Thermal property of polyacrylate copolymers and their application in multilayer ceramic capacitor
Polyacrylate resin is commonly used as a thickener in organic vehicle for electronic slurry, and thermal decomposition of the resin is important for sintering of the electronic slurry. Polymethyl methacrylate-butyl methacrylate (PMMA-BMA) was prepared by free radical polymerization in this paper, th...
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| Veröffentlicht in: | Journal of polymer research 2023-08, Vol.30 (8), Article 314 |
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| creator | Gan, Ruolong Lin, Han Li, Junrong Huang, Jun Cao, Xiuhua Qian, Liying |
| description | Polyacrylate resin is commonly used as a thickener in organic vehicle for electronic slurry, and thermal decomposition of the resin is important for sintering of the electronic slurry. Polymethyl methacrylate-butyl methacrylate (PMMA-BMA) was prepared by free radical polymerization in this paper, the molecular structure of the copolymers was characterized by FTIR and
1
H-NMR. The molar ratio of structure units and the yield were investigated. The effects of temperature, solvent/monomer ratio, initiator concentration and monomer ratio on the molecular weight and Mw/Mn of the copolymer resin were studied. The thermal decomposition of the polyacrylate resin was characterized with various monomer ratios, third monomers and chain transfer agents. The electronic slurry was prepared and sintered with the obtained polyacrylate resin as a thickener. The results showed that the molecular weight and Mw/Mn of the copolymer were influenced by polymerization conditions. The monomer content is closely related to the thermal decomposition and carbon residue of the resin. Addition of third monomer and chain transfer agent is an effective way to adjust the thermal decomposition of the resin. The electronic slurry with the obtained polyacrylate resin as a thickener, was sintered and showed excellent film compactness. |
| doi_str_mv | 10.1007/s10965-023-03665-y |
| format | Article |
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1
H-NMR. The molar ratio of structure units and the yield were investigated. The effects of temperature, solvent/monomer ratio, initiator concentration and monomer ratio on the molecular weight and Mw/Mn of the copolymer resin were studied. The thermal decomposition of the polyacrylate resin was characterized with various monomer ratios, third monomers and chain transfer agents. The electronic slurry was prepared and sintered with the obtained polyacrylate resin as a thickener. The results showed that the molecular weight and Mw/Mn of the copolymer were influenced by polymerization conditions. The monomer content is closely related to the thermal decomposition and carbon residue of the resin. Addition of third monomer and chain transfer agent is an effective way to adjust the thermal decomposition of the resin. The electronic slurry with the obtained polyacrylate resin as a thickener, was sintered and showed excellent film compactness.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-023-03665-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Acrylic resins ; Capacitors ; Chain transfer ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Copolymers ; Decomposition ; Electronic components industry ; Free radical polymerization ; Free radicals ; Industrial Chemistry/Chemical Engineering ; Molecular structure ; Molecular weight ; Monomers ; Multilayers ; NMR ; Nuclear magnetic resonance ; Original Paper ; Polymer Sciences ; Polymerization ; Polymethyl methacrylate ; Polymethylmethacrylate ; Reagents ; Sintering ; Slurries ; Temperature effects ; Thermal decomposition ; Thermal properties ; Thermodynamic properties ; Thickening agents</subject><ispartof>Journal of polymer research, 2023-08, Vol.30 (8), Article 314</ispartof><rights>The Polymer Society, Taipei 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-b9e955b6e3c42e85435027083e131c9cbd76a9f63af8d78a24c1c0518e66f07a3</citedby><cites>FETCH-LOGICAL-c358t-b9e955b6e3c42e85435027083e131c9cbd76a9f63af8d78a24c1c0518e66f07a3</cites><orcidid>0000-0003-4383-1122</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-023-03665-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-023-03665-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Gan, Ruolong</creatorcontrib><creatorcontrib>Lin, Han</creatorcontrib><creatorcontrib>Li, Junrong</creatorcontrib><creatorcontrib>Huang, Jun</creatorcontrib><creatorcontrib>Cao, Xiuhua</creatorcontrib><creatorcontrib>Qian, Liying</creatorcontrib><title>Thermal property of polyacrylate copolymers and their application in multilayer ceramic capacitor</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>Polyacrylate resin is commonly used as a thickener in organic vehicle for electronic slurry, and thermal decomposition of the resin is important for sintering of the electronic slurry. Polymethyl methacrylate-butyl methacrylate (PMMA-BMA) was prepared by free radical polymerization in this paper, the molecular structure of the copolymers was characterized by FTIR and
1
