Optimization of annealing temperature on the formation CZTSe absorber layer

In the present work, we studied the optimization of annealing temperature on the formation of Cu 2 ZnSnSe 4 (CZTSe) thin films and its impact on the film properties. The CZTSe films were deposited on Mo/SLG substrate by the thermal evaporation method. All the elements of the compound were deposited...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2023-06, Vol.129 (6), Article 414
Hauptverfasser: Kumar, Vishvas, Singh, Udai P.
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description In the present work, we studied the optimization of annealing temperature on the formation of Cu 2 ZnSnSe 4 (CZTSe) thin films and its impact on the film properties. The CZTSe films were deposited on Mo/SLG substrate by the thermal evaporation method. All the elements of the compound were deposited in the stack using its pellets. After the successful deposition of the films, the composition of the as deposited film was measured, then it was proceeded further for two steps annealing. The annealing parameter is one of the crucial steps for obtaining good quality kesterite-based absorber layer. In the present work, we have utilized two-step annealing to achieve the absorber layer suitable for device fabrication. The annealing in Se atmosphere were carried out at 230 °C for 10 min in first step followed by another 10 min annealing in second step with a temperature variation from 430 to 490 °C. The final temperature was varied to investigate the influence of annealing temperature on the absorber layer (CZTSe) film properties and its optimization. The films annealed between 470 and 490 °C are showing better structural, optical, electrical and morphological properties for further processing.
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subjects Absorbers
Annealing
Applied physics
Characterization and Evaluation of Materials
Condensed Matter Physics
Copper zinc tin selenide
Machines
Manufacturing
Materials science
Nanotechnology
Optical and Electronic Materials
Optical properties
Optimization
Photovoltaic cells
Physics
Physics and Astronomy
Processes
Substrates
Surfaces and Interfaces
Thin Films
title Optimization of annealing temperature on the formation CZTSe absorber layer
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