Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids
New heteroleptic metal-organic frameworks of lanthanides, units of which contain anionic organic ligands of two types, are prepared by the solvothermal synthesis in N , N -dimethylformamide (DMF). The cross-linked coordination polymer [Ho 2 (CA) 2 (Bdc)·4DMF] ( I ) and two scaffold derivatives [La 2...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2023-05, Vol.49 (5), p.276-285 |
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| container_end_page | 285 |
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| container_title | Russian journal of coordination chemistry |
| container_volume | 49 |
| creator | Trofimova, O. Yu Maleeva, A. V. Arsen’eva, K. V. Klimashevskaya, A. V. Cherkasov, A. V. Piskunov, A. V. |
| description | New heteroleptic metal-organic frameworks of lanthanides, units of which contain anionic organic ligands of two types, are prepared by the solvothermal synthesis in
N
,
N
-dimethylformamide (DMF). The cross-linked coordination polymer [Ho
2
(CA)
2
(Bdc)·4DMF] (
I
) and two scaffold derivatives [La
2
(pQ)
2
(Bpdc)·4DMF] (
II
) and [Ce
2
(CA)(Bdc)
2
·4DMF]·2DMF (
III
·2DMF), where CA is chloranilic acid dianion, pQ is 2,5-dihydroxy-3,6-di-
tert
-butyl-
para
-benzoquinone dianion, Bdc is terephthalic acid dianion, and Bpdc is 4,4'-biphenyldicarboxylic acid dianion, are synthesized. The structures of compounds
I
,
II
, and
III
·2DMF are studied by X-ray diffraction (XRD) (CIF file CCDC nos. 2212230, 2212231, and 2212232, respectively). |
| doi_str_mv | 10.1134/S1070328423600183 |
| format | Article |
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N
,
N
-dimethylformamide (DMF). The cross-linked coordination polymer [Ho
2
(CA)
2
(Bdc)·4DMF] (
I
) and two scaffold derivatives [La
2
(pQ)
2
(Bpdc)·4DMF] (
II
) and [Ce
2
(CA)(Bdc)
2
·4DMF]·2DMF (
III
·2DMF), where CA is chloranilic acid dianion, pQ is 2,5-dihydroxy-3,6-di-
tert
-butyl-
para
-benzoquinone dianion, Bdc is terephthalic acid dianion, and Bpdc is 4,4'-biphenyldicarboxylic acid dianion, are synthesized. The structures of compounds
I
,
II
, and
III
·2DMF are studied by X-ray diffraction (XRD) (CIF file CCDC nos. 2212230, 2212231, and 2212232, respectively).</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328423600183</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Benzoquinone ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Dicarboxylic acids ; Dimethylformamide ; Inorganic Chemistry ; Lanthanides ; Ligands ; Metal-organic frameworks ; Physical Chemistry ; Terephthalic acid</subject><ispartof>Russian journal of coordination chemistry, 2023-05, Vol.49 (5), p.276-285</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2023, Vol. 49, No. 5, pp. 276–285. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Koordinatsionnaya Khimiya, 2023, Vol. 49, No. 5, pp. 278–289.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-d6c833ec6ad0fd17c04659b061e9a99db062a023ada18d1d70f1e8bfc958d6633</citedby><cites>FETCH-LOGICAL-c316t-d6c833ec6ad0fd17c04659b061e9a99db062a023ada18d1d70f1e8bfc958d6633</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328423600183$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328423600183$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Trofimova, O. Yu</creatorcontrib><creatorcontrib>Maleeva, A. V.</creatorcontrib><creatorcontrib>Arsen’eva, K. V.</creatorcontrib><creatorcontrib>Klimashevskaya, A. V.</creatorcontrib><creatorcontrib>Cherkasov, A. V.</creatorcontrib><creatorcontrib>Piskunov, A. V.</creatorcontrib><title>Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>New heteroleptic metal-organic frameworks of lanthanides, units of which contain anionic organic ligands of two types, are prepared by the solvothermal synthesis in
N
,
N
-dimethylformamide (DMF). The cross-linked coordination polymer [Ho
2
(CA)
2
(Bdc)·4DMF] (
I
) and two scaffold derivatives [La
2
(pQ)
2
(Bpdc)·4DMF] (
II
) and [Ce
2
(CA)(Bdc)
2
·4DMF]·2DMF (
III
·2DMF), where CA is chloranilic acid dianion, pQ is 2,5-dihydroxy-3,6-di-
tert
-butyl-
para
-benzoquinone dianion, Bdc is terephthalic acid dianion, and Bpdc is 4,4'-biphenyldicarboxylic acid dianion, are synthesized. The structures of compounds