H-NMR. The molar ratio of structure units and the yield were investigated. The effects of temperature, solvent/monomer ratio, initiator concentration and monomer ratio on the molecular weight and Mw/Mn of the copolymer resin were studied. The thermal decomposition of the polyacrylate resin was characterized with various monomer ratios, third monomers and chain transfer agents. The electronic slurry was prepared and sintered with the obtained polyacrylate resin as a thickener. The results showed that the molecular weight and Mw/Mn of the copolymer were influenced by polymerization conditions. The monomer content is closely related to the thermal decomposition and carbon residue of the resin. Addition of third monomer and chain transfer agent is an effective way to adjust the thermal decomposition of the resin. The electronic slurry with the obtained polyacrylate resin as a thickener, was sintered and showed excellent film compactness.</description><subject>Acrylic resins</subject><subject>Capacitors</subject><subject>Chain transfer</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Decomposition</subject><subject>Electronic components industry</subject><subject>Free radical polymerization</subject><subject>Free radicals</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Molecular structure</subject><subject>Molecular weight</subject><subject>Monomers</subject><subject>Multilayers</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymethyl methacrylate</subject><subject>Polymethylmethacrylate</subject><subject>Reagents</subject><subject>Sintering</subject><subject>Slurries</subject><subject>Temperature effects</subject><subject>Thermal decomposition</subject><subject>Thermal properties</subject><subject>Thermodynamic properties</subject><subject>Thickening agents</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kElPwzAQhSMEEusf4GSJc8BLveSIKjYJiUs5W1N30rpK4mC7h_x7XILEDfngsfW-mXmvqm4ZvWeU6ofEaKNkTbmoqVClmk6qCyY1r00j5GmpKed1oxU9ry5T2lMqpVbmooLVDmMPHRljGDHmiYSWjKGbwMWpg4zEheOzx5gIDBuSd-gjgXHsvIPsw0D8QPpDl30HE0biMELvHXEwgvM5xOvqrIUu4c3vfVV9Pj-tlq_1-8fL2_LxvXZCmlyvG2ykXCsUbsHRyIWQlGtqBDLBXOPWG62gaZWA1my0Ab5wzFHJDCrVUg3iqrqb-xYnXwdM2e7DIQ5lpOVGNIYVx7qo7mfVFjq0fmhDjuDK2WDZOgzY-vL_qKU2gi5-AD4DLoaUIrZ2jL6HOFlG7TF7O2dvS_b2J3s7FUjMUCriYYvxb5d_qG9V5oj8</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Gan, Ruolong</creator><creator>Lin, Han</creator><creator>Li, Junrong</creator><creator>Huang, Jun</creator><creator>Cao, Xiuhua</creator><creator>Qian, Liying</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-4383-1122</orcidid></search><sort><creationdate>20230801</creationdate><title>Thermal property of polyacrylate copolymers and their application in multilayer ceramic capacitor</title><author>Gan, Ruolong ; Lin, Han ; Li, Junrong ; Huang, Jun ; Cao, Xiuhua ; Qian, Liying</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-b9e955b6e3c42e85435027083e131c9cbd76a9f63af8d78a24c1c0518e66f07a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acrylic resins</topic><topic>Capacitors</topic><topic>Chain transfer</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Decomposition</topic><topic>Electronic components industry</topic><topic>Free radical polymerization</topic><topic>Free radicals</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Molecular structure</topic><topic>Molecular weight</topic><topic>Monomers</topic><topic>Multilayers</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Original Paper</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymethyl methacrylate</topic><topic>Polymethylmethacrylate</topic><topic>Reagents</topic><topic>Sintering</topic><topic>Slurries</topic><topic>Temperature effects</topic><topic>Thermal decomposition</topic><topic>Thermal properties</topic><topic>Thermodynamic properties</topic><topic>Thickening agents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gan, Ruolong</creatorcontrib><creatorcontrib>Lin, Han</creatorcontrib><creatorcontrib>Li, Junrong</creatorcontrib><creatorcontrib>Huang, Jun</creatorcontrib><creatorcontrib>Cao, Xiuhua</creatorcontrib><creatorcontrib>Qian, Liying</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gan, Ruolong</au><au>Lin, Han</au><au>Li, Junrong</au><au>Huang, Jun</au><au>Cao, Xiuhua</au><au>Qian, Liying</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal property of polyacrylate copolymers and their application in multilayer ceramic capacitor</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2023-08-01</date><risdate>2023</risdate><volume>30</volume><issue>8</issue><artnum>314</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>Polyacrylate resin is commonly used as a thickener in organic vehicle for electronic slurry, and thermal decomposition of the resin is important for sintering of the electronic slurry. Polymethyl methacrylate-butyl methacrylate (PMMA-BMA) was prepared by free radical polymerization in this paper, the molecular structure of the copolymers was characterized by FTIR and
1
H-NMR. The molar ratio of structure units and the yield were investigated. The effects of temperature, solvent/monomer ratio, initiator concentration and monomer ratio on the molecular weight and Mw/Mn of the copolymer resin were studied. The thermal decomposition of the polyacrylate resin was characterized with various monomer ratios, third monomers and chain transfer agents. The electronic slurry was prepared and sintered with the obtained polyacrylate resin as a thickener. The results showed that the molecular weight and Mw/Mn of the copolymer were influenced by polymerization conditions. The monomer content is closely related to the thermal decomposition and carbon residue of the resin. Addition of third monomer and chain transfer agent is an effective way to adjust the thermal decomposition of the resin. The electronic slurry with the obtained polyacrylate resin as a thickener, was sintered and showed excellent film compactness.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-023-03665-y</doi><orcidid>https://orcid.org/0000-0003-4383-1122</orcidid></addata></record> |
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| subjects | Acrylic resins Capacitors Chain transfer Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Copolymers Decomposition Electronic components industry Free radical polymerization Free radicals Industrial Chemistry/Chemical Engineering Molecular structure Molecular weight Monomers Multilayers NMR Nuclear magnetic resonance Original Paper Polymer Sciences Polymerization Polymethyl methacrylate Polymethylmethacrylate Reagents Sintering Slurries Temperature effects Thermal decomposition Thermal properties Thermodynamic properties Thickening agents |
| title | Thermal property of polyacrylate copolymers and their application in multilayer ceramic capacitor |
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