Selective colorimetric detection of cysteine based on phenylvinylbisquinoline for its potential implementation in optoelectronic sensors
We report a sensitive colorimetric chemosensor for cysteine based on phenylvinylbisquinoline, named M1. Selectivity for l -cysteine was demonstrated, causing a colorimetric change. The interaction between M1 and l -cysteine suggests a possible click reaction that alters the optical properties, which...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2023-05, Vol.34 (13), p.1116, Article 1116 |
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| container_title | Journal of materials science. Materials in electronics |
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| creator | Islas-Rodríguez, N. Muñoz, R. Vázquez-García, R. A. Rodríguez, Jose A. Reyes-Pérez, M. Hernández-Ortiz, O. J. |
| description | We report a sensitive colorimetric chemosensor for cysteine based on phenylvinylbisquinoline, named M1. Selectivity for
l
-cysteine was demonstrated, causing a colorimetric change. The interaction between M1 and
l
-cysteine suggests a possible click reaction that alters the optical properties, which are consistent with the predictions in the study of TD-DFT.
1
H RMN, FTIR spectroscopies, and mass spectrometry confirmed the chemical structure obtained by the click reaction. Optical characterization revealed a bathochromic shift and a weakening of the fluorescence of M1 with increasing
l
-cysteine concentration. The detection limit for cysteine was 0.45 mM, the quantification limit was 1.36 mM, and the molar ratio method confirmed a stoichiometry of 1:2 between M1 and
l
-cysteine. This molecule can be used in electronic devices for in situ sensing of
l
-cysteine by a colorimetric shift. |
| doi_str_mv | 10.1007/s10854-023-10538-z |
| format | Article |
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l
-cysteine was demonstrated, causing a colorimetric change. The interaction between M1 and
l
-cysteine suggests a possible click reaction that alters the optical properties, which are consistent with the predictions in the study of TD-DFT.
1
H RMN, FTIR spectroscopies, and mass spectrometry confirmed the chemical structure obtained by the click reaction. Optical characterization revealed a bathochromic shift and a weakening of the fluorescence of M1 with increasing
l
-cysteine concentration. The detection limit for cysteine was 0.45 mM, the quantification limit was 1.36 mM, and the molar ratio method confirmed a stoichiometry of 1:2 between M1 and
l
-cysteine. This molecule can be used in electronic devices for in situ sensing of
l
-cysteine by a colorimetric shift.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-023-10538-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alzheimer's disease ; Biosensors ; Characterization and Evaluation of Materials ; Chemical reactions ; Chemical sensors ; Chemistry and Materials Science ; Chemoreceptors ; Chromatography ; Colorimetry ; Cysteine ; Electronic devices ; Mass spectrometry ; Materials Science ; Optical and Electronic Materials ; Optical properties ; Optoelectronic devices ; Scientific imaging ; Sensors ; Stoichiometry</subject><ispartof>Journal of materials science. Materials in electronics, 2023-05, Vol.34 (13), p.1116, Article 1116</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-3f977316b327e6bdfbbde98122c40f9553509b26feb2e14d8dfd29467542fde63</citedby><cites>FETCH-LOGICAL-c319t-3f977316b327e6bdfbbde98122c40f9553509b26feb2e14d8dfd29467542fde63</cites><orcidid>0000-0002-5805-9035</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-023-10538-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-023-10538-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Islas-Rodríguez, N.</creatorcontrib><creatorcontrib>Muñoz, R.</creatorcontrib><creatorcontrib>Vázquez-García, R. A.</creatorcontrib><creatorcontrib>Rodríguez, Jose A.</creatorcontrib><creatorcontrib>Reyes-Pérez, M.</creatorcontrib><creatorcontrib>Hernández-Ortiz, O. J.</creatorcontrib><title>Selective colorimetric detection of cysteine based on phenylvinylbisquinoline for its potential implementation in optoelectronic sensors</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>We report a sensitive colorimetric chemosensor for cysteine based on phenylvinylbisquinoline, named M1. Selectivity for
l
-cysteine was demonstrated, causing a colorimetric change. The interaction between M1 and
l
-cysteine suggests a possible click reaction that alters the optical properties, which are consistent with the predictions in the study of TD-DFT.
