Modulating the luminescent performances on blue-emitting coordination polymers via tuning the end-solvent molecules
In this paper, a series of coordination polymers, {[Zn(adb)(L1) 2 ]·solvent} n (L1 = solvent = N , N -dimethylacetamide, Hui-3-DMA ; L1 = N , N -dimethylformamide and no solvent, Hui-3-DMF ; L1 = N , N -diethylformamide and no solvent, Hui-3-DEF ) have been synthesized by hydrothermal reactions of Z...
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| Veröffentlicht in: | CrystEngComm 2023-07, Vol.25 (27), p.3896-3903 |
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| creator | Hu, Hui Zhang, Zhen-Wei Zhang, Da-Shuai Zhou, Xue Ji, Hui Zhang, Yong-Zheng Deng, Yuchen Geng, Longlong Zhang, Xiuling Lv, Chao Wei, Rongmin Wang, Jin-Hua |
| description | In this paper, a series of coordination polymers, {[Zn(adb)(L1)
2
]·solvent}
n
(L1 = solvent =
N
,
N
-dimethylacetamide,
Hui-3-DMA
; L1 =
N
,
N
-dimethylformamide and no solvent,
Hui-3-DMF
; L1 =
N
,
N
-diethylformamide and no solvent,
Hui-3-DEF
) have been synthesized by hydrothermal reactions of Zn(NO
3
)
3
·6H
2
O and 4,4′-(anthracene-9,10-diyl)dibenzoic acid (H
2
adb). These compounds show similar one-dimensional (1D) zig-zag chain structures, which are limited by the end-coordination of the solvent molecules. Interestingly, these compounds all show blue-emission properties, which could be easily modulated by using different solvents. Among them,
Hui-3-DMA
presents an excellent quantum yield performance, as high as to 54.1%, which is very promising for blue-emission materials. Moreover, various-temperature fluorescence studies reveal good linear or exponential decline trends for their emission intensity as temperature increases, demonstrating the potential of these compounds as fluorescent thermometers. |
| doi_str_mv | 10.1039/D3CE00551H |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2834902420</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2834902420</sourcerecordid><originalsourceid>FETCH-LOGICAL-c259t-e647fdf1d54d337542286e10a9c1771f113b321b1d59fa73c1baa77176837d1b3</originalsourceid><addsrcrecordid>eNpNkE1LxDAQhoMouK5e_AUBb0I1k6RfR1lXV1jxoueSphPtkiY1aRf239t1FT3NwPvMM_AScgnsBpgob-_FYslYmsLqiMxAZllSMCGO_-2n5CzGDWMgAdiMxGffjFYNrXunwwdSO3atw6jRDbTHYHzolNMYqXe0tiMm2LXDN629D03rptMp6r3ddRgi3baKDqP71aFrkujtdq_rvEU9Wozn5MQoG_HiZ87J28PydbFK1i-PT4u7daJ5Wg4JZjI3jYEmlY0QeSo5LzIEpkoNeQ4GQNSCQz0BpVG50FArNQV5Voi8gVrMydXB2wf_OWIcqo0fg5teVrwQsmRccjZR1wdKBx9jQFP1oe1U2FXAqn2p1V-p4gvuZmtC</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2834902420</pqid></control><display><type>article</type><title>Modulating the luminescent performances on blue-emitting coordination polymers via tuning the end-solvent molecules</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Hu, Hui ; Zhang, Zhen-Wei ; Zhang, Da-Shuai ; Zhou, Xue ; Ji, Hui ; Zhang, Yong-Zheng ; Deng, Yuchen ; Geng, Longlong ; Zhang, Xiuling ; Lv, Chao ; Wei, Rongmin ; Wang, Jin-Hua</creator><creatorcontrib>Hu, Hui ; Zhang, Zhen-Wei ; Zhang, Da-Shuai ; Zhou, Xue ; Ji, Hui ; Zhang, Yong-Zheng ; Deng, Yuchen ; Geng, Longlong ; Zhang, Xiuling ; Lv, Chao ; Wei, Rongmin ; Wang, Jin-Hua</creatorcontrib><description>In this paper, a series of coordination polymers, {[Zn(adb)(L1)
2
]·solvent}
n
(L1 = solvent =
N
,
N
-dimethylacetamide,
Hui-3-DMA
; L1 =
N
,
N
-dimethylformamide and no solvent,
Hui-3-DMF
; L1 =
N
,
N
-diethylformamide and no solvent,
Hui-3-DEF
) have been synthesized by hydrothermal reactions of Zn(NO
3
)
3
·6H
2
O and 4,4′-(anthracene-9,10-diyl)dibenzoic acid (H
2
adb). These compounds show similar one-dimensional (1D) zig-zag chain structures, which are limited by the end-coordination of the solvent molecules. Interestingly, these compounds all show blue-emission properties, which could be easily modulated by using different solvents. Among them,
Hui-3-DMA
