A tetrathiafulvalene salt of the nitrite (NO) anion: investigations of the spin-Peierls phase

Electrocrystallization of ortho -dimethyltetrathiafulvalene ( o -DMTTF) in the presence of a nitrite (NO 2 − ) anion affords a 2 : 1 phase, namely ( o -DMTTF) 2 NO 2 , the first example of an isolated cation radical salt with NO 2 − . The o -DMTTF molecule organizes into strongly dimerized stacks th...

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Veröffentlicht in:	Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2023-06, Vol.11 (24), p.817-8177
Hauptverfasser:	Soriano, Loïc, Orio, Maylis, Pilone, Olivier, Jeannin, Olivier, Reinheimer, Eric, Quéméré, Nicolas, Auban-Senzier, Pascale, Fourmigué, Marc, Bertaina, Sylvain
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Chemical Sciences Defects Dimerization Electron paramagnetic resonance Inhomogeneity Low temperature Magnetic measurement Material chemistry Nitrogen dioxide Superconducting quantum interference devices Temperature dependence
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