Ionic Conductivity at Room Temperature and Thermal Stability of Chlorine-Conducting Solid Electrolytes
Search for chlorine-conducting solid electrolytes with a high ionic conductivity σ 293K at room temperature (293 K) is based on the analysis of temperature measurements of the electrical conductivity σ( T ) of simple and complex compounds, solid solutions, composites, and glasses. A comparison of th...
Gespeichert in:
| Veröffentlicht in: | Crystallography reports 2023-04, Vol.68 (2), p.187-194 |
|---|---|
| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 194 |
|---|---|
| container_issue | 2 |
| container_start_page | 187 |
| container_title | Crystallography reports |
| container_volume | 68 |
| creator | Sorokin, N. I. |
| description | Search for chlorine-conducting solid electrolytes with a high ionic conductivity σ
293K
at room temperature (293 K) is based on the analysis of temperature measurements of the electrical conductivity σ(
T
) of simple and complex compounds, solid solutions, composites, and glasses. A comparison of the thermal stability of chlorides is based on the analysis of the dependences σ(
T
) in cyclic heating–cooling measurements and the physicochemical data. Maximum σ
293K
values were found for the solid solutions
(3 × 10
−5
S/cm) and
(1 × 10
−4
S/cm). Promising directions of search for chlorine-ion solid electrolytes for chemical current sources and chlorine sensors operating at room temperature are the method of crystallochemical heterovalent substitutions and implementation of the vacancy mechanism of electrical conductivity in crystal structures of the cotunnite (PbCl
2
) and fluorite (CaF
2
) types. The parameters of the ionic conductivity of cotunnite and fluorite crystals of chlorides and fluorides are analyzed. |
| doi_str_mv | 10.1134/S1063774523020177 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2841449473</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2841449473</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-bd4756bfef7565bcaf076c2cabb94143ea1601722c0200dfb21f8d3a671aecaf3</originalsourceid><addsrcrecordid>eNp1kM1KAzEUhYMoWH8ewF3A9WiSySTTpQxVCwXBVnA3JJmkTZlJapIR-vamVHEhrs6F851zuReAG4zuMC7p_RIjVnJOK1IigjDnJ2CCK0YKVk_fT_Oc7eLgn4OLGLcIobrGdALM3DurYONdN6pkP23aQ5Hgq_cDXOlhp4NIY9BQuA6uNjoMoofLJKTtD6Q3sNn0Plini58Kt4ZL39sOznqtUvD9Pul4Bc6M6KO-_tZL8PY4WzXPxeLlad48LApFWJ0K2VFeMWm0yVJJJQziTBElpJxSTEstMMvHEaLykagzkmBTd6VgHAud6fIS3B57d8F_jDqmduvH4PLKltS5gU4pLzOFj5QKPsagTbsLdhBh32LUHt7Z_nlnzpBjJmbWrXX4bf4_9AWQG3hx</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2841449473</pqid></control><display><type>article</type><title>Ionic Conductivity at Room Temperature and Thermal Stability of Chlorine-Conducting Solid Electrolytes</title><source>SpringerLink</source><creator>Sorokin, N. I.</creator><creatorcontrib>Sorokin, N. I.</creatorcontrib><description>Search for chlorine-conducting solid electrolytes with a high ionic conductivity σ
293K
at room temperature (293 K) is based on the analysis of temperature measurements of the electrical conductivity σ(
T
) of simple and complex compounds, solid solutions, composites, and glasses. A comparison of the thermal stability of chlorides is based on the analysis of the dependences σ(
T
) in cyclic heating–cooling measurements and the physicochemical data. Maximum σ
293K
values were found for the solid solutions
(3 × 10
−5
S/cm) and
(1 × 10
−4
S/cm). Promising directions of search for chlorine-ion solid electrolytes for chemical current sources and chlorine sensors operating at room temperature are the method of crystallochemical heterovalent substitutions and implementation of the vacancy mechanism of electrical conductivity in crystal structures of the cotunnite (PbCl
2
) and fluorite (CaF
2
) types. The parameters of the ionic conductivity of cotunnite and fluorite crystals of chlorides and fluorides are analyzed.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774523020177</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chlorine ; Complex compounds ; Crystallography and Scattering Methods ; Current sources ; Electrical resistivity ; Fluorite ; Ion currents ; Lead chlorides ; Molten salt electrolytes ; Physics ; Physics and Astronomy ; Reviews ; Room temperature ; Solid electrolytes ; Solid solutions ; Stability analysis ; Thermal cycling ; Thermal stability</subject><ispartof>Crystallography reports, 2023-04, Vol.68 (2), p.187-194</ispartof><rights>Pleiades Publishing, Inc. 2023. ISSN 1063-7745, Crystallography Reports, 2023, Vol. 68, No. 2, pp. 187–194. © Pleiades Publishing, Inc., 2023. Russian Text © The Author(s), 2023, published in Kristallografiya, 2023, Vol. 68, No. 2, pp. 171–179.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-bd4756bfef7565bcaf076c2cabb94143ea1601722c0200dfb21f8d3a671aecaf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1063774523020177$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1063774523020177$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sorokin, N. I.</creatorcontrib><title>Ionic Conductivity at Room Temperature and Thermal Stability of Chlorine-Conducting Solid Electrolytes</title><title>Crystallography reports</title><addtitle>Crystallogr. Rep</addtitle><description>Search for chlorine-conducting solid electrolytes with a high ionic conductivity σ
293K
at room temperature (293 K) is based on the analysis of temperature measurements of the electrical conductivity σ(
T
) of simple and complex compounds, solid solutions, composites, and glasses. A comparison of the thermal stability of chlorides is based on the analysis of the dependences σ(
T
