Amplified Chirality Transfer to Aromatic Molecules through Non‐specific Inclusion by Amorphous, Hyperbranched Poly(fluorenevinylene) Derivatives

Optically active, hyperbranched, poly(fluorene‐2,4,7‐triylethene‐1,2‐diyl) [poly(fluorenevinylene)] derivatives bearing a neomenthyl group and a pentyl group at the 9‐position of the fluorene backbone at various ratios acted as a chirality donor (host polymers) efficiently included naphthalene, anthracene, pyrene, 9‐phenylanthracene, and 9,10‐diphenyanthracene as a chirality acceptor (guest molecules) in their interior space in film as well as in solution, with the guest molecules exhibiting intense circular dichroism through chirality transfer with chirality amplification. The efficiency of the chirality transfer was much higher with higher‐molar‐mass polymers than lower‐molar‐mass ones as well as with hyperbranched polymers compared to the analogous linear ones. The hyperbranched polymers include the small molecules in their complex structure without any specific interactions at various stoichiometries. The included molecules may have ordered intermolecular arrangement that may be somewhat similar to those of liquid crystals. Naphthalene, anthracene, and pyrene included in the polymer exhibited efficient circularly polarized luminescence, where the chirality was remarkably amplified in excited states, and anthracene exhibited especially high anisotropies in the emission on the order of 10−2. Optically active, hyperbranched poly(fluorenevinylene) derivatives have been shown to include aromatic small molecules in their interior space. These small molecules form liquid‐crystal‐like intermolecular arrangements and exhibit clear circular dichroism and efficient circularly polarized luminescence with remarkably amplified anisotropy.