Synthesis and electrochemical energy storage performance evaluation of PANI functionalized CNTs/Ni–Zn (PO4)2 nanocomposites
In this study, the nanocomposites of binary transition metal phosphate [Ni 0.75 Zn 0.25 (PO 4 ) 2 ] with PANI–CNTs were prepared through sonochemical-assisted synthesis approach and were characterized for their potential use in electrochemical energy storage applications. The morphology and hierarch...
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| Veröffentlicht in: | Applied physics. A, Materials science & processing Materials science & processing, 2023-07, Vol.129 (7), Article 492 |
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| creator | Shehzad, Waseem Abdul Karim, Muhammad Ramzan |
| description | In this study, the nanocomposites of binary transition metal phosphate [Ni
0.75
Zn
0.25
(PO
4
)
2
] with PANI–CNTs were prepared through sonochemical-assisted synthesis approach and were characterized for their potential use in electrochemical energy storage applications. The morphology and hierarchical structure were seen by scanning electron microscopy (SEM) coupled with EDX mapping, whereas the chemical composition and functional group analysis were done by EDX, XRD, and FT-IR. At 0.7 Ag
−1
current density, the best-performing electrode of Ni
0.75
Zn
0.25
(PO
4
)
2
–60 mg PANI/CNTs (NZP60) showed specific capacity of 1143 Cg
−1
. A representative asymmetric supercapacitor (ASC) device of NZP60//AC showed an exceptional energy density of 89.2 Wh kg
−1
at 630 W kg
−1
power density. Additionally, the cyclic performance (99.86% after 5000 GCD cycles) and rate performance (25% increase after stability test) were excellent. The ASC device has dominant diffusive behavior (89.7%) due to its highest pseudocapacitive binary metal phosphate chemically grafted on conductive polyaniline and carbon nanotubes (CNTs). Hence, Ni–Zn binary metal phosphate/PANI functionalized CNTs nanocomposites have good potential to be used in ASC-based energy storage applications. |
| doi_str_mv | 10.1007/s00339-023-06732-9 |
| format | Article |
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0.75
Zn
0.25
(PO
4
)
2
] with PANI–CNTs were prepared through sonochemical-assisted synthesis approach and were characterized for their potential use in electrochemical energy storage applications. The morphology and hierarchical structure were seen by scanning electron microscopy (SEM) coupled with EDX mapping, whereas the chemical composition and functional group analysis were done by EDX, XRD, and FT-IR. At 0.7 Ag
−1
current density, the best-performing electrode of Ni
0.75
Zn
0.25
(PO
4
)
2
–60 mg PANI/CNTs (NZP60) showed specific capacity of 1143 Cg
−1
. A representative asymmetric supercapacitor (ASC) device of NZP60//AC showed an exceptional energy density of 89.2 Wh kg
−1
at 630 W kg
−1
power density. Additionally, the cyclic performance (99.86% after 5000 GCD cycles) and rate performance (25% increase after stability test) were excellent. The ASC device has dominant diffusive behavior (89.7%) due to its highest pseudocapacitive binary metal phosphate chemically grafted on conductive polyaniline and carbon nanotubes (CNTs). Hence, Ni–Zn binary metal phosphate/PANI functionalized CNTs nanocomposites have good potential to be used in ASC-based energy storage applications.</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-023-06732-9</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied physics ; Carbon nanotubes ; Characterization and Evaluation of Materials ; Chemical composition ; Condensed Matter Physics ; Electrons ; Energy storage ; Functional groups ; Machines ; Manufacturing ; Materials science ; Nanocomposites ; Nanotechnology ; Optical and Electronic Materials ; Performance evaluation ; Physics ; Physics and Astronomy ; Polyanilines ; Processes ; Stability tests ; Surfaces and Interfaces ; Synthesis ; Thin Films ; Transition metals ; Zinc</subject><ispartof>Applied physics. A, Materials science & processing, 2023-07, Vol.129 (7), Article 492</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-baa990ffc34a4e826afb4774c93996415c60fca6e57c5d3beabab589328fb0733</citedby><cites>FETCH-LOGICAL-c319t-baa990ffc34a4e826afb4774c93996415c60fca6e57c5d3beabab589328fb0733</cites><orcidid>0000-0003-3061-3687</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00339-023-06732-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00339-023-06732-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Shehzad, Waseem</creatorcontrib><creatorcontrib>Abdul Karim, Muhammad Ramzan</creatorcontrib><title>Synthesis and electrochemical energy storage performance evaluation of PANI functionalized CNTs/Ni–Zn (PO4)2 nanocomposites</title><title>Applied physics. A, Materials science & processing</title><addtitle>Appl. Phys. A</addtitle><description>In this study, the nanocomposites of binary transition metal phosphate [Ni
0.75
Zn
0.25
(PO
4
)
2
] with PANI–CNTs were prepared through sonochemical-assisted synthesis approach and were characterized for their potential use in electrochemical energy storage applications. The morphology and hierarchical structure were seen by scanning electron microscopy (SEM) coupled with EDX mapping, whereas the chemical composition and functional group analysis were done by EDX, XRD, and FT-IR. At 0.7 Ag
−1
current density, the best-performing electrode of Ni
0.75
Zn
0.25
(PO
4
)
2
–60 mg PANI/CNTs (NZP60) showed specific capacity of 1143 Cg
−1
. A representative asymmetric supercapacitor (ASC) device of NZP60//AC showed an exceptional energy density of 89.2 Wh kg
−1
at 630 W kg
−1
