Photocatalytic Metal Hydride Hydrogen Atom Transfer Mediated Allene Functionalization by Cobalt and Titanium Dual Catalysis

Catalytic metal hydride hydrogen atom transfer (MHAT) reactions have proven to be a powerful method for alkene functionalization. This work reports the discovery of Co‐porphines as highly efficient MHAT catalysts with a loading of only 0.01 mol % for unprecedented chemoselective allene functionaliza...

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Veröffentlicht in:	Angewandte Chemie 2023-06, Vol.135 (24), p.n/a
Hauptverfasser:	Yan, Huaipu, Liao, Qian, Chen, Yuqing, Gurzadyan, Gagik G., Lu, Binghui, Wu, Chao, Shi, Lei
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Allene Allyl compounds Allylic Compounds Bimetals Carbonyl compounds Carbonyls Catalysis Catalysts Chemical reactions Chemistry Cobalt Hydrogen Hydrogen atoms Metal hydrides Photoredox Catalysis Porphines Radicals Reaction Mechanism Stereoselectivity Titanium
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