Remarkably enhanced dielectric properties in PVDF composites via engineering core@shell structured ZnO@PS nanoparticles
In order to concurrently suppress the dielectric loss and enhance the breakdown strength ( E b ) of raw zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) composites, in this study, the polystyrene (PS) encapsulated ZnO particles were fabricated via a suspension polymerization method, and further compo...
Gespeichert in:
| Veröffentlicht in: | Journal of materials science. Materials in electronics 2023-06, Vol.34 (16), p.1314, Article 1314 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 16 |
| container_start_page | 1314 |
| container_title | Journal of materials science. Materials in electronics |
| container_volume | 34 |
| creator | Yang, Yating Zhou, Wenying Zhou, Juanjuan Cao, Jing Liu, Jing Niu, Hongmei Liu, Dengfeng Feng, Aihong Li, Ying |
| description | In order to concurrently suppress the dielectric loss and enhance the breakdown strength (
E
b
) of raw zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) composites, in this study, the polystyrene (PS) encapsulated ZnO particles were fabricated via a suspension polymerization method, and further composited with PVDF to deliberately generate morphology-controllable high dielectric permittivity (
ε′
) and
E
b
but low-loss nanocomposites. The effects of the PS shell and its thickness on the dielectric properties of the ZnO/PVDF were investigated as a function of the filler concentration and frequency. Besides, the Havriliak-Negami (H-N) expression was used to fit the dielectric properties so as to theoretically comprehend the PS interlayer’s effect on the polarization and carrier migration mechanism in the nanocomposites. Research results verify that the ZnO@PS/PVDF nanocomposites present very low loss and conductivity when compared to the raw ZnO/PVDF thanks to the insulating PS shell’s ability to effectively prevent the ZnO particles from contacting with one another, thereby prohibiting the appearance of leakage current. And the filler’s homogeneous dispersion in PVDF is also enhanced owing to improved interfacial compatibility and interactions subsequently elevating the
E
b
of nanocomposites. Moreover, by adjusting the PS shell’ thickness, the dielectric properties of the nanocomposites can be efficiently tuned. Therefore, the developed ZnO@PS/PVDF nanocomposites with high-ε′ and
E
b
but low loss, present promising application prospects in microelectronic and electrical industries. |
| doi_str_mv | 10.1007/s10854-023-10728-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2825543098</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2825543098</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-9b1f178566f0795f560e5ed6a317942d1949579346996b825b19db96bd9f05253</originalsourceid><addsrcrecordid>eNp9kN1LwzAUxYMoOKf_gE8Bn6v5aNrmbTKdCoOJX4gvoU1vt8wurUmr7L83s4JvPt1wc865nB9Cp5ScU0LSC09JJuKIMB5RkrIskntoREXKozhjr_toRKRIo1gwdoiOvF8TQpKYZyP09QCb3L3nRb3FYFe51VDi0kANunNG49Y1LbjOgMfG4vuXqxnWzaZtvOnC6tPkwbU0FsAZuwxfDiZ-BXWNfed63fUuxL3ZxeT-EdvcNm0esnQN_hgdVHnt4eR3jtHz7PppehvNFzd308t5pDmVXSQLWtE0E0lSkVSKSiQEBJRJzmkqY1ZSGYdikseJlEmRMVFQWRbhWcqKCCb4GJ0NuaHIRw--U-umdzacVCzIRcyJzIKKDSrtGu8dVKp1JnDZKkrUDrAaAKsAWP0AVjKY-GDy7a48uL_of1zf7tN_Cg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2825543098</pqid></control><display><type>article</type><title>Remarkably enhanced dielectric properties in PVDF composites via engineering core@shell structured ZnO@PS nanoparticles</title><source>Springer Nature - Complete Springer Journals</source><creator>Yang, Yating ; Zhou, Wenying ; Zhou, Juanjuan ; Cao, Jing ; Liu, Jing ; Niu, Hongmei ; Liu, Dengfeng ; Feng, Aihong ; Li, Ying</creator><creatorcontrib>Yang, Yating ; Zhou, Wenying ; Zhou, Juanjuan ; Cao, Jing ; Liu, Jing ; Niu, Hongmei ; Liu, Dengfeng ; Feng, Aihong ; Li, Ying</creatorcontrib><description>In order to concurrently suppress the dielectric loss and enhance the breakdown strength (
