Synthesis of poly(ethylene glycol)- co -poly(caprolactone) di- and triblock copolymers and effect of architecture, dispersity and end-functionalisation on their aqueous self-assembly

The synthesis of block copolymers based on polyethylene glycol (PEG) and polycaprolactone (PCL) is reported. PEG- b -PCL diblock copolymers were prepared using both enzymatic and tin-mediated ring-opening polymerisation. Well-defined PEG- b -PCL- b -PEG triblock copolymers were synthesised through c...

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Veröffentlicht in:	Polymer chemistry 2023-08, Vol.14 (30), p.3433-3445
Hauptverfasser:	Norinkevicius, Karolis, Madsen, Jeppe, Christiansen, Line Elmstrøm, Meier, Sebastian, Horner, Andreas, Górecki, Radosław, Regueira, Torsten Høybye Bak, Daugaard, Anders Egede
Format:	Artikel
Sprache:	eng
Schlagworte:	Block copolymers Chemical synthesis Composition Copolymers Cysteamine Hexamethylene diisocyanate Membranes Micelles Polycaprolactone Polyethylene glycol Polymer chemistry Ring opening polymerization Self-assembly
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