Paleoenvironment Comparison of the Longmaxi and Qiongzhusi Formations, Weiyuan Shale Gas Field, Sichuan Basin
The Lower Cambrian Qiongzhusi formation and the Lower Silurian Longmaxi Formation are the two most important shale strata. Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using cores...
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description | The Lower Cambrian Qiongzhusi formation and the Lower Silurian Longmaxi Formation are the two most important shale strata. Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using cores of both Longmaxi and Qiongzhusi formations of well W201, the in situ comparison of the sedimentary environment was realized, and the interference of other factors was eliminated, which made the results more reliable. In this study, 72 samples from both formations were collected from well W201, Weiyuan shale gas field, Sichuan Basin. A systematic study, including total organic carbon (TOC) content, mineral composition, and major/trace elemental analyses, was conducted to elucidate the paleoenvironments of the Qiongzhusi and Longmaxi formations. The results show both formations were deposited in non-sulfidic environments. The depositional conditions of the Longmaxi formation varied from reducing to oxidizing from bottom to top. The detrital flow happened during the deposition of the Qiongzhusi formation, which resulted in three stages of the redox conditions, from anoxic to oxic and then to anoxic from bottom to top of the Qiongzhusi formation. The anoxic conditions of the Qiongzhusi formation were considerably stronger than those of the Longmaxi formation. Both formations were deposited in warm and humid climates. Ratios of Eu/Eu*, Y/Y*, LaN/YbN, light rare earth element (LREE) and heavy rare earth element (HREE) revealed that the Longmaxi formation was primarily controlled by seawater, whereas the Qiongzhusi formation was jointly influenced by seawater and hydrothermal fluid. The organic matter enrichment for the Longmaxi and Qiongzhusi formations was controlled by paleoproductivity and redox conditions. Due to the slightly lower paleoproductivity and influence of detrital input, the degree of organic matter enrichment in the Qiongzhusi formation was lower than that in the Longmaxi formation. |
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Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using cores of both Longmaxi and Qiongzhusi formations of well W201, the in situ comparison of the sedimentary environment was realized, and the interference of other factors was eliminated, which made the results more reliable. In this study, 72 samples from both formations were collected from well W201, Weiyuan shale gas field, Sichuan Basin. A systematic study, including total organic carbon (TOC) content, mineral composition, and major/trace elemental analyses, was conducted to elucidate the paleoenvironments of the Qiongzhusi and Longmaxi formations. The results show both formations were deposited in non-sulfidic environments. The depositional conditions of the Longmaxi formation varied from reducing to oxidizing from bottom to top. The detrital flow happened during the deposition of the Qiongzhusi formation, which resulted in three stages of the redox conditions, from anoxic to oxic and then to anoxic from bottom to top of the Qiongzhusi formation. The anoxic conditions of the Qiongzhusi formation were considerably stronger than those of the Longmaxi formation. Both formations were deposited in warm and humid climates. Ratios of Eu/Eu*, Y/Y*, LaN/YbN, light rare earth element (LREE) and heavy rare earth element (HREE) revealed that the Longmaxi formation was primarily controlled by seawater, whereas the Qiongzhusi formation was jointly influenced by seawater and hydrothermal fluid. The organic matter enrichment for the Longmaxi and Qiongzhusi formations was controlled by paleoproductivity and redox conditions. Due to the slightly lower paleoproductivity and influence of detrital input, the degree of organic matter enrichment in the Qiongzhusi formation was lower than that in the Longmaxi formation.