Hydrophobically Associated Poly(acrylamide/octadecyl acrylate)-Carboxymethyl Cellulose Hydrogels: Synthesis, Characterization, and Shape Memory Ability
In this study, hydrophobic modified poly(acrylamide/octadecyl acrylate) (poly(AAm/C18)) and poly(acrylamide/octadecyl acrylate)-carboxymethyl cellulose (poly(AAm/C18)-CMC) hydrogels with high mechanical strength and shape memory properties were synthesized by random copolymerization method. Hydrogel...
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| Veröffentlicht in: | Journal of polymers and the environment 2023-08, Vol.31 (8), p.3650-3663 |
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| creator | Olukman Şahin, Merve Demirbilek Bucak, Celile |
| description | In this study, hydrophobic modified poly(acrylamide/octadecyl acrylate) (poly(AAm/C18)) and poly(acrylamide/octadecyl acrylate)-carboxymethyl cellulose (poly(AAm/C18)-CMC) hydrogels with high mechanical strength and shape memory properties were synthesized by random copolymerization method. Hydrogel synthesis was successfully carried out in one step on the basis of the hydrophobic monomer units carrying alkyl side chains included in the hydrophilic polymer network, and these hydrophobes clustered in water and acted as crosslinks. Hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), Differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and X-ray diffractometry (XRD). The results showed that with the increase of the amount of hydrophobic monomer (C18) in the hydrogels, the crystal regions in the hydrogel structure increased. The swelling behaviour of the hydrogels was investigated as a function of the hydrophobic monomer content. Experimental swelling data confirmed the DSC and XRD results. The shape memory properties of hydrogels containing CMC were investigated. The new shape of the hydrogels was fixed by complexation between CMC and metal (M
2+
and M
3+
valence) ions. |
| doi_str_mv | 10.1007/s10924-023-02807-z |
| format | Article |
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2+
and M
3+
valence) ions.</description><subject>Acrylamide</subject><subject>acrylamides</subject><subject>Calorimetry</subject><subject>Carboxymethyl cellulose</subject><subject>Carboxymethylcellulose</subject><subject>Cellulose</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymerization</subject><subject>crosslinking</subject><subject>Differential scanning calorimetry</subject><subject>electron microscopy</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Fourier transforms</subject><subject>Gravimetric analysis</subject><subject>Hydrogels</subject><subject>hydrophilicity</subject><subject>Hydrophobicity</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Materials Science</subject><subject>Mechanical properties</subject><subject>Monomers</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Scanning electron microscopy</subject><subject>Shape memory</subject><subject>strength (mechanics)</subject><subject>Swelling</subject><subject>Thermal analysis</subject><subject>Thermogravimetric analysis</subject><subject>thermogravimetry</subject><subject>X-ray diffraction</subject><issn>1566-2543</issn><issn>1572-8919</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kV9r1jAYxYs4cG5-Aa8K3kxYXZq_rXejqBMmG0yvQ5o8XTPS5jXJC8v7Rfy6ZqsgeOFFSDj8znmecKrqbYs-tAiJi9iiHtMGYVJOh0RzeFEdt0zgpuvb_uXTm_MGM0peVa9jfEAI9cV4XP26yib43exHq5Vzub6M0WurEpj61rt8pnTITi3WwIXXSRnQ2dWbmOB9M6gw-se8QJqLPoBze-cj1M-x9-Dix_our2mGaON5PcwqKJ0g2INK1q_ntVpNfTerHdTfYPGhzB-tsymfVkeTchHe_LlPqh-fP30frprrmy9fh8vrRhOGU2PE1GE19lj1uOsER8ZgSgTv-hEo54giJsikOOUMFBNm7Alno8ZTN9KW4o6cVGdb7i74n3uISS426vINtYLfR0laRlqBWIcK-u4f9MHvw1q2kyVIcMowoYXCG6WDjzHAJHfBLipk2SL51JXcupKlK_nclTwUE9lMscDrPYS_0f9x_QbV55n6</recordid><startdate>20230801</startdate><enddate>20230801</enddate><creator>Olukman Şahin, Merve</creator><creator>Demirbilek Bucak, Celile</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20230801</creationdate><title>Hydrophobically Associated Poly(acrylamide/octadecyl acrylate)-Carboxymethyl Cellulose Hydrogels: Synthesis, Characterization, and Shape Memory Ability</title><author>Olukman Şahin, Merve ; Demirbilek