Investigation of Phase Formation in Ceramic Based on Zn, Sn, and Ti Oxides

Solid-phase sintering was used to make ceramic from a mixture of ZnO, SnO 2 , and TiO 2 nanopowders used as precipitation-strengthening and arc-quenching components in silver-based electrocontact materials. The phase formation and microstructure of the resulting material were studied by electron mic...

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Veröffentlicht in:Glass and ceramics 2023-03, Vol.79 (11-12), p.507-511
Hauptverfasser: Zeer, G. M., Zelenkova, E. G., Shubin, A. A., Abkaryan, A. K., Beletskii, V. V.
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container_end_page 511
container_issue 11-12
container_start_page 507
container_title Glass and ceramics
container_volume 79
creator Zeer, G. M.
Zelenkova, E. G.
Shubin, A. A.
Abkaryan, A. K.
Beletskii, V. V.
description Solid-phase sintering was used to make ceramic from a mixture of ZnO, SnO 2 , and TiO 2 nanopowders used as precipitation-strengthening and arc-quenching components in silver-based electrocontact materials. The phase formation and microstructure of the resulting material were studied by electron microscopy, energy-dispersive microanalysis, and x-ray phase analysis. It was found that a dispersed structure of size 0.5 – 1.0 μm forms from the Zn 2 TiO 4 and ZnO phases at sintering temperature 1123 K, and the samples have quite high porosity. Solid-phase reactions in the ZnO/TiO 2 system at T sint = 1123 K effect the formation of two-phase ZnO/Zn 2 TiO 4 ceramic with zinc and tin oxide phases in residual amounts. At sintering temperature 1443 K grain growth occurs, Zn 2 SnO 4 becomes the predominant phase, and a certain amount of zinc and tin oxide phases remains. There is no manifestations of titanium-containing phases (presumably TiO 2 and Zn 2 TiO 4 ), probably because of their low content.
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subjects Analysis
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Dispersion
Glass
Grain growth
Investigations
Materials Science
Natural Materials
Oxides
Precipitation hardening
Sintering
Sintering (powder metallurgy)
Solid phases
Tin
Tin dioxide
Tin oxides
Titanium
Titanium dioxide
Zinc oxide
Zinc stannate
title Investigation of Phase Formation in Ceramic Based on Zn, Sn, and Ti Oxides
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