Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands
New heteroleptic zinc catecholate complexes based on 3,6-di- tert -butyl- o -benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermo...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2023-07, Vol.49 (7), p.420-428 |
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| container_title | Russian journal of coordination chemistry |
| container_volume | 49 |
| creator | Maleeva, A. V. Trofimova, O. Yu Yakushev, I. A. Aysin, R. R. Piskunov, A. V. |
| description | New heteroleptic zinc catecholate complexes based on 3,6-di-
tert
-butyl-
o
-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (
I
), 2222705 (
II
)). The electronic transmission spectra of crystalline samples of
I
and
II
and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm. |
| doi_str_mv | 10.1134/S1070328423600134 |
| format | Article |
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tert
-butyl-
o
-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (
I
), 2222705 (
II
)). The electronic transmission spectra of crystalline samples of
I
and
II
and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328423600134</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Absorption spectra ; Benzoquinone ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Ligands ; Physical Chemistry ; Zinc</subject><ispartof>Russian journal of coordination chemistry, 2023-07, Vol.49 (7), p.420-428</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2023, Vol. 49, No. 7, pp. 420–428. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Koordinatsionnaya Khimiya, 2023, Vol. 49, No. 7, pp. 412–421.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-2c1cce05651fa7a268fa5cacaf668121aeadcda72d746a31b2ee0bd6b3cad9543</citedby><cites>FETCH-LOGICAL-c316t-2c1cce05651fa7a268fa5cacaf668121aeadcda72d746a31b2ee0bd6b3cad9543</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328423600134$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328423600134$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Maleeva, A. V.</creatorcontrib><creatorcontrib>Trofimova, O. Yu</creatorcontrib><creatorcontrib>Yakushev, I. A.</creatorcontrib><creatorcontrib>Aysin, R. R.</creatorcontrib><creatorcontrib>Piskunov, A. V.</creatorcontrib><title>Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>New heteroleptic zinc catecholate complexes based on 3,6-di-
tert
-butyl-
o
-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (
I
), 2222705 (
II
)). The electronic transmission spectra of crystalline samples of
I
and
II
and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.</description><subject>Absorption spectra</subject><subject>Benzoquinone</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Physical Chemistry</subject><subject>Zinc</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLw0AQhRdRsFZ_gLeA5-jObnaTgheJ1gpBD-rFS5huJm1Kmo27Keq_d0sED-JphnnfewOPsXPglwAyuXoGnnIpskRIzXm4HLAJaJ7FUkJ2GPYgx3v9mJ14vwkI52o2YdcLGsjZlvqhMdFb05kox4HM2rZhRLnd9i19ko8-mmEdPca3trMuKpoVdpU_ZUc1tp7OfuaUvc7vXvJFXDzdP-Q3RWwk6CEWBowhrrSCGlMUOqtRGTRYa52BACSsTIWpqNJEo4SlIOLLSi-lwWqmEjllF2Nu7-z7jvxQbuzOdeFlKTIppFJyJgMFI2Wc9d5RXfau2aL7KoGX-5LKPyUFjxg9PrDditxv8v-mb-iDaGo</recordid><startdate>20230701</startdate><enddate>20230701</enddate><creator>Maleeva, A. V.</creator><creator>Trofimova, O. Yu</creator><creator>Yakushev, I. A.</creator><creator>Aysin, R. R.</creator><creator>Piskunov, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230701</creationdate><title>Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands</title><author>Maleeva, A. V. ; Trofimova, O. Yu ; Yakushev, I. A. ; Aysin, R. R. ; Piskunov, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-2c1cce05651fa7a268fa5cacaf668121aeadcda72d746a31b2ee0bd6b3cad9543</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Absorption spectra</topic><topic>Benzoquinone</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Physical Chemistry</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maleeva, A. V.</creatorcontrib><creatorcontrib>Trofimova, O. Yu</creatorcontrib><creatorcontrib>Yakushev, I. A.</creatorcontrib><creatorcontrib>Aysin, R. R.</creatorcontrib><creatorcontrib>Piskunov, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maleeva, A. V.</au><au>Trofimova, O. Yu</au><au>Yakushev, I. A.</au><au>Aysin, R. R.</au><au>Piskunov, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2023-07-01</date><risdate>2023</risdate><volume>49</volume><issue>7</issue><spage>420</spage><epage>428</epage><pages>420-428</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>New heteroleptic zinc catecholate complexes based on 3,6-di-
tert
-butyl-
o
-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (
I
), 2222705 (
II
)). The electronic transmission spectra of crystalline samples of
I
and
II
and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328423600134</doi><tpages>9</tpages></addata></record> |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Absorption spectra Benzoquinone Chemistry Chemistry and Materials Science Inorganic Chemistry Ligands Physical Chemistry Zinc |
| title | Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands |
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