Physicochemical characteristics of polysaccharides from catalytic and noncatalytic acetic acid-peroxide delignification of larch wood
The composition and physicochemical characteristics of polysaccharides extracted from spent liquors of catalytic and noncatalytic delignification of larch wood in the acetic acid-hydrogen peroxide medium were studied. The following were used as catalysts: (NH 4 ) 6 Mo 7 O 24 , MnSO 4 , TiO 2 , and Z...
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| Veröffentlicht in: | Biomass conversion and biorefinery 2023-07, Vol.13 (11), p.9765-9774 |
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| creator | Chudina, Anna I. Malyar, Yuriy N. Sudakova, Irina G. Kazachenko, Aleksandr S. Skripnikov, Andrey M. Borovkova, Valentina S. Kondrasenko, Alexander A. Mazurova, Elena V. Fetisova, Olga Yu Ivanov, Ivan P. |
| description | The composition and physicochemical characteristics of polysaccharides extracted from spent liquors of catalytic and noncatalytic delignification of larch wood in the acetic acid-hydrogen peroxide medium were studied. The following were used as catalysts: (NH
4
)
6
Mo
7
O
24
, MnSO
4
, TiO
2
, and ZnSO
4
. The structure of polysaccharides was identified by FTIR and NMR spectroscopy. Their composition was established using gas chromatography, and the physicochemical characteristics were studied using gel permeation chromatography, scanning electron microscopy, thermogravimetric analysis, gas adsorption, and elemental analysis. It was shown that in the process of oxidative delignification, a significant amount of hemicelluloses and arabinogalactan passes into the spent liquor. The yield of polysaccharides was up to 16.9 wt%. Polysaccharides had a weight-average molecular weight of up to 22.9 kDa and a narrow molecular weight distribution.
Graphical abstract |
| doi_str_mv | 10.1007/s13399-021-01833-y |
| format | Article |
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4
)
6
Mo
7
O
24
, MnSO
4
, TiO
2
, and ZnSO
4
. The structure of polysaccharides was identified by FTIR and NMR spectroscopy. Their composition was established using gas chromatography, and the physicochemical characteristics were studied using gel permeation chromatography, scanning electron microscopy, thermogravimetric analysis, gas adsorption, and elemental analysis. It was shown that in the process of oxidative delignification, a significant amount of hemicelluloses and arabinogalactan passes into the spent liquor. The yield of polysaccharides was up to 16.9 wt%. Polysaccharides had a weight-average molecular weight of up to 22.9 kDa and a narrow molecular weight distribution.
Graphical abstract</description><identifier>ISSN: 2190-6815</identifier><identifier>EISSN: 2190-6823</identifier><identifier>DOI: 10.1007/s13399-021-01833-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Acetic acid ; Ammonium molybdate ; Biotechnology ; Chemical analysis ; Composition ; Energy ; Gas chromatography ; Gel chromatography ; Hydrogen peroxide ; Molecular weight distribution ; NMR spectroscopy ; Original Article ; Polysaccharides ; Renewable and Green Energy ; Spent liquors ; Thermogravimetric analysis ; Titanium dioxide</subject><ispartof>Biomass conversion and biorefinery, 2023-07, Vol.13 (11), p.9765-9774</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-a89ad6dbd23f8b3dac7964b0111a05040c18ff333d9d79d47e0e6ffc843bd8b43</citedby><cites>FETCH-LOGICAL-c319t-a89ad6dbd23f8b3dac7964b0111a05040c18ff333d9d79d47e0e6ffc843bd8b43</cites><orcidid>0000-0001-9380-0290</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13399-021-01833-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13399-021-01833-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Chudina, Anna I.</creatorcontrib><creatorcontrib>Malyar, Yuriy N.