Structural and Crystal-Chemical Features of Mixed-Layer Illite-Containing Minerals from Catagenetically Altered Upper Jurassic Oil-Source Rocks

Illite-smectite (I-S) minerals from the Upper Jurassic oil-source shales of Denmark and the North Sea were studied by a complex of diffraction and spectroscopic methods. Detailed structures were identified to reveal the mechanism of postsedimentary transformations of these shales. Usually, oil is ge...

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Veröffentlicht in:Lithology and Mineral Resources 2023-06, Vol.58 (3), p.183-195
Hauptverfasser: Drits, V. A., Sakharov, B. A., Zviagina, B. B.
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container_title Lithology and Mineral Resources
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creator Drits, V. A.
Sakharov, B. A.
Zviagina, B. B.
description Illite-smectite (I-S) minerals from the Upper Jurassic oil-source shales of Denmark and the North Sea were studied by a complex of diffraction and spectroscopic methods. Detailed structures were identified to reveal the mechanism of postsedimentary transformations of these shales. Usually, oil is generated in the oil-source rocks of sedimentary basins simultaneously with the diagenetic and catagenetic I-S transformations. The results obtained demonstrate the relationship between these two reactions: NH 3 molecules released from kerogen during the maximum oil formation are fixed as NH 4 cations in smectite or vermiculite interlayers, forming mica or tobelite structural fragments. This solid-phase transformation produces the mixed-layer structures consisting of illite, tobelite, smectite, and vermiculite (I-T-S-V) layers.
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subjects Ammonia
Cations
Diagenesis
Earth and Environmental Science
Earth Sciences
Illite
Illites
Interlayers
Jurassic
Kerogen
Mica
Mineral Resources
Mineralogy
Minerals
Oil
Phase transitions
Rocks
Sedimentary basins
Sedimentology
Shales
Smectites
Solid phases
Vermiculite
Vermiculites
title Structural and Crystal-Chemical Features of Mixed-Layer Illite-Containing Minerals from Catagenetically Altered Upper Jurassic Oil-Source Rocks
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