A novel green amino acid derivative hydrogel with multi-stimulus responsiveness
Even though amino acid derivatives are always used as the building blocks to construct gels in supramolecular chemistry, there is still no report about N -alpha-Fmoc- L -valine (Fmoc-V) hydrogel induced by metal ions. Herein, a novel green Fmoc-V hydrogel with stimuli responsiveness was reported. A...
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| Veröffentlicht in: | Colloid and polymer science 2023-06, Vol.301 (6), p.569-576 |
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| container_title | Colloid and polymer science |
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| creator | Ma, Mingfang Wang, Tongyu Liu, Renrui Jiang, Wenwen Niu, Zhaocan Bai, Mingjuan Wu, Weiwei Hao, Aiyou Shang, Wenqing |
| description | Even though amino acid derivatives are always used as the building blocks to construct gels in supramolecular chemistry, there is still no report about
N
-alpha-Fmoc-
L
-valine (Fmoc-V) hydrogel induced by metal ions. Herein, a novel green Fmoc-V hydrogel with stimuli responsiveness was reported. A total of eight metal ions are applied to fabricate gels, but only Zn
2+
and Cu
2+
can induce Fmoc-V hydrogel formation. The formation of Fmoc-V hydrogel is verified by rheometer detection. FT-IR, UV–vis, and SAXS detections are used to study the formation mechanism of Fmoc-V hydrogel, implying hydrogen bond, metal–ligand, and π-π stacking interactions are the driving forces to gel formation. Moreover, this novel green hydrogel with high electrical conductivity performs multiple stimulus responsiveness to temperature, metal ion, and acid, illustrating its great potential applications in various areas. |
| doi_str_mv | 10.1007/s00396-023-05095-0 |
| format | Article |
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N
-alpha-Fmoc-
L
-valine (Fmoc-V) hydrogel induced by metal ions. Herein, a novel green Fmoc-V hydrogel with stimuli responsiveness was reported. A total of eight metal ions are applied to fabricate gels, but only Zn
2+
and Cu
2+
can induce Fmoc-V hydrogel formation. The formation of Fmoc-V hydrogel is verified by rheometer detection. FT-IR, UV–vis, and SAXS detections are used to study the formation mechanism of Fmoc-V hydrogel, implying hydrogen bond, metal–ligand, and π-π stacking interactions are the driving forces to gel formation. Moreover, this novel green hydrogel with high electrical conductivity performs multiple stimulus responsiveness to temperature, metal ion, and acid, illustrating its great potential applications in various areas.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-023-05095-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Amino acids ; Aqueous solutions ; Behavior ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Electrical resistivity ; Food Science ; Hydrogels ; Hydrogen bonds ; Ions ; Ligands ; Molecular weight ; Nanotechnology and Microengineering ; Original Contribution ; Physical Chemistry ; Polymer Sciences ; Polymers ; Rheology ; Scanning electron microscopy ; Sodium ; Soft and Granular Matter ; Valine</subject><ispartof>Colloid and polymer science, 2023-06, Vol.301 (6), p.569-576</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-122417ad72dedf3bd2cd413366fcc84da7f69bccb01b920d97a55ff486a551ac3</citedby><cites>FETCH-LOGICAL-c319t-122417ad72dedf3bd2cd413366fcc84da7f69bccb01b920d97a55ff486a551ac3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-023-05095-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-023-05095-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Ma, Mingfang</creatorcontrib><creatorcontrib>Wang, Tongyu</creatorcontrib><creatorcontrib>Liu, Renrui</creatorcontrib><creatorcontrib>Jiang, Wenwen</creatorcontrib><creatorcontrib>Niu, Zhaocan</creatorcontrib><creatorcontrib>Bai, Mingjuan</creatorcontrib><creatorcontrib>Wu, Weiwei</creatorcontrib><creatorcontrib>Hao, Aiyou</creatorcontrib><creatorcontrib>Shang, Wenqing</creatorcontrib><title>A novel green amino acid derivative hydrogel with multi-stimulus responsiveness</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Even though amino acid derivatives are always used as the building blocks to construct gels in supramolecular chemistry, there is still no report about
N
-alpha-Fmoc-
L
-valine (Fmoc-V) hydrogel induced by metal ions. Herein, a novel green Fmoc-V hydrogel with stimuli responsiveness was reported. A total of eight metal ions are applied to fabricate gels, but only Zn
2+
and Cu
2+