) in cyclic heating–cooling measurements and the physicochemical data. Maximum σ
293K
values were found for the solid solutions
(3 × 10
−5
S/cm) and
(1 × 10
−4
S/cm). Promising directions of search for chlorine-ion solid electrolytes for chemical current sources and chlorine sensors operating at room temperature are the method of crystallochemical heterovalent substitutions and implementation of the vacancy mechanism of electrical conductivity in crystal structures of the cotunnite (PbCl
2
) and fluorite (CaF
2
) types. The parameters of the ionic conductivity of cotunnite and fluorite crystals of chlorides and fluorides are analyzed.</description><subject>Chlorine</subject><subject>Complex compounds</subject><subject>Crystallography and Scattering Methods</subject><subject>Current sources</subject><subject>Electrical resistivity</subject><subject>Fluorite</subject><subject>Ion currents</subject><subject>Lead chlorides</subject><subject>Molten salt electrolytes</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Reviews</subject><subject>Room temperature</subject><subject>Solid electrolytes</subject><subject>Solid solutions</subject><subject>Stability analysis</subject><subject>Thermal cycling</subject><subject>Thermal stability</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KAzEUhYMoWH8ewF3A9WiSySTTpQxVCwXBVnA3JJmkTZlJapIR-vamVHEhrs6F851zuReAG4zuMC7p_RIjVnJOK1IigjDnJ2CCK0YKVk_fT_Oc7eLgn4OLGLcIobrGdALM3DurYONdN6pkP23aQ5Hgq_cDXOlhp4NIY9BQuA6uNjoMoofLJKTtD6Q3sNn0Plini58Kt4ZL39sOznqtUvD9Pul4Bc6M6KO-_tZL8PY4WzXPxeLlad48LApFWJ0K2VFeMWm0yVJJJQziTBElpJxSTEstMMvHEaLykagzkmBTd6VgHAud6fIS3B57d8F_jDqmduvH4PLKltS5gU4pLzOFj5QKPsagTbsLdhBh32LUHt7Z_nlnzpBjJmbWrXX4bf4_9AWQG3hx</recordid><startdate>20230401</startdate><enddate>20230401</enddate><creator>Sorokin, N. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230401</creationdate><title>Ionic Conductivity at Room Temperature and Thermal Stability of Chlorine-Conducting Solid Electrolytes</title><author>Sorokin, N. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-bd4756bfef7565bcaf076c2cabb94143ea1601722c0200dfb21f8d3a671aecaf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chlorine</topic><topic>Complex compounds</topic><topic>Crystallography and Scattering Methods</topic><topic>Current sources</topic><topic>Electrical resistivity</topic><topic>Fluorite</topic><topic>Ion currents</topic><topic>Lead chlorides</topic><topic>Molten salt electrolytes</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Reviews</topic><topic>Room temperature</topic><topic>Solid electrolytes</topic><topic>Solid solutions</topic><topic>Stability analysis</topic><topic>Thermal cycling</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sorokin, N. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sorokin, N. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic Conductivity at Room Temperature and Thermal Stability of Chlorine-Conducting Solid Electrolytes</atitle><jtitle>Crystallography reports</jtitle><stitle>Crystallogr. Rep</stitle><date>2023-04-01</date><risdate>2023</risdate><volume>68</volume><issue>2</issue><spage>187</spage><epage>194</epage><pages>187-194</pages><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>Search for chlorine-conducting solid electrolytes with a high ionic conductivity σ
293K
at room temperature (293 K) is based on the analysis of temperature measurements of the electrical conductivity σ(
T
) of simple and complex compounds, solid solutions, composites, and glasses. A comparison of the thermal stability of chlorides is based on the analysis of the dependences σ(
T
) in cyclic heating–cooling measurements and the physicochemical data. Maximum σ
293K
values were found for the solid solutions
(3 × 10
−5
S/cm) and
(1 × 10
−4
S/cm). Promising directions of search for chlorine-ion solid electrolytes for chemical current sources and chlorine sensors operating at room temperature are the method of crystallochemical heterovalent substitutions and implementation of the vacancy mechanism of electrical conductivity in crystal structures of the cotunnite (PbCl
2
) and fluorite (CaF
2
) types. The parameters of the ionic conductivity of cotunnite and fluorite crystals of chlorides and fluorides are analyzed.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1063774523020177</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1063-7745 |
| ispartof | Crystallography reports, 2023-04, Vol.68 (2), p.187-194 |
| issn | 1063-7745 1562-689X |
| language | eng |
| recordid | cdi_proquest_journals_2841449473 |
| source | SpringerLink |
| subjects | Chlorine Complex compounds Crystallography and Scattering Methods Current sources Electrical resistivity Fluorite Ion currents Lead chlorides Molten salt electrolytes Physics Physics and Astronomy Reviews Room temperature Solid electrolytes Solid solutions Stability analysis Thermal cycling Thermal stability |
| title | Ionic Conductivity at Room Temperature and Thermal Stability of Chlorine-Conducting Solid Electrolytes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-11T19%3A29%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ionic%20Conductivity%20at%20Room%20Temperature%20and%20Thermal%20Stability%20of%20Chlorine-Conducting%20Solid%20Electrolytes&rft.jtitle=Crystallography%20reports&rft.au=Sorokin,%20N.%20I.&rft.date=2023-04-01&rft.volume=68&rft.issue=2&rft.spage=187&rft.epage=194&rft.pages=187-194&rft.issn=1063-7745&rft.eissn=1562-689X&rft_id=info:doi/10.1134/S1063774523020177&rft_dat=%3Cproquest_cross%3E2841449473%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2841449473&rft_id=info:pmid/&rfr_iscdi=true |