E
b
) of raw zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) composites, in this study, the polystyrene (PS) encapsulated ZnO particles were fabricated via a suspension polymerization method, and further composited with PVDF to deliberately generate morphology-controllable high dielectric permittivity (
ε′
) and
E
b
but low-loss nanocomposites. The effects of the PS shell and its thickness on the dielectric properties of the ZnO/PVDF were investigated as a function of the filler concentration and frequency. Besides, the Havriliak-Negami (H-N) expression was used to fit the dielectric properties so as to theoretically comprehend the PS interlayer’s effect on the polarization and carrier migration mechanism in the nanocomposites. Research results verify that the ZnO@PS/PVDF nanocomposites present very low loss and conductivity when compared to the raw ZnO/PVDF thanks to the insulating PS shell’s ability to effectively prevent the ZnO particles from contacting with one another, thereby prohibiting the appearance of leakage current. And the filler’s homogeneous dispersion in PVDF is also enhanced owing to improved interfacial compatibility and interactions subsequently elevating the
E
b
of nanocomposites. Moreover, by adjusting the PS shell’ thickness, the dielectric properties of the nanocomposites can be efficiently tuned. Therefore, the developed ZnO@PS/PVDF nanocomposites with high-ε′ and
E
b
but low loss, present promising application prospects in microelectronic and electrical industries.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-023-10728-9</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Controllability ; Core-shell structure ; Dielectric breakdown ; Dielectric loss ; Dielectric properties ; Dielectric strength ; Fillers ; Insulation ; Interlayers ; Leakage current ; Materials Science ; Nanocomposites ; Nanoparticles ; Optical and Electronic Materials ; Polystyrene resins ; Polyvinylidene fluorides ; Suspension polymerization ; Thickness ; Zinc oxide ; Zinc oxides</subject><ispartof>Journal of materials science. Materials in electronics, 2023-06, Vol.34 (16), p.1314, Article 1314</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-9b1f178566f0795f560e5ed6a317942d1949579346996b825b19db96bd9f05253</citedby><cites>FETCH-LOGICAL-c319t-9b1f178566f0795f560e5ed6a317942d1949579346996b825b19db96bd9f05253</cites><orcidid>0000-0001-6481-2604</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-023-10728-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-023-10728-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Yang, Yating</creatorcontrib><creatorcontrib>Zhou, Wenying</creatorcontrib><creatorcontrib>Zhou, Juanjuan</creatorcontrib><creatorcontrib>Cao, Jing</creatorcontrib><creatorcontrib>Liu, Jing</creatorcontrib><creatorcontrib>Niu, Hongmei</creatorcontrib><creatorcontrib>Liu, Dengfeng</creatorcontrib><creatorcontrib>Feng, Aihong</creatorcontrib><creatorcontrib>Li, Ying</creatorcontrib><title>Remarkably enhanced dielectric properties in PVDF composites via engineering core@shell structured ZnO@PS nanoparticles</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>In order to concurrently suppress the dielectric loss and enhance the breakdown strength (
E
b
) of raw zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) composites, in this study, the polystyrene (PS) encapsulated ZnO particles were fabricated via a suspension polymerization method, and further composited with PVDF to deliberately generate morphology-controllable high dielectric permittivity (
ε′
) and
E
b
