Solid/Solid State Interfacial Reactions in the Sn-9Zn/Cu-Based Alloys (C1990 HP, Alloy 25, and C194) Couples

We investigated the kinetics of the intermetallic compound (IMC) growth during the solid/solid state reaction at 125–175°C for 100–2000 h between Sn-9 wt.% Zn (SZ) with Cu-3.28 wt.%Ti (C1990 HP), Cu-2.0 wt.% Be (Alloy 25), and Cu-2.3 wt.% Fe (C194) alloys, respectively. The results revealed that bot...

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Veröffentlicht in:JOM (1989) 2023-06, Vol.75 (6), p.1889-1901
Hauptverfasser: Laksono, Andromeda Dwi, Al-Audhah, Lutfi Yunus Wahab, Chen, Chih-Ming, Ho, Yu Xuan, Yen, Yee-Wen
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container_end_page 1901
container_issue 6
container_start_page 1889
container_title JOM (1989)
container_volume 75
creator Laksono, Andromeda Dwi
Al-Audhah, Lutfi Yunus Wahab
Chen, Chih-Ming
Ho, Yu Xuan
Yen, Yee-Wen
description We investigated the kinetics of the intermetallic compound (IMC) growth during the solid/solid state reaction at 125–175°C for 100–2000 h between Sn-9 wt.% Zn (SZ) with Cu-3.28 wt.%Ti (C1990 HP), Cu-2.0 wt.% Be (Alloy 25), and Cu-2.3 wt.% Fe (C194) alloys, respectively. The results revealed that both the CuZn 5 and Cu 5 Zn 8 phases were formed at early stage and the CuZn 5 phase was transformed to the Cu 5 Zn 8 phase when the aging temperature and time were increased in the SZ/C1990 HP couples. The CuZn 5 and Cu 5 Zn 8 phases were formed, and no phase transformation was observed in the SZ/Alloy 25 couples. In the SZ/C194 couples, only Cu 5 Zn 8 phase formed at early stage of aging. The Sn tunneling phenomena promoted Cu-Sn IMC formed at a higher temperature and longer aging time. The Cu 6 Sn 5 phase was formed around the Sn-rich matrix and consumed the Cu atom from the C194 substrate. A diffusion-controlled mechanism was responsible for IMC growth in all couples. The activation energy for overall IMCs was 51.1 kJ/mol on SZ/C1990 HP, 45.7 kJ/mol on SZ/Alloy 25 couples, and 87.0 kJ/mol on SZ/C194.
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The results revealed that both the CuZn 5 and Cu 5 Zn 8 phases were formed at early stage and the CuZn 5 phase was transformed to the Cu 5 Zn 8 phase when the aging temperature and time were increased in the SZ/C1990 HP couples. The CuZn 5 and Cu 5 Zn 8 phases were formed, and no phase transformation was observed in the SZ/Alloy 25 couples. In the SZ/C194 couples, only Cu 5 Zn 8 phase formed at early stage of aging. The Sn tunneling phenomena promoted Cu-Sn IMC formed at a higher temperature and longer aging time. The Cu 6 Sn 5 phase was formed around the Sn-rich matrix and consumed the Cu atom from the C194 substrate. A diffusion-controlled mechanism was responsible for IMC growth in all couples. The activation energy for overall IMCs was 51.1 kJ/mol on SZ/C1990 HP, 45.7 kJ/mol on SZ/Alloy 25 couples, and 87.0 kJ/mol on SZ/C194.</description><identifier>ISSN: 1047-4838</identifier><identifier>EISSN: 1543-1851</identifier><identifier>DOI: 10.1007/s11837-023-05827-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Advanced Technology for Electronic Packaging and Interconnection Materials ; Aging ; Alloys ; Chemistry/Food Science ; Copper ; Copper base alloys ; Earth Sciences ; Engineering ; Environment ; Hydrochloric acid ; Interface reactions ; Intermetallic compounds ; Mechanical properties ; Phase transitions ; Physics ; Solid state ; Substrates ; Temperature ; Thermal cycling ; Tin</subject><ispartof>JOM (1989), 2023-06, Vol.75 (6), p.1889-1901</ispartof><rights>The Minerals, Metals &amp; Materials Society 2023. 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The results revealed that both the CuZn 5 and Cu 5 Zn 8 phases were formed at early stage and the CuZn 5 phase was transformed to the Cu 5 Zn 8 phase when the aging temperature and time were increased in the SZ/C1990 HP couples. The CuZn 5 and Cu 5 Zn 8 phases were formed, and no phase transformation was observed in the SZ/Alloy 25 couples. In the SZ/C194 couples, only Cu 5 Zn 8 phase formed at early stage of aging. The Sn tunneling phenomena promoted Cu-Sn IMC formed at a higher temperature and longer aging time. The Cu 6 Sn 5 phase was formed around the Sn-rich matrix and consumed the Cu atom from the C194 substrate. A diffusion-controlled mechanism was responsible for IMC growth in all couples. 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The results revealed that both the CuZn 5 and Cu 5 Zn 8 phases were formed at early stage and the CuZn 5 phase was transformed to the Cu 5 Zn 8 phase when the aging temperature and time were increased in the SZ/C1990 HP couples. The CuZn 5 and Cu 5 Zn 8 phases were formed, and no phase transformation was observed in the SZ/Alloy 25 couples. In the SZ/C194 couples, only Cu 5 Zn 8 phase formed at early stage of aging. The Sn tunneling phenomena promoted Cu-Sn IMC formed at a higher temperature and longer aging time. The Cu 6 Sn 5 phase was formed around the Sn-rich matrix and consumed the Cu atom from the C194 substrate. A diffusion-controlled mechanism was responsible for IMC growth in all couples. The activation energy for overall IMCs was 51.1 kJ/mol on SZ/C1990 HP, 45.7 kJ/mol on SZ/Alloy 25 couples, and 87.0 kJ/mol on SZ/C194.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11837-023-05827-1</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-6469-6666</orcidid></addata></record>
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subjects Advanced Technology for Electronic Packaging and Interconnection Materials
Aging
Alloys
Chemistry/Food Science
Copper
Copper base alloys
Earth Sciences
Engineering
Environment
Hydrochloric acid
Interface reactions
Intermetallic compounds
Mechanical properties
Phase transitions
Physics
Solid state
Substrates
Temperature
Thermal cycling
Tin
title Solid/Solid State Interfacial Reactions in the Sn-9Zn/Cu-Based Alloys (C1990 HP, Alloy 25, and C194) Couples
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