Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study
The diverse local environment of zinc ions in a ZnCl 2 solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc K -edge XANES spectra in a ZnCl 2 aqueous solution with a critically low concentration (10 –3 М)...
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| Veröffentlicht in: | Crystallography reports 2023-04, Vol.68 (2), p.242-246 |
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| creator | Lysenko, V. Yu Kremennaya, M. A. Yalovega, G. E. |
| description | The diverse local environment of zinc ions in a ZnCl
2
solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc
K
-edge XANES spectra in a ZnCl
2
aqueous solution with a critically low concentration (10
–3
М) have been theoretically analyzed. It is shown that Zn(H
2
O)
complexes with Zn
2+
ions in the octahedral coordination environment of water molecules are dominant in this solution. |
| doi_str_mv | 10.1134/S1063774523020116 |
| format | Article |
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2
solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc
K
-edge XANES spectra in a ZnCl
2
aqueous solution with a critically low concentration (10
–3
М) have been theoretically analyzed. It is shown that Zn(H
2
O)
complexes with Zn
2+
ions in the octahedral coordination environment of water molecules are dominant in this solution.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774523020116</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Crystallography and Scattering Methods ; Physics ; Physics and Astronomy ; Structure of Inorganic Compounds ; Zinc chloride</subject><ispartof>Crystallography reports, 2023-04, Vol.68 (2), p.242-246</ispartof><rights>Pleiades Publishing, Inc. 2023. ISSN 1063-7745, Crystallography Reports, 2023, Vol. 68, No. 2, pp. 242–246. © Pleiades Publishing, Inc., 2023. Russian Text © The Author(s), 2023, published in Kristallografiya, 2023, Vol. 68, No. 2, pp. 228–233.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-54269c567130bf04da8992ff6f05af70da020b846ff5309f391d99e2f99e0b3f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1063774523020116$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1063774523020116$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Lysenko, V. Yu</creatorcontrib><creatorcontrib>Kremennaya, M. A.</creatorcontrib><creatorcontrib>Yalovega, G. E.</creatorcontrib><title>Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study</title><title>Crystallography reports</title><addtitle>Crystallogr. Rep</addtitle><description>The diverse local environment of zinc ions in a ZnCl
2
solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc
K
-edge XANES spectra in a ZnCl
2
aqueous solution with a critically low concentration (10
–3
М) have been theoretically analyzed. It is shown that Zn(H
2
O)
complexes with Zn
2+
ions in the octahedral coordination environment of water molecules are dominant in this solution.</description><subject>Aqueous solutions</subject><subject>Crystallography and Scattering Methods</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Structure of Inorganic Compounds</subject><subject>Zinc chloride</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UEtLxDAQDqLguvoDvAU8SnXyaJp4K8uqC0UPVVi81GzbSJduokmr7L83ywoexMvMMN9jHgidE7gihPHrkoBgWcZTyoACIeIATUgqaCKkWh7GOsLJDj9GJyGsAUBKwifotXC17nE-uE1X47n97Lyzm9YO2Bn8YuklXjgbcGexxoX7SmbO1hH1euicjYRZT3H-MbZuDLh0_bhr3-Bl_jAvcTmMzfYUHRndh_bsJ0_R8-38aXafFI93i1leJDVRckhSToWqU5ERBisDvNFSKWqMMJBqk0Gj41kryYUxKQNlmCKNUi01McCKGTZFF3vfd-_iPmGo1m70No6sqOSEc0WliCyyZ9XeheBbU737bqP9tiJQ7R5Z_Xlk1NC9JkSufWv9r_P_om_Ad3Ky</recordid><startdate>20230401</startdate><enddate>20230401</enddate><creator>Lysenko, V. Yu</creator><creator>Kremennaya, M. A.</creator><creator>Yalovega, G. E.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230401</creationdate><title>Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study</title><author>Lysenko, V. Yu ; Kremennaya, M. A. ; Yalovega, G. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-54269c567130bf04da8992ff6f05af70da020b846ff5309f391d99e2f99e0b3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aqueous solutions</topic><topic>Crystallography and Scattering Methods</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Structure of Inorganic Compounds</topic><topic>Zinc chloride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lysenko, V. Yu</creatorcontrib><creatorcontrib>Kremennaya, M. A.</creatorcontrib><creatorcontrib>Yalovega, G. E.</creatorcontrib><collection>CrossRef</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lysenko, V. Yu</au><au>Kremennaya, M. A.</au><au>Yalovega, G. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study</atitle><jtitle>Crystallography reports</jtitle><stitle>Crystallogr. Rep</stitle><date>2023-04-01</date><risdate>2023</risdate><volume>68</volume><issue>2</issue><spage>242</spage><epage>246</epage><pages>242-246</pages><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>The diverse local environment of zinc ions in a ZnCl
2
solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc
K
-edge XANES spectra in a ZnCl
2
aqueous solution with a critically low concentration (10
–3
М) have been theoretically analyzed. It is shown that Zn(H
2
O)
complexes with Zn
2+
ions in the octahedral coordination environment of water molecules are dominant in this solution.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1063774523020116</doi><tpages>5</tpages></addata></record> |
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| ispartof | Crystallography reports, 2023-04, Vol.68 (2), p.242-246 |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Aqueous solutions Crystallography and Scattering Methods Physics Physics and Astronomy Structure of Inorganic Compounds Zinc chloride |
| title | Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study |
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