power density. Additionally, the cyclic performance (99.86% after 5000 GCD cycles) and rate performance (25% increase after stability test) were excellent. The ASC device has dominant diffusive behavior (89.7%) due to its highest pseudocapacitive binary metal phosphate chemically grafted on conductive polyaniline and carbon nanotubes (CNTs). Hence, Ni–Zn binary metal phosphate/PANI functionalized CNTs nanocomposites have good potential to be used in ASC-based energy storage applications.</description><subject>Applied physics</subject><subject>Carbon nanotubes</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical composition</subject><subject>Condensed Matter Physics</subject><subject>Electrons</subject><subject>Energy storage</subject><subject>Functional groups</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials science</subject><subject>Nanocomposites</subject><subject>Nanotechnology</subject><subject>Optical and Electronic Materials</subject><subject>Performance evaluation</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Polyanilines</subject><subject>Processes</subject><subject>Stability tests</subject><subject>Surfaces and Interfaces</subject><subject>Synthesis</subject><subject>Thin Films</subject><subject>Transition metals</subject><subject>Zinc</subject><issn>0947-8396</issn><issn>1432-0630</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKAzEUhoMoWC8v4CrgRhejmSSdmSxL8QbSCurGTTiTnrRTpklNpkIFwXfwDX0SoxXceTY5hO__OXyEHOXsLGesPI-MCaEyxkXGilLwTG2RXi7TwgrBtkmPKVlmlVDFLtmLcc7SSM575O1-7boZxiZScBOKLZoueDPDRWOgpegwTNc0dj7AFOkSg_VhAc4gxRdoV9A13lFv6d1gdEPtypnvD2ibV5zQ4eghno-az_ePJ0dP7sbylFMHzhu_WPrYdBgPyI6FNuLh77tPHi8vHobX2e346mY4uM2MyFWX1QBKMWuNkCCx4gXYWpalNEooVci8bwpmDRTYL01_ImqEGup-pQSvbM1KIfbJ8aZ3GfzzCmOn534V0p1R81RXMZmgRPENZYKPMaDVy9AsIKx1zvS3Zr3RrJNm_aNZqxQSm1BMsJti-Kv-J_UFbwOCvw</recordid><startdate>20230701</startdate><enddate>20230701</enddate><creator>Shehzad, Waseem</creator><creator>Abdul Karim, Muhammad Ramzan</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3061-3687</orcidid></search><sort><creationdate>20230701</creationdate><title>Synthesis and electrochemical energy storage performance evaluation of PANI functionalized CNTs/Ni–Zn (PO4)2 nanocomposites</title><author>Shehzad, Waseem ; Abdul Karim, Muhammad Ramzan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-baa990ffc34a4e826afb4774c93996415c60fca6e57c5d3beabab589328fb0733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Applied physics</topic><topic>Carbon nanotubes</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical composition</topic><topic>Condensed Matter Physics</topic><topic>Electrons</topic><topic>Energy storage</topic><topic>Functional groups</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials science</topic><topic>Nanocomposites</topic><topic>Nanotechnology</topic><topic>Optical and Electronic Materials</topic><topic>Performance evaluation</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Polyanilines</topic><topic>Processes</topic><topic>Stability tests</topic><topic>Surfaces and Interfaces</topic><topic>Synthesis</topic><topic>Thin Films</topic><topic>Transition metals</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shehzad, Waseem</creatorcontrib><creatorcontrib>Abdul Karim, Muhammad Ramzan</creatorcontrib><collection>CrossRef</collection><jtitle>Applied physics. A, Materials science & processing</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shehzad, Waseem</au><au>Abdul Karim, Muhammad Ramzan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and electrochemical energy storage performance evaluation of PANI functionalized CNTs/Ni–Zn (PO4)2 nanocomposites</atitle><jtitle>Applied physics. A, Materials science & processing</jtitle><stitle>Appl. Phys. A</stitle><date>2023-07-01</date><risdate>2023</risdate><volume>129</volume><issue>7</issue><artnum>492</artnum><issn>0947-8396</issn><eissn>1432-0630</eissn><abstract>In this study, the nanocomposites of binary transition metal phosphate [Ni
0.75
Zn
0.25
(PO
4
)
2
] with PANI–CNTs were prepared through sonochemical-assisted synthesis approach and were characterized for their potential use in electrochemical energy storage applications. The morphology and hierarchical structure were seen by scanning electron microscopy (SEM) coupled with EDX mapping, whereas the chemical composition and functional group analysis were done by EDX, XRD, and FT-IR. At 0.7 Ag
−1
current density, the best-performing electrode of Ni
0.75
Zn
0.25
(PO
4
)
2
–60 mg PANI/CNTs (NZP60) showed specific capacity of 1143 Cg
−1
. A representative asymmetric supercapacitor (ASC) device of NZP60//AC showed an exceptional energy density of 89.2 Wh kg
−1
at 630 W kg
−1
power density. Additionally, the cyclic performance (99.86% after 5000 GCD cycles) and rate performance (25% increase after stability test) were excellent. The ASC device has dominant diffusive behavior (89.7%) due to its highest pseudocapacitive binary metal phosphate chemically grafted on conductive polyaniline and carbon nanotubes (CNTs). Hence, Ni–Zn binary metal phosphate/PANI functionalized CNTs nanocomposites have good potential to be used in ASC-based energy storage applications.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-023-06732-9</doi><orcidid>https://orcid.org/0000-0003-3061-3687</orcidid></addata></record> |
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| subjects | Applied physics Carbon nanotubes Characterization and Evaluation of Materials Chemical composition Condensed Matter Physics Electrons Energy storage Functional groups Machines Manufacturing Materials science Nanocomposites Nanotechnology Optical and Electronic Materials Performance evaluation Physics Physics and Astronomy Polyanilines Processes Stability tests Surfaces and Interfaces Synthesis Thin Films Transition metals Zinc |
| title | Synthesis and electrochemical energy storage performance evaluation of PANI functionalized CNTs/Ni–Zn (PO4)2 nanocomposites |
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