I
,
II
, and
III
·2DMF are studied by X-ray diffraction (XRD) (CIF file CCDC nos. 2212230, 2212231, and 2212232, respectively).</description><subject>Anions</subject><subject>Benzoquinone</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Dicarboxylic acids</subject><subject>Dimethylformamide</subject><subject>Inorganic Chemistry</subject><subject>Lanthanides</subject><subject>Ligands</subject><subject>Metal-organic frameworks</subject><subject>Physical Chemistry</subject><subject>Terephthalic acid</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM1OAjEUhRujiYg-gLsmbjRhtHcKpbNEFDEZw0JcT0p7BwbH6dgOUbY-kY_iI1nAxIVxdf_Od25yCDkFdgnAu1ePwPqMx7Ibc8EYSL5HWiCYjDgHuR_6cI4290Ny5P0ySBjrJS3yMcYGnS2xbgpNH7BRZTRxc1WFaeTUC75Z9-ypzWmqqmYR9gY9PU-_Pjt0iB2qKkPH9oJeK4-G2oqmRYDNlmgWSAdVUaoG6XRd41Z8U2jlZvZ9XYYPA10Yf0wOclV6PPmpbfI0up0Ox1E6ubsfDtJIcxBNZISWnKMWyrDcQF-zruglMyYAE5UkJnSxYjFXRoE0YPosB5SzXCc9aYTgvE3Odr61s68r9E22tCtXhZdZLGMQIumHCNsEdirtrPcO86x2xYty6wxYtok6-xN1YOId44O2mqP7df4f-gZ25X_W</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Trofimova, O. Yu</creator><creator>Maleeva, A. V.</creator><creator>Arsen’eva, K. V.</creator><creator>Klimashevskaya, A. V.</creator><creator>Cherkasov, A. V.</creator><creator>Piskunov, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230501</creationdate><title>Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids</title><author>Trofimova, O. Yu ; Maleeva, A. V. ; Arsen’eva, K. V. ; Klimashevskaya, A. V. ; Cherkasov, A. V. ; Piskunov, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-d6c833ec6ad0fd17c04659b061e9a99db062a023ada18d1d70f1e8bfc958d6633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anions</topic><topic>Benzoquinone</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Dicarboxylic acids</topic><topic>Dimethylformamide</topic><topic>Inorganic Chemistry</topic><topic>Lanthanides</topic><topic>Ligands</topic><topic>Metal-organic frameworks</topic><topic>Physical Chemistry</topic><topic>Terephthalic acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Trofimova, O. Yu</creatorcontrib><creatorcontrib>Maleeva, A. V.</creatorcontrib><creatorcontrib>Arsen’eva, K. V.</creatorcontrib><creatorcontrib>Klimashevskaya, A. V.</creatorcontrib><creatorcontrib>Cherkasov, A. V.</creatorcontrib><creatorcontrib>Piskunov, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Trofimova, O. Yu</au><au>Maleeva, A. V.</au><au>Arsen’eva, K. V.</au><au>Klimashevskaya, A. V.</au><au>Cherkasov, A. V.</au><au>Piskunov, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>49</volume><issue>5</issue><spage>276</spage><epage>285</epage><pages>276-285</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>New heteroleptic metal-organic frameworks of lanthanides, units of which contain anionic organic ligands of two types, are prepared by the solvothermal synthesis in
N
,
N
-dimethylformamide (DMF). The cross-linked coordination polymer [Ho
2
(CA)
2
(Bdc)·4DMF] (
I
) and two scaffold derivatives [La
2
(pQ)
2
(Bpdc)·4DMF] (
II
) and [Ce
2
(CA)(Bdc)
2
·4DMF]·2DMF (
III
·2DMF), where CA is chloranilic acid dianion, pQ is 2,5-dihydroxy-3,6-di-
tert
-butyl-
para
-benzoquinone dianion, Bdc is terephthalic acid dianion, and Bpdc is 4,4'-biphenyldicarboxylic acid dianion, are synthesized. The structures of compounds
I
,
II
, and
III
·2DMF are studied by X-ray diffraction (XRD) (CIF file CCDC nos. 2212230, 2212231, and 2212232, respectively).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328423600183</doi><tpages>10</tpages></addata></record> |
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| issn | 1070-3284 1608-3318 |
| language | eng |
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| subjects | Anions Benzoquinone Chemistry Chemistry and Materials Science Coordination polymers Dicarboxylic acids Dimethylformamide Inorganic Chemistry Lanthanides Ligands Metal-organic frameworks Physical Chemistry Terephthalic acid |
| title | Heteroleptic Metal-Organic Frameworks of Lanthanides (Lа, Ce, and Ho) Based on Ligands of the Anilate Type and Dicarboxylic Acids |
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