</description><identifier>ISSN: 2227-9717</identifier><identifier>EISSN: 2227-9717</identifier><identifier>DOI: 10.3390/pr11072153</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Carbon ; Comparative studies ; Formations ; Gas fields ; Natural gas ; Organic carbon ; Organic matter ; Oxidation ; Paleoenvironments ; Quartz ; Rare earth elements ; Rare earth metals ; Research methodology ; Seawater ; Sediments ; Shale ; Shale gas ; Shale oils ; Silurian ; Total organic carbon ; Trace elements</subject><ispartof>Processes, 2023-07, Vol.11 (7), p.2153</ispartof><rights>COPYRIGHT 2023 MDPI AG</rights><rights>2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c293t-17d3ad6c5e16b2da6d566da09f7da3532342df774a05f6ebc08834c2d308496a3</cites><orcidid>0000-0002-2241-9377</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Zhang, Qin</creatorcontrib><creatorcontrib>Liang, Feng</creatorcontrib><creatorcontrib>Zeng, Jingbo</creatorcontrib><creatorcontrib>Qiu, Zhen</creatorcontrib><creatorcontrib>Zhou, Shangwen</creatorcontrib><creatorcontrib>Liu, Wen</creatorcontrib><creatorcontrib>Kong, Weiliang</creatorcontrib><title>Paleoenvironment Comparison of the Longmaxi and Qiongzhusi Formations, Weiyuan Shale Gas Field, Sichuan Basin</title><title>Processes</title><description>The Lower Cambrian Qiongzhusi formation and the Lower Silurian Longmaxi Formation are the two most important shale strata. Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using cores of both Longmaxi and Qiongzhusi formations of well W201, the in situ comparison of the sedimentary environment was realized, and the interference of other factors was eliminated, which made the results more reliable. In this study, 72 samples from both formations were collected from well W201, Weiyuan shale gas field, Sichuan Basin. A systematic study, including total organic carbon (TOC) content, mineral composition, and major/trace elemental analyses, was conducted to elucidate the paleoenvironments of the Qiongzhusi and Longmaxi formations. The results show both formations were deposited in non-sulfidic environments. The depositional conditions of the Longmaxi formation varied from reducing to oxidizing from bottom to top. The detrital flow happened during the deposition of the Qiongzhusi formation, which resulted in three stages of the redox conditions, from anoxic to oxic and then to anoxic from bottom to top of the Qiongzhusi formation. The anoxic conditions of the Qiongzhusi formation were considerably stronger than those of the Longmaxi formation. Both formations were deposited in warm and humid climates. Ratios of Eu/Eu*, Y/Y*, LaN/YbN, light rare earth element (LREE) and heavy rare earth element (HREE) revealed that the Longmaxi formation was primarily controlled by seawater, whereas the Qiongzhusi formation was jointly influenced by seawater and hydrothermal fluid. The organic matter enrichment for the Longmaxi and Qiongzhusi formations was controlled by paleoproductivity and redox conditions. Due to the slightly lower paleoproductivity and influence of detrital input, the degree of organic matter enrichment in the Qiongzhusi formation was lower than that in the Longmaxi formation.</description><subject>Carbon</subject><subject>Comparative studies</subject><subject>Formations</subject><subject>Gas fields</subject><subject>Natural gas</subject><subject>Organic carbon</subject><subject>Organic matter</subject><subject>Oxidation</subject><subject>Paleoenvironments</subject><subject>Quartz</subject><subject>Rare earth elements</subject><subject>Rare earth metals</subject><subject>Research methodology</subject><subject>Seawater</subject><subject>Sediments</subject><subject>Shale</subject><subject>Shale gas</subject><subject>Shale oils</subject><subject>Silurian</subject><subject>Total organic carbon</subject><subject>Trace elements</subject><issn>2227-9717</issn><issn>2227-9717</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNpNUU1LAzEQDaJg0V78BQFv0tZ87Ca7x1psFQoqVTwu0022m9JN1mRXrL_elAo6c5h5M28-4CF0RcmE85zctp5SIhlN-QkaMMbkOJdUnv7Lz9EwhC2JllOepWKAmmfYaaftp_HONtp2eOaaFrwJzmJX4a7WeOnspoEvg8Eq_GIi-q77YPDc-Qa6iMMIv2uz78HiVR334QUEPDd6p0Z4Zcr60LiDYOwlOqtgF_TwN16gt_n96-xhvHxaPM6my3HJct6NqVQclChTTcWaKRAqFUIBySupgKec8YSpSsoESFoJvS5JlvGkZIqTLMkF8At0fdzbevfR69AVW9d7G08WLEs4JWm0yJocWZv4c2Fs5ToPZXSlG1M6qysT61OZ5jQnGU3iwM1xoPQuBK-rovWmAb8vKCkOEhR_EvAfqIJ4gg</recordid><startdate>20230701</startdate><enddate>20230701</enddate><creator>Zhang, Qin</creator><creator>Liang, Feng</creator><creator>Zeng, Jingbo</creator><creator>Qiu, Zhen</creator><creator>Zhou, Shangwen</creator><creator>Liu, Wen</creator><creator>Kong, Weiliang</creator><general>MDPI AG</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>LK8</scope><scope>M7P</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-2241-9377</orcidid></search><sort><creationdate>20230701</creationdate><title>Paleoenvironment Comparison of the Longmaxi and Qiongzhusi Formations, Weiyuan Shale Gas Field, Sichuan