclotron resonance</topic><topic>Debris</topic><topic>Fourier transforms</topic><topic>Fuels</topic><topic>Inductively coupled plasma mass spectrometry</topic><topic>Mass spectrometry</topic><topic>Nuclear reactors</topic><topic>Nuclides</topic><topic>Quadrupoles</topic><topic>Reactor cores</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kazama, Hiroyuki</creatorcontrib><creatorcontrib>Konashi, Kenji</creatorcontrib><creatorcontrib>Suzuki, Tatsuya</creatorcontrib><creatorcontrib>Koyama, Shin-ichi</creatorcontrib><creatorcontrib>Maeda, Koji</creatorcontrib><creatorcontrib>Sekio, Yoshihiro</creatorcontrib><creatorcontrib>Onishi, Takashi</creatorcontrib><creatorcontrib>Abe, Chikage</creatorcontrib><creatorcontrib>Shikamori, Yasuyuki</creatorcontrib><creatorcontrib>Nagai, Yasuyoshi</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of analytical atomic spectrometry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kazama, Hiroyuki</au><au>Konashi, Kenji</au><au>Suzuki, Tatsuya</au><au>Koyama, Shin-ichi</au><au>Maeda, Koji</au><au>Sekio, Yoshihiro</au><au>Onishi, Takashi</au><au>Abe, Chikage</au><au>Shikamori, Yasuyuki</au><au>Nagai, Yasuyoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reaction of Np, Am, and Cm ions with CO2 and O2 in a reaction cell in triple quadrupole inductively coupled plasma mass spectrometry</atitle><jtitle>Journal of analytical atomic spectrometry</jtitle><date>2023-08-02</date><risdate>2023</risdate><volume>38</volume><issue>8</issue><spage>1676</spage><epage>1681</epage><pages>1676-1681</pages><issn>0267-9477</issn><eissn>1364-5544</eissn><abstract>Ultratrace analysis is crucial for understanding fuel debris in a nuclear reactor core after severe accidents. Triple quadrupole inductively coupled plasma mass spectrometry measured the ion–molecule reactions of actinides (237Np, 241Am, and 244Cm) in a reaction cell. These nuclides were included in the fuel debris. A gas-phase ion–molecule reaction model has been developed to simulate the gas-phase reactions in the reaction cell. The model simulation results correlate well with the flow rate dependence of experimental data accurately. Reaction constants derived from the model were compared with those reported values by Fourier transform ion-cyclotron resonance mass spectrometry to evaluate the performance of the model. The similarity between the two reaction constants was found.</abstract><cop>London</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3ja00136a</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0267-9477 |
| ispartof | Journal of analytical atomic spectrometry, 2023-08, Vol.38 (8), p.1676-1681 |
| issn | 0267-9477 1364-5544 |
| language | eng |
| recordid | cdi_proquest_journals_2844572884 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Actinides Coupling (molecular) Cyclotron resonance Debris Fourier transforms Fuels Inductively coupled plasma mass spectrometry Mass spectrometry Nuclear reactors Nuclides Quadrupoles Reactor cores |
| title | Reaction of Np, Am, and Cm ions with CO2 and O2 in a reaction cell in triple quadrupole inductively coupled plasma mass spectrometry |
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