Bimetallic 3D hollow-nanoshell FeCo-oxynitride/N and S co-doped carbon nanotubes as a robust bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries
Herein, a novel 3D hierarchically hollow-shell porous structure of iron cobalt oxynitride anchored nitrogen and sulfur-doped bamboo-like carbon nanotubes (FeCo 2 ON/NSCNTs) are fabricated using a pyrolysis of Fe doped-ZIF-8/67@S-doped g-C 3 N 4 . The strong synergistic effects between hollow FeCo 2...
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| Veröffentlicht in: | Journal of materials science 2023-06, Vol.58 (21), p.8889-8907 |
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| creator | Akbarian, Parisa Kheirmand, Mehdi Asadi, Aliakbar |
| description | Herein, a novel 3D hierarchically hollow-shell porous structure of iron cobalt oxynitride anchored nitrogen and sulfur-doped bamboo-like carbon nanotubes (FeCo
2
ON/NSCNTs) are fabricated using a pyrolysis of Fe doped-ZIF-8/67@S-doped g-C
3
N
4
. The strong synergistic effects between hollow FeCo
2
ON, NC nanoshells, and NSCNTs lead to accelerating the mass and electron transfer between the active sites which is favorable for electrochemical activities. The introduction of Fe into the nanohybrid and nitrogen/sulfur atoms doped on CNTs leading to increase electrical conductivity and decrease the activation energy barrier of the rate-determining step. The electrocatalyst exhibit a more half-wave potential of 0.903 V vs. RHE, outperform to Pt/C. Moreover, the low overpotential of 268 mV at 10 mA cm
−1
is attained for FeCo
2
ON/NSCNTs. Its superiority as the air-electrode electrocatalyst corroborates in a Zn–air battery with a higher power density and specific capacity (235.4 mW cm
−2
, and 781 mAh g
−1
, respectively) than Pt/C + RuO
2
(184.6 mW cm
−2
, and 701 mAh g
−1
).
Graphical abstract |
| doi_str_mv | 10.1007/s10853-023-08551-y |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2820820261</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A751273219</galeid><sourcerecordid>A751273219</sourcerecordid><originalsourceid>FETCH-LOGICAL-c392t-de25462067b2f80075e3832e7402d6c3092ed345759df249aee6cf874b77003b3</originalsourceid><addsrcrecordid>eNp9kc9qHSEUh4fSQm_TvkBWQlddmPhnHGeW6W3SBkILSbrJRhznzFyDV2_VoZnX6ZPWZAIlm-IRQb7vePBXVceUnFBC5GmipBUcE1Z2KwTFy6tqQ4XkuG4Jf11tCGEMs7qhb6t3Kd0TQoRkdFP9-Wz3kLVz1iD-Be2Cc-E39tqHtAPn0AVsAw4Pi7c52gFOvyPtB3SDTMBDOMCAjI598OjRyHMPCelSKIZ-Thn1dpy9yTZ47VDpMoFH4MDkGIwury6FGUNEEcxOxwl07wDdeaxtRL3OGaKF9L56M2qX4MPzeVT9vDi_3X7DVz--Xm7PrrDhHct4ACbqhpFG9mxsy6cI4C1nIGvChsZw0jEYeC2k6IaR1Z0GaMzYyrqXkhDe86Pq49r3EMOvGVJW92GOZfKkWMtIKdbQQp2s1KQdKOvHkKM2ZQ2wtyZ4GG25P5OCMskZ7Yrw6YVQmAwPedJzSury5voly1bWxJBShFEdot3ruChK1GPQag1alaDVU9BqKRJfpVRgP0H8N_d_rL8JG6y_</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2820820261</pqid></control><display><type>article</type><title>Bimetallic 3D hollow-nanoshell FeCo-oxynitride/N and S co-doped carbon nanotubes as a robust bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries</title><source>SpringerLink</source><creator>Akbarian, Parisa ; Kheirmand, Mehdi ; Asadi, Aliakbar</creator><creatorcontrib>Akbarian, Parisa ; Kheirmand, Mehdi ; Asadi, Aliakbar</creatorcontrib><description>Herein, a novel 3D hierarchically hollow-shell porous structure of iron cobalt oxynitride anchored nitrogen and sulfur-doped bamboo-like carbon nanotubes (FeCo
2
ON/NSCNTs) are fabricated using a pyrolysis of Fe doped-ZIF-8/67@S-doped g-C
3
N
4
. The strong synergistic effects between hollow FeCo
2
ON, NC nanoshells, and NSCNTs lead to accelerating the mass and electron transfer between the active sites which is favorable for electrochemical activities. The introduction of Fe into the nanohybrid and nitrogen/sulfur atoms doped on CNTs leading to increase electrical conductivity and decrease the activation energy barrier of the rate-determining step. The electrocatalyst exhibit a more half-wave potential of 0.903 V vs. RHE, outperform to Pt/C. Moreover, the low overpotential of 268 mV at 10 mA cm
−1
is attained for FeCo
2
ON/NSCNTs. Its superiority as the air-electrode electrocatalyst corroborates in a Zn–air battery with a higher power density and specific capacity (235.4 mW cm
−2
, and 781 mAh g
−1
, respectively) than Pt/C + RuO
2
(184.6 mW cm
−2
, and 701 mAh g
−1
).
