Pressure Engineering Toward Harvesting the Bright Deep‐Blue‐Light Emission in Y‐based Metal‐Organic Frameworks
The emergence of metal‐organic frameworks (MOFs) provides a new platform of low‐cost and color‐saturated blue light‐emitting diodes ideal for display and solid‐state lighting applications. However, numerous established MOFs still exhibit weak deep‐blue‐light emission (
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| Veröffentlicht in: | Advanced functional materials 2023-05, Vol.33 (21), p.n/a |
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| creator | Wang, Yixuan Liu, Chuang Yong, Xue Yang, Xinyi Yu, Jingkun Lu, Siyu Bai, Fuquan Wang, Shiping Wang, Kai Liu, Zhaodong Feng, Bingtao Hou, Xuyuan Liu, Hao Chen, Banglin Fang, Qianrong Zou, Bo |
| description | The emergence of metal‐organic frameworks (MOFs) provides a new platform of low‐cost and color‐saturated blue light‐emitting diodes ideal for display and solid‐state lighting applications. However, numerous established MOFs still exhibit weak deep‐blue‐light emission ( |
| doi_str_mv | 10.1002/adfm.202300109 |
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Pressure‐treated Y(BTC)(H2O)6 exhibits a brilliant deep‐blue emission with a photoluminescence quantum yield from the initial 2.8% increasing to 75.0%. The hydrogen bonding cooperativity effect increases hydrogen bond binding energy after pressure treatment and thus the planarization structure is locked. The increased electronic transition diversity and oscillator strength facilitate the metal‐to‐ligand charge transfer process.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.202300109</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Benzene ; Charge efficiency ; Charge transfer ; Chemical-mechanical polishing ; deep‐blue‐light emission enhancements ; Hydrogen bonding ; hydrogen bonding cooperativity effects ; Hydrogen bonds ; Light emission ; Light emitting diodes ; Materials science ; Metal-organic frameworks ; metal‐to‐ligand charge‐transfers ; Photoluminescence ; pressure‐treated engineering ; Yttrium ; Y‐based metal‐organic frameworks</subject><ispartof>Advanced functional materials, 2023-05, Vol.33 (21), p.n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3179-203347afd18beefcf6bce5d0bad292245da263f4260c4bfc64d38371a791cdf93</citedby><cites>FETCH-LOGICAL-c3179-203347afd18beefcf6bce5d0bad292245da263f4260c4bfc64d38371a791cdf93</cites><orcidid>0000-0002-3215-1255</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadfm.202300109$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadfm.202300109$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27928,27929,45578,45579</link.rule.ids></links><search><creatorcontrib>Wang, Yixuan</creatorcontrib><creatorcontrib>Liu, Chuang</creatorcontrib><creatorcontrib>Yong, Xue</creatorcontrib><creatorcontrib>Yang, Xinyi</creatorcontrib><creatorcontrib>Yu, Jingkun</creatorcontrib><creatorcontrib>Lu, Siyu</creatorcontrib><creatorcontrib>Bai, Fuquan</creatorcontrib><creatorcontrib>Wang, Shiping</creatorcontrib><creatorcontrib>Wang, Kai</creatorcontrib><creatorcontrib>Liu, Zhaodong</creatorcontrib><creatorcontrib>Feng, Bingtao</creatorcontrib><creatorcontrib>Hou, Xuyuan</creatorcontrib><creatorcontrib>Liu, Hao</creatorcontrib><creatorcontrib>Chen, Banglin</creatorcontrib><creatorcontrib>Fang, Qianrong</creatorcontrib><creatorcontrib>Zou, Bo</creatorcontrib><title>Pressure Engineering Toward Harvesting the Bright Deep‐Blue‐Light Emission in Y‐based Metal‐Organic Frameworks</title><title>Advanced functional materials</title><description>The emergence of metal‐organic frameworks (MOFs) provides a new platform of low‐cost and color‐saturated blue light‐emitting diodes ideal for display and solid‐state lighting applications. However, numerous established MOFs still exhibit weak deep‐blue‐light emission (<450 nm) owing to low energy/charge transfer efficiency. Here a pressure‐treated strategy to greatly enhance photoluminescence performance of deep‐blue light‐emitting Y(BTC)(H2O)6 (H3BTC: benzene‐1,3,5‐tricarboxylic acid) is reported. Pressure‐treated Y(BTC)(H2O)6 exhibits a bright emission at 409 nm with a photoluminescence quantum yield from the initial 2.8% increasing to 75.0%. The hydrogen bonding cooperativity effect increases hydrogen bond binding energy after pressure treatment and thus the planarization structure is locked. The increased electronic transition diversity and oscillator strength originating from the planarization structure are highly responsible for boosting metal‐to‐ligand charge transfer. The findings in this study provide significant insights into the underlying mechanism of the structure‐property relationship in Y(BTC)(H2O)6 and offer a promising strategy to harvest deep‐blue‐emitting MOFs materials.
