Study of groundwater recharge using combined unsaturated‐and saturated‐zone chloride mass balance methods

Understanding groundwater recharge mechanisms is essential for reliable groundwater recharge estimation for sustainable groundwater resource assessment and management, especially in arid and semiarid areas. In this study, chloride, together with stable isotopes (18O and 2H), in 1‐year rainfall, soil water from representative profiles, and groundwater samples, collected in the Ordos Plateau, northern China were analysed. Groundwater recharge was estimated using unsaturated‐ and saturated‐zone chloride mass balance (CMB). An equation that describes the relationship between chloride concentrations in saturated zone water (Csz) and soil water residence time (τ) was derived. With the help of the relationship, chloride concentrations in unsaturated zone water (Cuz) and in groundwater (Csz) can be used to uncover water flow and chloride transport in the unsaturated zone. The relationship between Csz and Cuz indicates that, the groundwater was recharged mainly by intense rainfall events. Small rainfall events did not lead to groundwater recharge but contributed to the flux of chloride to soil surface. Stable isotopic compositions of 18O and 2H provided corroborative evidence of the recharge processes. The relationship between Csz and τ indicates further that there is no source of chloride in the groundwater other than that from precipitation. Thus, Csz can give more reliable recharge estimates. Cuz was influenced by heavy rainfall‐induced runoff, run‐on and bypass flow events and cannot give reliable recharge estimates. However, if used jointly with Csz, Cuz can help to gain insights into recharge processes and yield groundwater recharge estimates with higher certainty. The outcomes of this study can assist for groundwater recharge investigation and assessment in regions where the assumptions and boundary conditions necessary for the correct application of the CMB method may not be met. The groundwater was recharged mainly by intense rainfall events. Small rainfall events did not lead to groundwater recharge but contributed to the flux of chloride to soil surface. Csz can give more reliable recharge estimates. Cuz was influenced by heavy rainfall‐induced runoff, run‐on and bypass flow events. Combined usage of Csz and Cuz can help to gain insights into recharge processes and yield groundwater recharge estimates with higher certainty.