can induce Fmoc-V hydrogel formation. The formation of Fmoc-V hydrogel is verified by rheometer detection. FT-IR, UV–vis, and SAXS detections are used to study the formation mechanism of Fmoc-V hydrogel, implying hydrogen bond, metal–ligand, and π-π stacking interactions are the driving forces to gel formation. Moreover, this novel green hydrogel with high electrical conductivity performs multiple stimulus responsiveness to temperature, metal ion, and acid, illustrating its great potential applications in various areas.</description><subject>Amino acids</subject><subject>Aqueous solutions</subject><subject>Behavior</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Electrical resistivity</subject><subject>Food Science</subject><subject>Hydrogels</subject><subject>Hydrogen bonds</subject><subject>Ions</subject><subject>Ligands</subject><subject>Molecular weight</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Contribution</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Rheology</subject><subject>Scanning electron microscopy</subject><subject>Sodium</subject><subject>Soft and Granular Matter</subject><subject>Valine</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtLAzEUhYMoWKt_wFXAdfTmMUmzLMUXFLpRcBcySaZNaWdqMlPx3xsdwZ2rcxffORc-hK4p3FIAdZcBuJYEGCdQga4InKAJFbwitOLyFE2AAycC2Ns5ush5CwBCSzlBqzluu2PY4XUKocV2H9sOWxc99iHFo-3jMeDNp0_dukAfsd_g_bDrI8l9LMeQcQr50LW5cG3I-RKdNXaXw9VvTtHrw_3L4oksV4_Pi_mSOE51TyhjgirrFfPBN7z2zHlBOZeycW4mvFWN1LVzNdBaM_Ba2apqGjGTJal1fIpuxt1D6t6HkHuz7YbUlpeGzRhVgjMlC8VGyqUu5xQac0hxb9OnoWC-xZlRnCnizI84A6XEx1IucLsO6W_6n9YX3dByHQ</recordid><startdate>20230601</startdate><enddate>20230601</enddate><creator>Ma, Mingfang</creator><creator>Wang, Tongyu</creator><creator>Liu, Renrui</creator><creator>Jiang, Wenwen</creator><creator>Niu, Zhaocan</creator><creator>Bai, Mingjuan</creator><creator>Wu, Weiwei</creator><creator>Hao, Aiyou</creator><creator>Shang, Wenqing</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20230601</creationdate><title>A novel green amino acid derivative hydrogel with multi-stimulus responsiveness</title><author>Ma, Mingfang ; Wang, Tongyu ; Liu, Renrui ; Jiang, Wenwen ; Niu, Zhaocan ; Bai, Mingjuan ; Wu, Weiwei ; Hao, Aiyou ; Shang, Wenqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-122417ad72dedf3bd2cd413366fcc84da7f69bccb01b920d97a55ff486a551ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Amino acids</topic><topic>Aqueous solutions</topic><topic>Behavior</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Electrical resistivity</topic><topic>Food Science</topic><topic>Hydrogels</topic><topic>Hydrogen bonds</topic><topic>Ions</topic><topic>Ligands</topic><topic>Molecular weight</topic><topic>Nanotechnology and Microengineering</topic><topic>Original Contribution</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Rheology</topic><topic>Scanning electron microscopy</topic><topic>Sodium</topic><topic>Soft and Granular Matter</topic><topic>Valine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Mingfang</creatorcontrib><creatorcontrib>Wang, Tongyu</creatorcontrib><creatorcontrib>Liu, Renrui</creatorcontrib><creatorcontrib>Jiang, Wenwen</creatorcontrib><creatorcontrib>Niu, Zhaocan</creatorcontrib><creatorcontrib>Bai, Mingjuan</creatorcontrib><creatorcontrib>Wu, Weiwei</creatorcontrib><creatorcontrib>Hao, Aiyou</creatorcontrib><creatorcontrib>Shang, Wenqing</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Mingfang</au><au>Wang, Tongyu</au><au>Liu, Renrui</au><au>Jiang, Wenwen</au><au>Niu, Zhaocan</au><au>Bai, Mingjuan</au><au>Wu, Weiwei</au><au>Hao, Aiyou</au><au>Shang, Wenqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel green amino acid derivative hydrogel with multi-stimulus responsiveness</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2023-06-01</date><risdate>2023</risdate><volume>301</volume><issue>6</issue><spage>569</spage><epage>576</epage><pages>569-576</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><abstract>Even though amino acid derivatives are always used as the building blocks to construct gels in supramolecular chemistry, there is still no report about
N
-alpha-Fmoc-
L
-valine (Fmoc-V) hydrogel induced by metal ions. Herein, a novel green Fmoc-V hydrogel with stimuli responsiveness was reported. A total of eight metal ions are applied to fabricate gels, but only Zn
2+
and Cu
2+
can induce Fmoc-V hydrogel formation. The formation of Fmoc-V hydrogel is verified by rheometer detection. FT-IR, UV–vis, and SAXS detections are used to study the formation mechanism of Fmoc-V hydrogel, implying hydrogen bond, metal–ligand, and π-π stacking interactions are the driving forces to gel formation. Moreover, this novel green hydrogel with high electrical conductivity performs multiple stimulus responsiveness to temperature, metal ion, and acid, illustrating its great potential applications in various areas.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00396-023-05095-0</doi><tpages>8</tpages></addata></record> |
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| subjects | Amino acids Aqueous solutions Behavior Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Electrical resistivity Food Science Hydrogels Hydrogen bonds Ions Ligands Molecular weight Nanotechnology and Microengineering Original Contribution Physical Chemistry Polymer Sciences Polymers Rheology Scanning electron microscopy Sodium Soft and Granular Matter Valine |
| title | A novel green amino acid derivative hydrogel with multi-stimulus responsiveness |
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