Pressure‐treated Y(BTC)(H2O)6 exhibits a brilliant deep‐blue emission with a photoluminescence quantum yield from the initial 2.8% increasing to 75.0%. The hydrogen bonding cooperativity effect increases hydrogen bond binding energy after pressure treatment and thus the planarization structure is locked. The increased electronic transition diversity and oscillator strength facilitate the metal‐to‐ligand charge transfer process.</description><subject>Benzene</subject><subject>Charge efficiency</subject><subject>Charge transfer</subject><subject>Chemical-mechanical polishing</subject><subject>deep‐blue‐light emission enhancements</subject><subject>Hydrogen bonding</subject><subject>hydrogen bonding cooperativity effects</subject><subject>Hydrogen bonds</subject><subject>Light emission</subject><subject>Light emitting diodes</subject><subject>Materials science</subject><subject>Metal-organic frameworks</subject><subject>metal‐to‐ligand charge‐transfers</subject><subject>Photoluminescence</subject><subject>pressure‐treated engineering</subject><subject>Yttrium</subject><subject>Y‐based metal‐organic frameworks</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOAkEQRTtGExHduu7ENdgv5rHkKSYQXGCiq0nPdPXQOA_snoGw8xP8Rr_EQQwuXVXVzblVqYvQLSVdSgi7l0rnXUYYJ4SS8Ay1qEe9DicsOD_19OUSXTm3bhDf56KFtk8WnKst4HGRmgLAmiLFy3InrcJTabfgqoNSrQAPrElXFR4BbL4-PgdZDU2Z_Wjj3DhnygKbAr82aiwdKDyHSmbNtLCpLEyCJ1bmsCvtm7tGF1pmDm5-axs9T8bL4bQzWzw8DvuzTsKpH3YY4Vz4UisaxAA60V6cQE-RWCoWMiZ6SjKPa8E8kohYJ55QPOA-lX5IE6VD3kZ3x70bW77XzS_Ruqxt0ZyMWEAFF4HPew3VPVKJLZ2zoKONNbm0-4iS6JBtdMg2OmXbGMKjYWcy2P9DR_3RZP7n_QYq2IMA</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Wang, Yixuan</creator><creator>Liu, Chuang</creator><creator>Yong, Xue</creator><creator>Yang, Xinyi</creator><creator>Yu, Jingkun</creator><creator>Lu, Siyu</creator><creator>Bai, Fuquan</creator><creator>Wang, Shiping</creator><creator>Wang, Kai</creator><creator>Liu, Zhaodong</creator><creator>Feng, Bingtao</creator><creator>Hou, Xuyuan</creator><creator>Liu, Hao</creator><creator>Chen, Banglin</creator><creator>Fang, Qianrong</creator><creator>Zou, Bo</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3215-1255</orcidid></search><sort><creationdate>20230501</creationdate><title>Pressure Engineering Toward Harvesting the Bright Deep‐Blue‐Light Emission in Y‐based Metal‐Organic Frameworks</title><author>Wang, Yixuan ; Liu, Chuang ; Yong, Xue ; Yang, Xinyi ; Yu, Jingkun ; Lu, Siyu ; Bai, Fuquan ; Wang, Shiping ; Wang, Kai ; Liu, Zhaodong ; Feng, Bingtao ; Hou, Xuyuan ; Liu, Hao ; Chen, Banglin ; Fang, Qianrong ; Zou, Bo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3179-203347afd18beefcf6bce5d0bad292245da263f4260c4bfc64d38371a791cdf93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Benzene</topic><topic>Charge efficiency</topic><topic>Charge transfer</topic><topic>Chemical-mechanical polishing</topic><topic>deep‐blue‐light emission enhancements</topic><topic>Hydrogen bonding</topic><topic>hydrogen bonding cooperativity effects</topic><topic>Hydrogen bonds</topic><topic>Light emission</topic><topic>Light emitting diodes</topic><topic>Materials science</topic><topic>Metal-organic frameworks</topic><topic>metal‐to‐ligand charge‐transfers</topic><topic>Photoluminescence</topic><topic>pressure‐treated engineering</topic><topic>Yttrium</topic><topic>Y‐based metal‐organic