presents an excellent quantum yield performance, as high as to 54.1%, which is very promising for blue-emission materials. Moreover, various-temperature fluorescence studies reveal good linear or exponential decline trends for their emission intensity as temperature increases, demonstrating the potential of these compounds as fluorescent thermometers.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/D3CE00551H</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anthracene ; Chemical synthesis ; Coordination polymers ; Dimethyl acetamide ; Dimethylformamide ; Emission analysis ; Emission spectra ; Fluorescence ; Hydrothermal reactions ; Solvents</subject><ispartof>CrystEngComm, 2023-07, Vol.25 (27), p.3896-3903</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-e647fdf1d54d337542286e10a9c1771f113b321b1d59fa73c1baa77176837d1b3</citedby><cites>FETCH-LOGICAL-c259t-e647fdf1d54d337542286e10a9c1771f113b321b1d59fa73c1baa77176837d1b3</cites><orcidid>0000-0003-4798-3641 ; 0000-0002-5744-0352 ; 0000-0003-2864-9007 ; 0000-0002-7171-6933 ; 0000-0003-4528-7829</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hu, Hui</creatorcontrib><creatorcontrib>Zhang, Zhen-Wei</creatorcontrib><creatorcontrib>Zhang, Da-Shuai</creatorcontrib><creatorcontrib>Zhou, Xue</creatorcontrib><creatorcontrib>Ji, Hui</creatorcontrib><creatorcontrib>Zhang, Yong-Zheng</creatorcontrib><creatorcontrib>Deng, Yuchen</creatorcontrib><creatorcontrib>Geng, Longlong</creatorcontrib><creatorcontrib>Zhang, Xiuling</creatorcontrib><creatorcontrib>Lv, Chao</creatorcontrib><creatorcontrib>Wei, Rongmin</creatorcontrib><creatorcontrib>Wang, Jin-Hua</creatorcontrib><title>Modulating the luminescent performances on blue-emitting coordination polymers via tuning the end-solvent molecules</title><title>CrystEngComm</title><description>In this paper, a series of coordination polymers, {[Zn(adb)(L1)
2
]·solvent}
n
(L1 = solvent =
N
,
N
-dimethylacetamide,
Hui-3-DMA
; L1 =
N
,
N
-dimethylformamide and no solvent,
Hui-3-DMF
; L1 =
N
,
N
-diethylformamide and no solvent,
Hui-3-DEF
) have been synthesized by hydrothermal reactions of Zn(NO
3
)
3
·6H
2
O and 4,4′-(anthracene-9,10-diyl)dibenzoic acid (H
2
adb). These compounds show similar one-dimensional (1D) zig-zag chain structures, which are limited by the end-coordination of the solvent molecules. Interestingly, these compounds all show blue-emission properties, which could be easily modulated by using different solvents. Among them,
Hui-3-DMA
presents an excellent quantum yield performance, as high as to 54.1%, which is very promising for blue-emission materials. Moreover, various-temperature fluorescence studies reveal good linear or exponential decline trends for their emission intensity as temperature increases, demonstrating the potential of these compounds as fluorescent thermometers.</description><subject>Anthracene</subject><subject>Chemical synthesis</subject><subject>Coordination polymers</subject><subject>Dimethyl acetamide</subject><subject>Dimethylformamide</subject><subject>Emission analysis</subject><subject>Emission spectra</subject><subject>Fluorescence</subject><subject>Hydrothermal reactions</subject><subject>Solvents</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkE1LxDAQhoMouK5e_AUBb0I1k6RfR1lXV1jxoueSphPtkiY1aRf239t1FT3NwPvMM_AScgnsBpgob-_FYslYmsLqiMxAZllSMCGO_-2n5CzGDWMgAdiMxGffjFYNrXunwwdSO3atw6jRDbTHYHzolNMYqXe0tiMm2LXDN629D03rptMp6r3ddRgi3baKDqP71aFrkujtdq_rvEU9Wozn5MQoG_HiZ87J28PydbFK1i-PT4u7daJ5Wg4JZjI3jYEmlY0QeSo5LzIEpkoNeQ4GQNSCQz0BpVG50FArNQV5Voi8gVrMydXB2wf_OWIcqo0fg5teVrwQsmRccjZR1wdKBx9jQFP1oe1U2FXAqn2p1V-p4gvuZmtC</recordid><startdate>20230710</startdate><enddate>20230710</enddate><creator>Hu, Hui</creator><creator>Zhang, Zhen-Wei</creator><creator>Zhang, Da-Shuai</creator><creator>Zhou, Xue</creator><creator>Ji, Hui</creator><creator>Zhang, Yong-Zheng</creator><creator>Deng, Yuchen</creator><creator>Geng, Longlong</creator><creator>Zhang, Xiuling</creator><creator>Lv, Chao</creator><creator>Wei, Rongmin</creator><creator>Wang, Jin-Hua</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-4798-3641</orcidid><orcidid>https://orcid.org/0000-0002-5744-0352</orcidid><orcidid>https://orcid.org/0000-0003-2864-9007</orcidid><orcidid>https://orcid.org/0000-0002-7171-6933</orcidid><orcidid>https://orcid.org/0000-0003-4528-7829</orcidid></search><sort><creationdate>20230710</creationdate><title>Modulating