</creatorcontrib><creatorcontrib>Sudakova, Irina G.</creatorcontrib><creatorcontrib>Kazachenko, Aleksandr S.</creatorcontrib><creatorcontrib>Skripnikov, Andrey M.</creatorcontrib><creatorcontrib>Borovkova, Valentina S.</creatorcontrib><creatorcontrib>Kondrasenko, Alexander A.</creatorcontrib><creatorcontrib>Mazurova, Elena V.</creatorcontrib><creatorcontrib>Fetisova, Olga Yu</creatorcontrib><creatorcontrib>Ivanov, Ivan P.</creatorcontrib><title>Physicochemical characteristics of polysaccharides from catalytic and noncatalytic acetic acid-peroxide delignification of larch wood</title><title>Biomass conversion and biorefinery</title><addtitle>Biomass Conv. Bioref</addtitle><description>The composition and physicochemical characteristics of polysaccharides extracted from spent liquors of catalytic and noncatalytic delignification of larch wood in the acetic acid-hydrogen peroxide medium were studied. The following were used as catalysts: (NH
4
)
6
Mo
7
O
24
, MnSO
4
, TiO
2
, and ZnSO
4
. The structure of polysaccharides was identified by FTIR and NMR spectroscopy. Their composition was established using gas chromatography, and the physicochemical characteristics were studied using gel permeation chromatography, scanning electron microscopy, thermogravimetric analysis, gas adsorption, and elemental analysis. It was shown that in the process of oxidative delignification, a significant amount of hemicelluloses and arabinogalactan passes into the spent liquor. The yield of polysaccharides was up to 16.9 wt%. Polysaccharides had a weight-average molecular weight of up to 22.9 kDa and a narrow molecular weight distribution.
Graphical abstract</description><subject>Acetic acid</subject><subject>Ammonium molybdate</subject><subject>Biotechnology</subject><subject>Chemical analysis</subject><subject>Composition</subject><subject>Energy</subject><subject>Gas chromatography</subject><subject>Gel chromatography</subject><subject>Hydrogen peroxide</subject><subject>Molecular weight distribution</subject><subject>NMR spectroscopy</subject><subject>Original Article</subject><subject>Polysaccharides</subject><subject>Renewable and Green Energy</subject><subject>Spent liquors</subject><subject>Thermogravimetric analysis</subject><subject>Titanium dioxide</subject><issn>2190-6815</issn><issn>2190-6823</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAQx4souKz7BTwFPFcnnW6bHGXxBQt60HNI89hm6TY16aL9AH5vu1bUk6cZZv4P-CXJOYVLClBeRYrIeQoZTYEyxHQ4SmYZ5ZAWLMPjn50uT5NFjFsAyLBEhjBLPp7qITrlVW12TsmGqFoGqXoTXOydisRb0vlmiFIdPk6bSGzwO6JkL5thlBDZatL69s9BmWk4nXYm-PfRRbRp3KZ1dizpnW8PuY0MqiZv3uuz5MTKJprF95wnL7c3z6v7dP1497C6XqcKKe9TybjUha50hpZVqKUqeZFXQCmVsIQcFGXWIqLmuuQ6Lw2YwlrFcqw0q3KcJxdTbhf8697EXmz9PrRjpcgYcmT5soRRlU0qFXyMwVjRBbeTYRAUxIG4mIiLkbj4Ii6G0YSTKY7idmPCb_Q_rk8J-Igi</recordid><startdate>20230701</startdate><enddate>20230701</enddate><creator>Chudina, Anna I.</creator><creator>Malyar, Yuriy N.</creator><creator>Sudakova, Irina G.</creator><creator>Kazachenko, Aleksandr S.</creator><creator>Skripnikov, Andrey M.</creator><creator>Borovkova, Valentina S.</creator><creator>Kondrasenko, Alexander A.</creator><creator>Mazurova, Elena V.</creator><creator>Fetisova, Olga Yu</creator><creator>Ivanov, Ivan P.