1
H RMN, FTIR spectroscopies, and mass spectrometry confirmed the chemical structure obtained by the click reaction. Optical characterization revealed a bathochromic shift and a weakening of the fluorescence of M1 with increasing
l
-cysteine concentration. The detection limit for cysteine was 0.45 mM, the quantification limit was 1.36 mM, and the molar ratio method confirmed a stoichiometry of 1:2 between M1 and
l
-cysteine. This molecule can be used in electronic devices for in situ sensing of
l
-cysteine by a colorimetric shift.</description><subject>Alzheimer's disease</subject><subject>Biosensors</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical reactions</subject><subject>Chemical sensors</subject><subject>Chemistry and Materials Science</subject><subject>Chemoreceptors</subject><subject>Chromatography</subject><subject>Colorimetry</subject><subject>Cysteine</subject><subject>Electronic devices</subject><subject>Mass spectrometry</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Optoelectronic devices</subject><subject>Scientific imaging</subject><subject>Sensors</subject><subject>Stoichiometry</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kMtKAzEUhoMoWKsv4CrgejTXuSyleIOCCxXchbmcaMo0mSZpoT6Bj22mI7hzcw7n8F_gQ-iSkmtKSHETKCmlyAjjGSWSl9nXEZpRWfBMlOz9GM1IJYtMSMZO0VkIK0JILng5Q98v0EMbzQ5w63rnzRqiNy3uII5vZ7HTuN2HCMYCbuoAHU7P4RPsvt-ZNBoTNltjXT8KtPPYxIAHF8FGU_fYrIce1umoD2kmBQ7RHUq9s6kpgA3Oh3N0ous-wMXvnqO3-7vXxWO2fH54Wtwus5bTKmZcV0XBad5wVkDedLppOqhKylgriK6k5JJUDcs1NAyo6MpOd6wSeSEF0x3kfI6uptzBu80WQlQrt_U2VSpW0hFjkQDOEZtUrXcheNBqSGhqv1eUqJG4moirRFwdiKuvZOKTKSSx_QD_F_2P6wfdi4lm</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Islas-Rodríguez, N.</creator><creator>Muñoz, R.</creator><creator>Vázquez-García, R. 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A. ; Rodríguez, Jose A. ; Reyes-Pérez, M. ; Hernández-Ortiz, O. 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Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Islas-Rodríguez, N.</au><au>Muñoz, R.</au><au>Vázquez-García, R. A.</au><au>Rodríguez, Jose A.</au><au>Reyes-Pérez, M.</au><au>Hernández-Ortiz, O. J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective colorimetric detection of cysteine based on phenylvinylbisquinoline for its potential implementation in optoelectronic sensors</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>34</volume><issue>13</issue><spage>1116</spage><pages>1116-</pages><artnum>1116</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>We report a sensitive colorimetric chemosensor for cysteine based on phenylvinylbisquinoline, named M1. Selectivity for
l
-cysteine was demonstrated, causing a colorimetric change. The interaction between M1 and
l
-cysteine suggests a possible click reaction that alters the optical properties, which are consistent with the predictions in the study of TD-DFT.
1
H RMN, FTIR spectroscopies, and mass spectrometry confirmed the chemical structure obtained by the click reaction. Optical characterization revealed a bathochromic shift and a weakening of the fluorescence of M1 with increasing
l
-cysteine concentration. The detection limit for cysteine was 0.45 mM, the quantification limit was 1.36 mM, and the molar ratio method confirmed a stoichiometry of 1:2 between M1 and
l
-cysteine. This molecule can be used in electronic devices for in situ sensing of
l
-cysteine by a colorimetric shift.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-023-10538-z</doi><orcidid>https://orcid.org/0000-0002-5805-9035</orcidid></addata></record> |
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| subjects | Alzheimer's disease Biosensors Characterization and Evaluation of Materials Chemical reactions Chemical sensors Chemistry and Materials Science Chemoreceptors Chromatography Colorimetry Cysteine Electronic devices Mass spectrometry Materials Science Optical and Electronic Materials Optical properties Optoelectronic devices Scientific imaging Sensors Stoichiometry |
| title | Selective colorimetric detection of cysteine based on phenylvinylbisquinoline for its potential implementation in optoelectronic sensors |
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