Graphical abstract</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-023-08551-y</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Activation energy ; Bamboo ; Batteries ; Bimetals ; Carbon ; Carbon nanotubes ; Carbon nitride ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystallography and Scattering Methods ; Electric properties ; Electrical conductivity ; Electrical resistivity ; Electrocatalysts ; Electron transfer ; Electron transport ; Energy ; Energy Materials ; Iron ; Materials Science ; Metal air batteries ; Metals ; Nanotubes ; Nitrates ; Nitrogen ; Oxynitrides ; Polymer Sciences ; Pyrolysis ; Rechargeable batteries ; Solid Mechanics ; Sulfur ; Synergistic effect ; Zinc ; Zinc compounds ; Zinc-oxygen batteries</subject><ispartof>Journal of materials science, 2023-06, Vol.58 (21), p.8889-8907</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-de25462067b2f80075e3832e7402d6c3092ed345759df249aee6cf874b77003b3</citedby><cites>FETCH-LOGICAL-c392t-de25462067b2f80075e3832e7402d6c3092ed345759df249aee6cf874b77003b3</cites><orcidid>0000-0002-6469-7797</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10853-023-08551-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10853-023-08551-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27933,27934,41497,42566,51328</link.rule.ids></links><search><creatorcontrib>Akbarian, Parisa</creatorcontrib><creatorcontrib>Kheirmand, Mehdi</creatorcontrib><creatorcontrib>Asadi, Aliakbar</creatorcontrib><title>Bimetallic 3D hollow-nanoshell FeCo-oxynitride/N and S co-doped carbon nanotubes as a robust bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Herein, a novel 3D hierarchically hollow-shell porous structure of iron cobalt oxynitride anchored nitrogen and sulfur-doped bamboo-like carbon nanotubes (FeCo
2
ON/NSCNTs) are fabricated using a pyrolysis of Fe doped-ZIF-8/67@S-doped g-C
3
N
4
. The strong synergistic effects between hollow FeCo
2
ON, NC nanoshells, and NSCNTs lead to accelerating the mass and electron transfer between the active sites which is favorable for electrochemical activities. The introduction of Fe into the nanohybrid and nitrogen/sulfur atoms doped on CNTs leading to increase electrical conductivity and decrease the activation energy barrier of the rate-determining step. The electrocatalyst exhibit a more half-wave potential of 0.903 V vs. RHE, outperform to Pt/C. Moreover, the low overpotential of 268 mV at 10 mA cm
−1
is attained for FeCo
2
ON/NSCNTs. Its superiority as the air-electrode electrocatalyst corroborates in a Zn–air battery with a higher power density and specific capacity (235.4 mW cm
−2
, and 781 mAh g
−1
, respectively) than Pt/C + RuO
2
(184.6 mW cm
−2
, and 701 mAh g
−1
).
Graphical abstract</description><subject>Activation energy</subject><subject>Bamboo</subject><subject>Batteries</subject><subject>Bimetals</subject><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Carbon nitride</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystallography and Scattering Methods</subject><subject>Electric properties</subject><subject>Electrical conductivity</subject><subject>Electrical resistivity</subject><subject>Electrocatalysts</subject><subject>Electron transfer</subject><subject>Electron transport</subject><subject>Energy</subject><subject>Energy Materials</subject><subject>Iron</subject><subject>Materials Science</subject><subject>Metal air batteries</subject><subject>Metals</subject><subject>Nanotubes</subject><subject>Nitrates</subject><subject>Nitrogen</subject><subject>Oxynitrides</subject><subject>Polymer Sciences</subject><subject>Pyrolysis</subject><subject>Rechargeable batteries</subject><subject>Solid Mechanics</subject><subject>Sulfur</subject><subject>Synergistic effect</subject><subject>Zinc</subject><subject>Zinc compounds</subject><subject>Zinc-oxygen batteries</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kc9qHSEUh4fSQm_TvkBWQlddmPhnHGeW6W3SBkILSbrJRhznzFyDV2_VoZnX6ZPWZAIlm-IRQb7vePBXVceUnFBC5GmipBUcE1Z2KwTFy6tqQ4XkuG4Jf11tCGEMs7qhb6t3Kd0TQoRkdFP9-Wz3kLVz1iD-Be2Cc-E39tqHtAPn0AVsAw4Pi7c52gFOvyPtB3SDTMBDOMCAjI598OjRyHMPCelSKIZ-Thn1dpy9yTZ47VDpMoFH4MDkGIwury6FGUNEEcxOxwl07wDdeaxtRL3OGaKF9L56M2qX4MPzeVT9vDi_3X7DVz--Xm7PrrDhHct4ACbqhpFG9mxsy6cI4C1nIGvChsZw0jEYeC2k6IaR1Z0GaMzYyrqXkhDe86Pq49r3EMOvGVJW92GOZfKkWMtIKdbQQp2s1KQdKOvHkKM2ZQ2wtyZ4GG25P5OCMskZ7Yrw6YVQmAwPedJzSury5voly1bWxJBShFEdot3ruChK1GPQag1alaDVU9BqKRJfpVRgP0H8N_d_rL8JG6y_</recordid><startdate>20230601</startdate><enddate>20230601</enddate><creator>Akbarian, Parisa</creator><creator>Kheirmand, Mehdi</creator><creator>Asadi, Aliakbar</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><orcidid>https://orcid.org/0000-0002-6469-7797</orcidid></search><sort><creationdate>20230601</creationdate><title>Bimetallic 