Methane/Nitrogen Mixture Plasma Assisted Surface Modification of Polymeric Materials

The aim of this study is to examine methane (CH 4 )/nitrogen (N 2 ) gas mixture plasma surface modification for various polymers including in polytetrafluoroethylene (PTFE), polystyrene (PS), polycarbonate (PC), and high-density polyethylene (HDPE). The static wetting properties of methane (CH 4 )/n...

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Veröffentlicht in:High energy chemistry 2023-08, Vol.57 (4), p.373-378
Hauptverfasser: Ma, Wei-Chun, Chiou, Jiun-Rung, Huang, Chun
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Chiou, Jiun-Rung
Huang, Chun
description The aim of this study is to examine methane (CH 4 )/nitrogen (N 2 ) gas mixture plasma surface modification for various polymers including in polytetrafluoroethylene (PTFE), polystyrene (PS), polycarbonate (PC), and high-density polyethylene (HDPE). The static wetting properties of methane (CH 4 )/nitrogen(N 2 ) plasma deposited films on conventional polymers were investigated using the sessile droplet method. The change of hydrophilicity and surface free energy was monitored by static contact angle measurement. The static contact angle is an excellent indication of the change in surface state properties from plasma surface modification. A new quick image-capturing device enables static contact angle measurement 2 to 4 seconds after contact with the polymeric surface. Significant increases in the surface energies of PTFE, PS, PC, and HDPE by CH 4 /N 2 mixture gas plasma treatments were observed. The experimental results show the critical position of chemical species in the interaction between CH 4 /N 2 mixture gas plasma and the polymeric substrate, which can be controlled by surface modification to tailor the hydrophilicity of the polymers.
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The static wetting properties of methane (CH 4 )/nitrogen(N 2 ) plasma deposited films on conventional polymers were investigated using the sessile droplet method. The change of hydrophilicity and surface free energy was monitored by static contact angle measurement. The static contact angle is an excellent indication of the change in surface state properties from plasma surface modification. A new quick image-capturing device enables static contact angle measurement 2 to 4 seconds after contact with the polymeric surface. Significant increases in the surface energies of PTFE, PS, PC, and HDPE by CH 4 /N 2 mixture gas plasma treatments were observed. 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subjects Chemistry
Chemistry and Materials Science
Contact angle
Free energy
Gas mixtures
Gas plasmas
High density polyethylenes
Hydrophilicity
Methane
Nitrogen
Nitrogen plasma
Physical Chemistry
Plasma
Plasma Chemistry
Polymers
Polystyrene resins
Polytetrafluoroethylene
Substrates
title Methane/Nitrogen Mixture Plasma Assisted Surface Modification of Polymeric Materials
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