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-9380-0290</orcidid></search><sort><creationdate>20230701</creationdate><title>Physicochemical characteristics of polysaccharides from catalytic and noncatalytic acetic acid-peroxide delignification of larch wood</title><author>Chudina, Anna I. ; Malyar, Yuriy N. ; Sudakova, Irina G. ; Kazachenko, Aleksandr S. ; Skripnikov, Andrey M. ; Borovkova, Valentina S. ; Kondrasenko, Alexander A. ; Mazurova, Elena V. ; Fetisova, Olga Yu ; Ivanov, Ivan P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-a89ad6dbd23f8b3dac7964b0111a05040c18ff333d9d79d47e0e6ffc843bd8b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acetic acid</topic><topic>Ammonium molybdate</topic><topic>Biotechnology</topic><topic>Chemical analysis</topic><topic>Composition</topic><topic>Energy</topic><topic>Gas chromatography</topic><topic>Gel chromatography</topic><topic>Hydrogen peroxide</topic><topic>Molecular weight distribution</topic><topic>NMR spectroscopy</topic><topic>Original Article</topic><topic>Polysaccharides</topic><topic>Renewable and Green Energy</topic><topic>Spent liquors</topic><topic>Thermogravimetric analysis</topic><topic>Titanium dioxide</topic><toplevel>online_resources</toplevel><creatorcontrib>Chudina, Anna I.</creatorcontrib><creatorcontrib>Malyar, Yuriy N.</creatorcontrib><creatorcontrib>Sudakova, Irina G.</creatorcontrib><creatorcontrib>Kazachenko, Aleksandr S.</creatorcontrib><creatorcontrib>Skripnikov, Andrey M.</creatorcontrib><creatorcontrib>Borovkova, Valentina S.</creatorcontrib><creatorcontrib>Kondrasenko, Alexander A.</creatorcontrib><creatorcontrib>Mazurova, Elena V.</creatorcontrib><creatorcontrib>Fetisova, Olga Yu</creatorcontrib><creatorcontrib>Ivanov, Ivan P.</creatorcontrib><collection>CrossRef</collection><jtitle>Biomass conversion and biorefinery</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chudina, Anna I.</au><au>Malyar, Yuriy N.</au><au>Sudakova, Irina G.</au><au>Kazachenko, Aleksandr S.</au><au>Skripnikov, Andrey M.</au><au>Borovkova, Valentina S.</au><au>Kondrasenko, Alexander A.</au><au>Mazurova, Elena V.</au><au>Fetisova, Olga Yu</au><au>Ivanov, Ivan P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Physicochemical characteristics of polysaccharides from catalytic and noncatalytic acetic acid-peroxide delignification of larch wood</atitle><jtitle>Biomass conversion and biorefinery</jtitle><stitle>Biomass Conv. Bioref</stitle><date>2023-07-01</date><risdate>2023</risdate><volume>13</volume><issue>11</issue><spage>9765</spage><epage>9774</epage><pages>9765-9774</pages><issn>2190-6815</issn><eissn>2190-6823</eissn><abstract>The composition and physicochemical characteristics of polysaccharides extracted from spent liquors of catalytic and noncatalytic delignification of larch wood in the acetic acid-hydrogen peroxide medium were studied. The following were used as catalysts: (NH
4
)
6
Mo
7
O
24
, MnSO
4
, TiO
2
, and ZnSO
4
. The structure of polysaccharides was identified by FTIR and NMR spectroscopy. Their composition was established using gas chromatography, and the physicochemical characteristics were studied using gel permeation chromatography, scanning electron microscopy, thermogravimetric analysis, gas adsorption, and elemental analysis. It was shown that in the process of oxidative delignification, a significant amount of hemicelluloses and arabinogalactan passes into the spent liquor. The yield of polysaccharides was up to 16.9 wt%. Polysaccharides had a weight-average molecular weight of up to 22.9 kDa and a narrow molecular weight distribution.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13399-021-01833-y</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-9380-0290</orcidid></addata></record> |
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| subjects | Acetic acid Ammonium molybdate Biotechnology Chemical analysis Composition Energy Gas chromatography Gel chromatography Hydrogen peroxide Molecular weight distribution NMR spectroscopy Original Article Polysaccharides Renewable and Green Energy Spent liquors Thermogravimetric analysis Titanium dioxide |
| title | Physicochemical characteristics of polysaccharides from catalytic and noncatalytic acetic acid-peroxide delignification of larch wood |
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