Aminated Polyacrylonitrile Nanofiber Membrane for Effective In Situ Bivalent Cadmium Contaminated Kaolin Remediation

Cadmium is a harmful pollutant in soil. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin. The aminated PAN (APAN) nanofiber membrane has the potent...

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Veröffentlicht in:Clean : soil, air, water air, water, 2023-06, Vol.51 (6), p.n/a
Hauptverfasser: Jia, Botao, Yang, Ning, Zhang, Xianwen, Wang, Gan, Wang, Peichen, Zhao, Junqiang, Chen, Li, Zhao, Yiping
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container_issue 6
container_start_page
container_title Clean : soil, air, water
container_volume 51
creator Jia, Botao
Yang, Ning
Zhang, Xianwen
Wang, Gan
Wang, Peichen
Zhao, Junqiang
Chen, Li
Zhao, Yiping
description Cadmium is a harmful pollutant in soil. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin. The aminated PAN (APAN) nanofiber membrane has the potential to be used as permeable reactive barrier (PRB) combined with electrokinetics (EK) for the remediation of potentially toxic metal contaminated soil. Morphology and chemical characterizations of the nanofibers are analyzed by scanning electron microscopy and attenuated total reflectance Fourier transform infrared spectroscopy. The maximal adsorption capacities of Cd(II) on APAN nanofiber membrane, as calculated from the Langmuir model, are 51.8 mg g−1. In addition, the obtained APAN nanofiber membrane can also be facilely regenerated through the adsorption/desorption experiments (5 cycles). The APAN‐15 nanofiber membrane is used for the remediation of Cd(II) contaminated kaolin. The pH, water content, conductivity, and Cd(II) concentration of kaolin are detected after EK process. These results show that the APAN‐15 nanofiber membrane works as adsorption medium and can accelerate the migration rate of Cd(II) in kaolin, stabilize the pH, and water content. The APAN nanofiber membrane as PRB material can remove Cd(II) in soil effectively and remediate the soil via the EK/APAN process. Cadmium (Cd) is the most serious pollutant of soil in China. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification. The aminated PAN nanofiber membrane has the potential to be used as permeable reactive barrier combined with electrokinetics for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin.
doi_str_mv 10.1002/clen.202200058
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Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin. The aminated PAN (APAN) nanofiber membrane has the potential to be used as permeable reactive barrier (PRB) combined with electrokinetics (EK) for the remediation of potentially toxic metal contaminated soil. Morphology and chemical characterizations of the nanofibers are analyzed by scanning electron microscopy and attenuated total reflectance Fourier transform infrared spectroscopy. The maximal adsorption capacities of Cd(II) on APAN nanofiber membrane, as calculated from the Langmuir model, are 51.8 mg g−1. In addition, the obtained APAN nanofiber membrane can also be facilely regenerated through the adsorption/desorption experiments (5 cycles). The APAN‐15 nanofiber membrane is used for the remediation of Cd(II) contaminated kaolin. The pH, water content, conductivity, and Cd(II) concentration of kaolin are detected after EK process. These results show that the APAN‐15 nanofiber membrane works as adsorption medium and can accelerate the migration rate of Cd(II) in kaolin, stabilize the pH, and water content. The APAN nanofiber membrane as PRB material can remove Cd(II) in soil effectively and remediate the soil via the EK/APAN process. Cadmium (Cd) is the most serious pollutant of soil in China. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification. The aminated PAN nanofiber membrane has the potential to be used as permeable reactive barrier combined with electrokinetics for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin.</description><identifier>ISSN: 1863-0650</identifier><identifier>EISSN: 1863-0669</identifier><identifier>DOI: 10.1002/clen.202200058</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Adsorption ; aminated nanofiber membranes ; Amination ; Analytical methods ; Cadmium ; Electrokinetics ; Electron microscopy ; electrostatic spinning ; Fourier transforms ; Heavy metals ; Infrared spectroscopy ; Kaolin ; Membranes ; Moisture content ; Nanofibers ; Permeable reactive barriers ; Pollution prevention ; Polyacrylonitrile ; potentially toxic metals ; Reflectance ; Remediation ; Scanning electron microscopy ; Soil ; Soil chemistry ; Soil contamination ; Soil permeability ; Soil pollution ; Soil remediation ; Soils ; Water content</subject><ispartof>Clean : soil, air, water, 2023-06, Vol.51 (6), p.n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2728-c2678cfa4c24b608c80a127bf95c772c70c24e7a2a5079d199d89153d698dc943</cites><orcidid>0000-0003-3232-7940</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fclen.202200058$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fclen.202200058$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Jia, Botao</creatorcontrib><creatorcontrib>Yang, Ning</creatorcontrib><creatorcontrib>Zhang, Xianwen</creatorcontrib><creatorcontrib>Wang, Gan</creatorcontrib><creatorcontrib>Wang, Peichen</creatorcontrib><creatorcontrib>Zhao, Junqiang</creatorcontrib><creatorcontrib>Chen, Li</creatorcontrib><creatorcontrib>Zhao, Yiping</creatorcontrib><title>Aminated Polyacrylonitrile Nanofiber Membrane for Effective In Situ Bivalent Cadmium Contaminated Kaolin Remediation</title><title>Clean : soil, air, water</title><description>Cadmium is a harmful pollutant in soil. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin. The aminated PAN (APAN) nanofiber membrane has the potential to be used as permeable reactive barrier (PRB) combined with electrokinetics (EK) for the remediation of potentially toxic metal contaminated soil. Morphology and chemical characterizations of the nanofibers are analyzed by scanning electron microscopy and attenuated total reflectance Fourier transform infrared spectroscopy. The maximal adsorption capacities of Cd(II) on APAN nanofiber membrane, as calculated from the Langmuir model, are 51.8 mg g−1. In addition, the obtained APAN nanofiber membrane can also be facilely regenerated through the adsorption/desorption experiments (5 cycles). The APAN‐15 nanofiber membrane is used for the remediation of Cd(II) contaminated kaolin. The pH, water content, conductivity, and Cd(II) concentration of kaolin are detected after EK process. These results show that the APAN‐15 nanofiber membrane works as adsorption medium and can accelerate the migration rate of Cd(II) in kaolin, stabilize the pH, and water content. The APAN nanofiber membrane as PRB material can remove Cd(II) in soil effectively and remediate the soil via the EK/APAN process. Cadmium (Cd) is the most serious pollutant of soil in China. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification. 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Fisheries Abstracts (ASFA) 3: Aquatic Pollution &amp; Environmental Quality</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><jtitle>Clean : soil, air, water</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia, Botao</au><au>Yang, Ning</au><au>Zhang, Xianwen</au><au>Wang, Gan</au><au>Wang, Peichen</au><au>Zhao, Junqiang</au><au>Chen, Li</au><au>Zhao, Yiping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aminated Polyacrylonitrile Nanofiber Membrane for Effective In Situ Bivalent Cadmium Contaminated Kaolin Remediation</atitle><jtitle>Clean : soil, air, water</jtitle><date>2023-06</date><risdate>2023</risdate><volume>51</volume><issue>6</issue><epage>n/a</epage><issn>1863-0650</issn><eissn>1863-0669</eissn><abstract>Cadmium is a harmful pollutant in soil. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin. The aminated PAN (APAN) nanofiber membrane has the potential to be used as permeable reactive barrier (PRB) combined with electrokinetics (EK) for the remediation of potentially toxic metal contaminated soil. Morphology and chemical characterizations of the nanofibers are analyzed by scanning electron microscopy and attenuated total reflectance Fourier transform infrared spectroscopy. The maximal adsorption capacities of Cd(II) on APAN nanofiber membrane, as calculated from the Langmuir model, are 51.8 mg g−1. In addition, the obtained APAN nanofiber membrane can also be facilely regenerated through the adsorption/desorption experiments (5 cycles). The APAN‐15 nanofiber membrane is used for the remediation of Cd(II) contaminated kaolin. The pH, water content, conductivity, and Cd(II) concentration of kaolin are detected after EK process. These results show that the APAN‐15 nanofiber membrane works as adsorption medium and can accelerate the migration rate of Cd(II) in kaolin, stabilize the pH, and water content. The APAN nanofiber membrane as PRB material can remove Cd(II) in soil effectively and remediate the soil via the EK/APAN process. Cadmium (Cd) is the most serious pollutant of soil in China. Here, an aminated polyacrylonitrile (PAN) nanofiber membrane is obtained by electrospinning and amination modification. The aminated PAN nanofiber membrane has the potential to be used as permeable reactive barrier combined with electrokinetics for effective in situ remediation of bivalent cadmium (Cd(II)) contaminated kaolin.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/clen.202200058</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-3232-7940</orcidid></addata></record>
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subjects Adsorption
aminated nanofiber membranes
Amination
Analytical methods
Cadmium
Electrokinetics
Electron microscopy
electrostatic spinning
Fourier transforms
Heavy metals
Infrared spectroscopy
Kaolin
Membranes
Moisture content
Nanofibers
Permeable reactive barriers
Pollution prevention
Polyacrylonitrile
potentially toxic metals
Reflectance
Remediation
Scanning electron microscopy
Soil
Soil chemistry
Soil contamination
Soil permeability
Soil pollution
Soil remediation
Soils
Water content
title Aminated Polyacrylonitrile Nanofiber Membrane for Effective In Situ Bivalent Cadmium Contaminated Kaolin Remediation
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