Expanding the Chemical Space of Non‐Proteinogenic N4‐Substituted Asparagine: Racemic, Enantioenriched, and Deuterated Derivatives

A site‐selective carbamoylation strategy to access non‐proteinogenic N4‐modified asparagines has been described. The protocol is characterized by mild reaction conditions, high functional group compatibility, and a wide diversity of functionalized carbamoyl radicals making possible the access to pep...

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Veröffentlicht in:	European journal of organic chemistry 2023-06, Vol.26 (21), p.n/a
Hauptverfasser:	Pissinati, Emanuele F., Delgado, José A. C., Moro, Pedro A. M., Correia, José T. M., Berlinck, Roberto G. S., Paixão, Márcio W.
Format:	Artikel
Sprache:	eng
Schlagworte:	carbamoyl radical dehydroalanine Deuteration Functional groups non-proteinogenic N4-substituted asparagines Peptides photocatalysis
Online-Zugang:	Volltext
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