the luminescent performances on blue-emitting coordination polymers via tuning the end-solvent molecules</title><author>Hu, Hui ; Zhang, Zhen-Wei ; Zhang, Da-Shuai ; Zhou, Xue ; Ji, Hui ; Zhang, Yong-Zheng ; Deng, Yuchen ; Geng, Longlong ; Zhang, Xiuling ; Lv, Chao ; Wei, Rongmin ; Wang, Jin-Hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-e647fdf1d54d337542286e10a9c1771f113b321b1d59fa73c1baa77176837d1b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anthracene</topic><topic>Chemical synthesis</topic><topic>Coordination polymers</topic><topic>Dimethyl acetamide</topic><topic>Dimethylformamide</topic><topic>Emission analysis</topic><topic>Emission spectra</topic><topic>Fluorescence</topic><topic>Hydrothermal reactions</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hu, Hui</creatorcontrib><creatorcontrib>Zhang, Zhen-Wei</creatorcontrib><creatorcontrib>Zhang, Da-Shuai</creatorcontrib><creatorcontrib>Zhou, Xue</creatorcontrib><creatorcontrib>Ji, Hui</creatorcontrib><creatorcontrib>Zhang, Yong-Zheng</creatorcontrib><creatorcontrib>Deng, Yuchen</creatorcontrib><creatorcontrib>Geng, Longlong</creatorcontrib><creatorcontrib>Zhang, Xiuling</creatorcontrib><creatorcontrib>Lv, Chao</creatorcontrib><creatorcontrib>Wei, Rongmin</creatorcontrib><creatorcontrib>Wang, Jin-Hua</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hu, Hui</au><au>Zhang, Zhen-Wei</au><au>Zhang, Da-Shuai</au><au>Zhou, Xue</au><au>Ji, Hui</au><au>Zhang, Yong-Zheng</au><au>Deng, Yuchen</au><au>Geng, Longlong</au><au>Zhang, Xiuling</au><au>Lv, Chao</au><au>Wei, Rongmin</au><au>Wang, Jin-Hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modulating the luminescent performances on blue-emitting coordination polymers via tuning the end-solvent molecules</atitle><jtitle>CrystEngComm</jtitle><date>2023-07-10</date><risdate>2023</risdate><volume>25</volume><issue>27</issue><spage>3896</spage><epage>3903</epage><pages>3896-3903</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>In this paper, a series of coordination polymers, {[Zn(adb)(L1)
2
]·solvent}
n
(L1 = solvent =
N
,
N
-dimethylacetamide,
Hui-3-DMA
; L1 =
N
,
N
-dimethylformamide and no solvent,
Hui-3-DMF
; L1 =
N
,
N
-diethylformamide and no solvent,
Hui-3-DEF
) have been synthesized by hydrothermal reactions of Zn(NO
3
)
3
·6H
2
O and 4,4′-(anthracene-9,10-diyl)dibenzoic acid (H
2
adb). These compounds show similar one-dimensional (1D) zig-zag chain structures, which are limited by the end-coordination of the solvent molecules. Interestingly, these compounds all show blue-emission properties, which could be easily modulated by using different solvents. Among them,
Hui-3-DMA
presents an excellent quantum yield performance, as high as to 54.1%, which is very promising for blue-emission materials. Moreover, various-temperature fluorescence studies reveal good linear or exponential decline trends for their emission intensity as temperature increases, demonstrating the potential of these compounds as fluorescent thermometers.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/D3CE00551H</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-4798-3641</orcidid><orcidid>https://orcid.org/0000-0002-5744-0352</orcidid><orcidid>https://orcid.org/0000-0003-2864-9007</orcidid><orcidid>https://orcid.org/0000-0002-7171-6933</orcidid><orcidid>https://orcid.org/0000-0003-4528-7829</orcidid></addata></record> |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anthracene Chemical synthesis Coordination polymers Dimethyl acetamide Dimethylformamide Emission analysis Emission spectra Fluorescence Hydrothermal reactions Solvents |
| title | Modulating the luminescent performances on blue-emitting coordination polymers via tuning the end-solvent molecules |
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