but low-loss nanocomposites. The effects of the PS shell and its thickness on the dielectric properties of the ZnO/PVDF were investigated as a function of the filler concentration and frequency. Besides, the Havriliak-Negami (H-N) expression was used to fit the dielectric properties so as to theoretically comprehend the PS interlayer’s effect on the polarization and carrier migration mechanism in the nanocomposites. Research results verify that the ZnO@PS/PVDF nanocomposites present very low loss and conductivity when compared to the raw ZnO/PVDF thanks to the insulating PS shell’s ability to effectively prevent the ZnO particles from contacting with one another, thereby prohibiting the appearance of leakage current. And the filler’s homogeneous dispersion in PVDF is also enhanced owing to improved interfacial compatibility and interactions subsequently elevating the
E
b
of nanocomposites. Moreover, by adjusting the PS shell’ thickness, the dielectric properties of the nanocomposites can be efficiently tuned. Therefore, the developed ZnO@PS/PVDF nanocomposites with high-ε′ and
E
b
but low loss, present promising application prospects in microelectronic and electrical industries.</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Controllability</subject><subject>Core-shell structure</subject><subject>Dielectric breakdown</subject><subject>Dielectric loss</subject><subject>Dielectric properties</subject><subject>Dielectric strength</subject><subject>Fillers</subject><subject>Insulation</subject><subject>Interlayers</subject><subject>Leakage current</subject><subject>Materials Science</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Optical and Electronic Materials</subject><subject>Polystyrene resins</subject><subject>Polyvinylidene fluorides</subject><subject>Suspension polymerization</subject><subject>Thickness</subject><subject>Zinc oxide</subject><subject>Zinc oxides</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kN1LwzAUxYMoOKf_gE8Bn6v5aNrmbTKdCoOJX4gvoU1vt8wurUmr7L83s4JvPt1wc865nB9Cp5ScU0LSC09JJuKIMB5RkrIskntoREXKozhjr_toRKRIo1gwdoiOvF8TQpKYZyP09QCb3L3nRb3FYFe51VDi0kANunNG49Y1LbjOgMfG4vuXqxnWzaZtvOnC6tPkwbU0FsAZuwxfDiZ-BXWNfed63fUuxL3ZxeT-EdvcNm0esnQN_hgdVHnt4eR3jtHz7PppehvNFzd308t5pDmVXSQLWtE0E0lSkVSKSiQEBJRJzmkqY1ZSGYdikseJlEmRMVFQWRbhWcqKCCb4GJ0NuaHIRw--U-umdzacVCzIRcyJzIKKDSrtGu8dVKp1JnDZKkrUDrAaAKsAWP0AVjKY-GDy7a48uL_of1zf7tN_Cg</recordid><startdate>20230601</startdate><enddate>20230601</enddate><creator>Yang, Yating</creator><creator>Zhou, Wenying</creator><creator>Zhou, Juanjuan</creator><creator>Cao, Jing</creator><creator>Liu, Jing</creator><creator>Niu, Hongmei</creator><creator>Liu, Dengfeng</creator><creator>Feng, Aihong</creator><creator>Li, Ying</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0001-6481-2604</orcidid></search><sort><creationdate>20230601</creationdate><title>Remarkably enhanced dielectric properties in PVDF composites via engineering core@shell structured ZnO@PS nanoparticles</title><author>Yang, Yating ; Zhou, Wenying ; Zhou, Juanjuan ; Cao, Jing ; Liu, Jing ; Niu, Hongmei ; Liu, Dengfeng ; Feng, Aihong ; Li, Ying</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-9b1f178566f0795f560e5ed6a317942d1949579346996b825b19db96bd9f05253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Controllability</topic><topic>Core-shell structure</topic><topic>Dielectric breakdown</topic><topic>Dielectric loss</topic><topic>Dielectric properties</topic><topic>Dielectric strength</topic><topic>Fillers</topic><topic>Insulation</topic><topic>Interlayers</topic><topic>Leakage current</topic><topic>Materials Science</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Optical and Electronic Materials</topic><topic>Polystyrene resins</topic><topic>Polyvinylidene fluorides</topic><topic>Suspension polymerization</topic><topic>Thickness</topic><topic>Zinc oxide</topic><topic>Zinc oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Yating</creatorcontrib><creatorcontrib>Zhou, Wenying</creatorcontrib><creatorcontrib>Zhou, Juanjuan</creatorcontrib><creatorcontrib>Cao, Jing</creatorcontrib><creatorcontrib>Liu, Jing</creatorcontrib><creatorcontrib>Niu, Hongmei</creatorcontrib><creatorcontrib>Liu, Dengfeng</creatorcontrib><creatorcontrib>Feng, Aihong</creatorcontrib><creatorcontrib>Li, Ying</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Yating</au><au>Zhou, Wenying</au><au>Zhou, Juanjuan</au><au>Cao, Jing</au><au>Liu, Jing</au><au>Niu, Hongmei</au><au>Liu, Dengfeng</au><au>Feng, Aihong</au><au>Li, Ying</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Remarkably enhanced dielectric properties in PVDF composites via engineering core@shell structured ZnO@PS nanoparticles</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2023-06-01</date><risdate>2023</risdate><volume>34</volume><issue>16</issue><spage>1314</spage><pages>1314-</pages><artnum>1314</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>In order to concurrently suppress the dielectric loss and enhance the breakdown strength (
E
b
) of raw zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) composites, in this study, the polystyrene (PS) encapsulated ZnO particles were fabricated via a suspension polymerization method, and further composited with PVDF to deliberately generate morphology-controllable high dielectric permittivity (
ε′
) and
E
b
but low-loss nanocomposites. The effects of the PS shell and its thickness on the dielectric properties of the ZnO/PVDF were investigated as a function of the filler concentration and frequency. Besides, the Havriliak-Negami (H-N) expression was used to fit the dielectric properties so as to theoretically comprehend the PS interlayer’s effect on the polarization and carrier migration mechanism in the nanocomposites. Research results verify that the ZnO@PS/PVDF nanocomposites present very low loss and conductivity when compared to the raw ZnO/PVDF thanks to the insulating PS shell’s ability to effectively prevent the ZnO particles from contacting with one another, thereby prohibiting the appearance of leakage current. And the filler’s homogeneous dispersion in PVDF is also enhanced owing to improved interfacial compatibility and interactions subsequently elevating the
E
b
of nanocomposites. Moreover, by adjusting the PS shell’ thickness, the dielectric properties of the nanocomposites can be efficiently tuned. Therefore, the developed ZnO@PS/PVDF nanocomposites with high-ε′ and
E
b
but low loss, present promising application prospects in microelectronic and electrical industries.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-023-10728-9</doi><orcidid>https://orcid.org/0000-0001-6481-2604</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2023-06, Vol.34 (16), p.1314, Article 1314 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_2825543098 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Characterization and Evaluation of Materials Chemistry and Materials Science Controllability Core-shell structure Dielectric breakdown Dielectric loss Dielectric properties Dielectric strength Fillers Insulation Interlayers Leakage current Materials Science Nanocomposites Nanoparticles Optical and Electronic Materials Polystyrene resins Polyvinylidene fluorides Suspension polymerization Thickness Zinc oxide Zinc oxides |
| title | Remarkably enhanced dielectric properties in PVDF composites via engineering core@shell structured ZnO@PS nanoparticles |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-23T04%3A56%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Remarkably%20enhanced%20dielectric%20properties%20in%20PVDF%20composites%20via%20engineering%20core@shell%20structured%20ZnO@PS%20nanoparticles&rft.jtitle=Journal%20of%20materials%20science.%20Materials%20in%20electronics&rft.au=Yang,%20Yating&rft.date=2023-06-01&rft.volume=34&rft.issue=16&rft.spage=1314&rft.pages=1314-&rft.artnum=1314&rft.issn=0957-4522&rft.eissn=1573-482X&rft_id=info:doi/10.1007/s10854-023-10728-9&rft_dat=%3Cproquest_cross%3E2825543098%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2825543098&rft_id=info:pmid/&rfr_iscdi=true |