frameworks</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yixuan</creatorcontrib><creatorcontrib>Liu, Chuang</creatorcontrib><creatorcontrib>Yong, Xue</creatorcontrib><creatorcontrib>Yang, Xinyi</creatorcontrib><creatorcontrib>Yu, Jingkun</creatorcontrib><creatorcontrib>Lu, Siyu</creatorcontrib><creatorcontrib>Bai, Fuquan</creatorcontrib><creatorcontrib>Wang, Shiping</creatorcontrib><creatorcontrib>Wang, Kai</creatorcontrib><creatorcontrib>Liu, Zhaodong</creatorcontrib><creatorcontrib>Feng, Bingtao</creatorcontrib><creatorcontrib>Hou, Xuyuan</creatorcontrib><creatorcontrib>Liu, Hao</creatorcontrib><creatorcontrib>Chen, Banglin</creatorcontrib><creatorcontrib>Fang, Qianrong</creatorcontrib><creatorcontrib>Zou, Bo</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yixuan</au><au>Liu, Chuang</au><au>Yong, Xue</au><au>Yang, Xinyi</au><au>Yu, Jingkun</au><au>Lu, Siyu</au><au>Bai, Fuquan</au><au>Wang, Shiping</au><au>Wang, Kai</au><au>Liu, Zhaodong</au><au>Feng, Bingtao</au><au>Hou, Xuyuan</au><au>Liu, Hao</au><au>Chen, Banglin</au><au>Fang, Qianrong</au><au>Zou, Bo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pressure Engineering Toward Harvesting the Bright Deep‐Blue‐Light Emission in Y‐based Metal‐Organic Frameworks</atitle><jtitle>Advanced functional materials</jtitle><date>2023-05-01</date><risdate>2023</risdate><volume>33</volume><issue>21</issue><epage>n/a</epage><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>The emergence of metal‐organic frameworks (MOFs) provides a new platform of low‐cost and color‐saturated blue light‐emitting diodes ideal for display and solid‐state lighting applications. However, numerous established MOFs still exhibit weak deep‐blue‐light emission (<450 nm) owing to low energy/charge transfer efficiency. Here a pressure‐treated strategy to greatly enhance photoluminescence performance of deep‐blue light‐emitting Y(BTC)(H2O)6 (H3BTC: benzene‐1,3,5‐tricarboxylic acid) is reported. Pressure‐treated Y(BTC)(H2O)6 exhibits a bright emission at 409 nm with a photoluminescence quantum yield from the initial 2.8% increasing to 75.0%. The hydrogen bonding cooperativity effect increases hydrogen bond binding energy after pressure treatment and thus the planarization structure is locked. The increased electronic transition diversity and oscillator strength originating from the planarization structure are highly responsible for boosting metal‐to‐ligand charge transfer. The findings in this study provide significant insights into the underlying mechanism of the structure‐property relationship in Y(BTC)(H2O)6 and offer a promising strategy to harvest deep‐blue‐emitting MOFs materials.
Pressure‐treated Y(BTC)(H2O)6 exhibits a brilliant deep‐blue emission with a photoluminescence quantum yield from the initial 2.8% increasing to 75.0%. The hydrogen bonding cooperativity effect increases hydrogen bond binding energy after pressure treatment and thus the planarization structure is locked. The increased electronic transition diversity and oscillator strength facilitate the metal‐to‐ligand charge transfer process.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.202300109</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-3215-1255</orcidid></addata></record> |
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| subjects | Benzene Charge efficiency Charge transfer Chemical-mechanical polishing deep‐blue‐light emission enhancements Hydrogen bonding hydrogen bonding cooperativity effects Hydrogen bonds Light emission Light emitting diodes Materials science Metal-organic frameworks metal‐to‐ligand charge‐transfers Photoluminescence pressure‐treated engineering Yttrium Y‐based metal‐organic frameworks |
| title | Pressure Engineering Toward Harvesting the Bright Deep‐Blue‐Light Emission in Y‐based Metal‐Organic Frameworks |
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