Covalent organic framework and hydrogen-bonded organic framework for solar-driven photocatalysis

The newly emerging porous crystalline materials, covalent organic framework (COF) and hydrogen-bonded organic framework (HOF), are characterized by their large surface area, considerable structural diversity, and functional tailorability. Combining these properties, they are considered to have the p...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2023-06, Vol.11 (24), p.12521-12538
Hauptverfasser: Qin, Wei-Kang, Tung, Chen-Ho, Wu, Li-Zhu
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container_title Journal of materials chemistry. A, Materials for energy and sustainability
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creator Qin, Wei-Kang
Tung, Chen-Ho
Wu, Li-Zhu
description The newly emerging porous crystalline materials, covalent organic framework (COF) and hydrogen-bonded organic framework (HOF), are characterized by their large surface area, considerable structural diversity, and functional tailorability. Combining these properties, they are considered to have the potential for photocatalysis. This review summarizes their advantages and compatibility, particularly focusing on design strategies to overcome the existing issues of poor charge conductivity and deficient active sites. With representative examples of solar-driven hydrogen (H 2 ) evolution and carbon dioxide (CO 2 ) reduction, the exploration and expectation of such functional porous materials are presented. The features of COF and HOF in porosity, light harvesting, and structural multifunctionality enable their application for photocatalysis. Focusing on the existing merits, rational developing way is helpful for constructing more excellent porous photocatalyst.
doi_str_mv 10.1039/d2ta09375h
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source Royal Society Of Chemistry Journals 2008-
subjects Carbon dioxide
Hydrogen
Hydrogen bonding
Photocatalysis
Porous materials
Structure-function relationships
title Covalent organic framework and hydrogen-bonded organic framework for solar-driven photocatalysis
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