Basin</title><author>Zhang, Qin ; Liang, Feng ; Zeng, Jingbo ; Qiu, Zhen ; Zhou, Shangwen ; Liu, Wen ; Kong, Weiliang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c293t-17d3ad6c5e16b2da6d566da09f7da3532342df774a05f6ebc08834c2d308496a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon</topic><topic>Comparative studies</topic><topic>Formations</topic><topic>Gas fields</topic><topic>Natural gas</topic><topic>Organic carbon</topic><topic>Organic matter</topic><topic>Oxidation</topic><topic>Paleoenvironments</topic><topic>Quartz</topic><topic>Rare earth elements</topic><topic>Rare earth metals</topic><topic>Research methodology</topic><topic>Seawater</topic><topic>Sediments</topic><topic>Shale</topic><topic>Shale gas</topic><topic>Shale oils</topic><topic>Silurian</topic><topic>Total organic carbon</topic><topic>Trace elements</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Qin</creatorcontrib><creatorcontrib>Liang, Feng</creatorcontrib><creatorcontrib>Zeng, Jingbo</creatorcontrib><creatorcontrib>Qiu, Zhen</creatorcontrib><creatorcontrib>Zhou, Shangwen</creatorcontrib><creatorcontrib>Liu, Wen</creatorcontrib><creatorcontrib>Kong, Weiliang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Biological Science Collection</collection><collection>Biological Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Processes</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Qin</au><au>Liang, Feng</au><au>Zeng, Jingbo</au><au>Qiu, Zhen</au><au>Zhou, Shangwen</au><au>Liu, Wen</au><au>Kong, Weiliang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Paleoenvironment Comparison of the Longmaxi and Qiongzhusi Formations, Weiyuan Shale Gas Field, Sichuan Basin</atitle><jtitle>Processes</jtitle><date>2023-07-01</date><risdate>2023</risdate><volume>11</volume><issue>7</issue><spage>2153</spage><pages>2153-</pages><issn>2227-9717</issn><eissn>2227-9717</eissn><abstract>The Lower Cambrian Qiongzhusi formation and the Lower Silurian Longmaxi Formation are the two most important shale strata. Although differences between these two shales have become the focus of current research, a comparative study of the depositional environments has not been performed. Using cores of both Longmaxi and Qiongzhusi formations of well W201, the in situ comparison of the sedimentary environment was realized, and the interference of other factors was eliminated, which made the results more reliable. In this study, 72 samples from both formations were collected from well W201, Weiyuan shale gas field, Sichuan Basin. A systematic study, including total organic carbon (TOC) content, mineral composition, and major/trace elemental analyses, was conducted to elucidate the paleoenvironments of the Qiongzhusi and Longmaxi formations. The results show both formations were deposited in non-sulfidic environments. The depositional conditions of the Longmaxi formation varied from reducing to oxidizing from bottom to top. The detrital flow happened during the deposition of the Qiongzhusi formation, which resulted in three stages of the redox conditions, from anoxic to oxic and then to anoxic from bottom to top of the Qiongzhusi formation. The anoxic conditions of the Qiongzhusi formation were considerably stronger than those of the Longmaxi formation. Both formations were deposited in warm and humid climates. Ratios of Eu/Eu*, Y/Y*, LaN/YbN, light rare earth element (LREE) and heavy rare earth element (HREE) revealed that the Longmaxi formation was primarily controlled by seawater, whereas the Qiongzhusi formation was jointly influenced by seawater and hydrothermal fluid. The organic matter enrichment for the Longmaxi and Qiongzhusi formations was controlled by paleoproductivity and redox conditions. Due to the slightly lower paleoproductivity and influence of detrital input, the degree of organic matter enrichment in the Qiongzhusi formation was lower than that in the Longmaxi formation.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/pr11072153</doi><orcidid>https://orcid.org/0000-0002-2241-9377</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Carbon Comparative studies Formations Gas fields Natural gas Organic carbon Organic matter Oxidation Paleoenvironments Quartz Rare earth elements Rare earth metals Research methodology Seawater Sediments Shale Shale gas Shale oils Silurian Total organic carbon Trace elements |
title | Paleoenvironment Comparison of the Longmaxi and Qiongzhusi Formations, Weiyuan Shale Gas Field, Sichuan Basin |
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