3D hollow-nanoshell FeCo-oxynitride/N and S co-doped carbon nanotubes as a robust bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries</title><author>Akbarian, Parisa ; Kheirmand, Mehdi ; Asadi, Aliakbar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-de25462067b2f80075e3832e7402d6c3092ed345759df249aee6cf874b77003b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Activation energy</topic><topic>Bamboo</topic><topic>Batteries</topic><topic>Bimetals</topic><topic>Carbon</topic><topic>Carbon nanotubes</topic><topic>Carbon nitride</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystallography and Scattering Methods</topic><topic>Electric properties</topic><topic>Electrical conductivity</topic><topic>Electrical resistivity</topic><topic>Electrocatalysts</topic><topic>Electron transfer</topic><topic>Electron transport</topic><topic>Energy</topic><topic>Energy Materials</topic><topic>Iron</topic><topic>Materials Science</topic><topic>Metal air batteries</topic><topic>Metals</topic><topic>Nanotubes</topic><topic>Nitrates</topic><topic>Nitrogen</topic><topic>Oxynitrides</topic><topic>Polymer Sciences</topic><topic>Pyrolysis</topic><topic>Rechargeable batteries</topic><topic>Solid Mechanics</topic><topic>Sulfur</topic><topic>Synergistic effect</topic><topic>Zinc</topic><topic>Zinc compounds</topic><topic>Zinc-oxygen batteries</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Akbarian, Parisa</creatorcontrib><creatorcontrib>Kheirmand, Mehdi</creatorcontrib><creatorcontrib>Asadi, Aliakbar</creatorcontrib><collection>CrossRef</collection><collection>Science In Context</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Akbarian, Parisa</au><au>Kheirmand, Mehdi</au><au>Asadi, Aliakbar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bimetallic 3D hollow-nanoshell FeCo-oxynitride/N and S co-doped carbon nanotubes as a robust bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2023-06-01</date><risdate>2023</risdate><volume>58</volume><issue>21</issue><spage>8889</spage><epage>8907</epage><pages>8889-8907</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Herein, a novel 3D hierarchically hollow-shell porous structure of iron cobalt oxynitride anchored nitrogen and sulfur-doped bamboo-like carbon nanotubes (FeCo
2
ON/NSCNTs) are fabricated using a pyrolysis of Fe doped-ZIF-8/67@S-doped g-C
3
N
4
. The strong synergistic effects between hollow FeCo
2
ON, NC nanoshells, and NSCNTs lead to accelerating the mass and electron transfer between the active sites which is favorable for electrochemical activities. The introduction of Fe into the nanohybrid and nitrogen/sulfur atoms doped on CNTs leading to increase electrical conductivity and decrease the activation energy barrier of the rate-determining step. The electrocatalyst exhibit a more half-wave potential of 0.903 V vs. RHE, outperform to Pt/C. Moreover, the low overpotential of 268 mV at 10 mA cm
−1
is attained for FeCo
2
ON/NSCNTs. Its superiority as the air-electrode electrocatalyst corroborates in a Zn–air battery with a higher power density and specific capacity (235.4 mW cm
−2
, and 781 mAh g
−1
, respectively) than Pt/C + RuO
2
(184.6 mW cm
−2
, and 701 mAh g
−1
).
Graphical abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-023-08551-y</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0002-6469-7797</orcidid></addata></record> |
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| ispartof | Journal of materials science, 2023-06, Vol.58 (21), p.8889-8907 |
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| language | eng |
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| source | SpringerLink |
| subjects | Activation energy Bamboo Batteries Bimetals Carbon Carbon nanotubes Carbon nitride Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystallography and Scattering Methods Electric properties Electrical conductivity Electrical resistivity Electrocatalysts Electron transfer Electron transport Energy Energy Materials Iron Materials Science Metal air batteries Metals Nanotubes Nitrates Nitrogen Oxynitrides Polymer Sciences Pyrolysis Rechargeable batteries Solid Mechanics Sulfur Synergistic effect Zinc Zinc compounds Zinc-oxygen batteries |
| title | Bimetallic 3D hollow-nanoshell FeCo-oxynitride/N and S co-doped carbon nanotubes as a robust bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries |
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