Synthesis and characterization of Cu2O@Cu/Al-CLDH for efficient adsorption of iodide anions in aqueous solutions

A HKUST-1 derivative composite based on LDH was synthesized to efficiently adsorb iodide anions in aqueous solutions. Specifically, Cu/Al-LDH, HKUST-1, HKUST-1@Cu/Al-LDH, Cu/Al-CLDH, Cu-C and Cu 2 O@Cu/Al-CLDH were synthesized and characterized. HKUST-1@Cu/Al-LDH kept the desirable characteristics o...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2023-07, Vol.332 (7), p.2793-2805
Hauptverfasser: Gong, Chun-Hui, Li, Zhi-Ying, Chen, Kai-Wei, Gu, Ao-Tian, Wang, Peng, Yang, Yi
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container_end_page 2805
container_issue 7
container_start_page 2793
container_title Journal of radioanalytical and nuclear chemistry
container_volume 332
creator Gong, Chun-Hui
Li, Zhi-Ying
Chen, Kai-Wei
Gu, Ao-Tian
Wang, Peng
Yang, Yi
description A HKUST-1 derivative composite based on LDH was synthesized to efficiently adsorb iodide anions in aqueous solutions. Specifically, Cu/Al-LDH, HKUST-1, HKUST-1@Cu/Al-LDH, Cu/Al-CLDH, Cu-C and Cu 2 O@Cu/Al-CLDH were synthesized and characterized. HKUST-1@Cu/Al-LDH kept the desirable characteristics of both Cu/Al-LDH and HKUST-1. Cu 2 O@Cu/Al-CLDH maintained the morphology of HKUST-1@Cu/Al-LDH, with its iodine anions absorption mechanism being chemical adsorption. Cu 2 O@Cu/Al-CLDH exhibited a significantly higher adsorption capacity than previously reported Cu-based adsorbents, with an adsorption capacity of 240.7 mg g −1 at pH 3, taking about 240 min to reach adsorption equilibrium. Thus, Cu 2 O@Cu/Al-CLDH is a promising adsorbent for removing iodide anions from aqueous solutions.
doi_str_mv 10.1007/s10967-023-08943-z
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subjects Adsorbents
Adsorption
Aluminum
Anions
Aqueous solutions
Chemistry
Chemistry and Materials Science
Copper
Copper oxides
Diagnostic Radiology
Hadrons
Heavy Ions
Inorganic Chemistry
Iodine
Nuclear Chemistry
Nuclear Physics
Physical Chemistry
Synthesis
title Synthesis and characterization of Cu2O@Cu/Al-CLDH for efficient adsorption of iodide anions in aqueous solutions
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