Bucak, Celile</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-d7f82ab92a9288760dd2437689be466040573fa6465ea57db9365bc2f8b414283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acrylamide</topic><topic>acrylamides</topic><topic>Calorimetry</topic><topic>Carboxymethyl cellulose</topic><topic>Carboxymethylcellulose</topic><topic>Cellulose</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymerization</topic><topic>crosslinking</topic><topic>Differential scanning calorimetry</topic><topic>electron microscopy</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Fourier transforms</topic><topic>Gravimetric analysis</topic><topic>Hydrogels</topic><topic>hydrophilicity</topic><topic>Hydrophobicity</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Materials Science</topic><topic>Mechanical properties</topic><topic>Monomers</topic><topic>Original Paper</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Scanning electron microscopy</topic><topic>Shape memory</topic><topic>strength (mechanics)</topic><topic>Swelling</topic><topic>Thermal analysis</topic><topic>Thermogravimetric analysis</topic><topic>thermogravimetry</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Olukman Şahin, Merve</creatorcontrib><creatorcontrib>Demirbilek Bucak, Celile</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Olukman Şahin, Merve</au><au>Demirbilek Bucak, Celile</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrophobically Associated Poly(acrylamide/octadecyl acrylate)-Carboxymethyl Cellulose Hydrogels: Synthesis, Characterization, and Shape Memory Ability</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2023-08-01</date><risdate>2023</risdate><volume>31</volume><issue>8</issue><spage>3650</spage><epage>3663</epage><pages>3650-3663</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><abstract>In this study, hydrophobic modified poly(acrylamide/octadecyl acrylate) (poly(AAm/C18)) and poly(acrylamide/octadecyl acrylate)-carboxymethyl cellulose (poly(AAm/C18)-CMC) hydrogels with high mechanical strength and shape memory properties were synthesized by random copolymerization method. Hydrogel synthesis was successfully carried out in one step on the basis of the hydrophobic monomer units carrying alkyl side chains included in the hydrophilic polymer network, and these hydrophobes clustered in water and acted as crosslinks. Hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), Differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and X-ray diffractometry (XRD). The results showed that with the increase of the amount of hydrophobic monomer (C18) in the hydrogels, the crystal regions in the hydrogel structure increased. The swelling behaviour of the hydrogels was investigated as a function of the hydrophobic monomer content. Experimental swelling data confirmed the DSC and XRD results. The shape memory properties of hydrogels containing CMC were investigated. The new shape of the hydrogels was fixed by complexation between CMC and metal (M
2+
and M
3+
valence) ions.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-023-02807-z</doi><tpages>14</tpages></addata></record> |
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| subjects | Acrylamide acrylamides Calorimetry Carboxymethyl cellulose Carboxymethylcellulose Cellulose Chemical synthesis Chemistry Chemistry and Materials Science Copolymerization crosslinking Differential scanning calorimetry electron microscopy Environmental Chemistry Environmental Engineering/Biotechnology Fourier transform infrared spectroscopy Fourier transforms Gravimetric analysis Hydrogels hydrophilicity Hydrophobicity Industrial Chemistry/Chemical Engineering Infrared analysis Infrared spectroscopy Materials Science Mechanical properties Monomers Original Paper Polymer Sciences Polymers Scanning electron microscopy Shape memory strength (mechanics) Swelling Thermal analysis Thermogravimetric analysis thermogravimetry X-ray diffraction |
| title | Hydrophobically Associated Poly(acrylamide/octadecyl acrylate)-Carboxymethyl Cellulose Hydrogels: Synthesis, Characterization, and Shape Memory Ability |
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