Optical Spectroscopic Study of Diffusion Combustion of a Suspension of Boron Nanoparticles in Isopropanol in Oxygen Coflow
The stationary diffusion combustion of a boron nanoparticle suspension in isopropanol in oxygen coflow and the pulsed laser photolytic initiation of this combustion were studied. Experiments were carried out using a number of spectroscopic methods. Coherent anti-Stokes Raman scattering spectroscopy...
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Veröffentlicht in: | Combustion, explosion, and shock waves explosion, and shock waves, 2023-04, Vol.59 (2), p.167-179 |
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creator | Aiyyzhy, K. O. Barmina, E. V. Kobtsev, V. D. Kozlov, D. N. Kostritsa, S. A. Orlov, S. N. Savel’ev, A. M. Smirnov, V. V. Titova, N. S. Shafeev, G. A. |
description | The stationary diffusion combustion of a boron nanoparticle suspension in isopropanol in oxygen coflow and the pulsed laser photolytic initiation of this combustion were studied. Experiments were carried out using a number of spectroscopic methods. Coherent anti-Stokes Raman scattering spectroscopy was used to determine the transverse distributions and concentrations of oxygen molecules diffusing into the fuel jet and the flame temperature variation at different distances from the edge of the burner nozzle due to the addition of boron nanoparticles into the fuel. The dimensions of the region of laser ignition of the combustible mixture were determined by laser-induced fluorescence spectroscopy of electronically excited O
molecules. Chemiluminescence spectroscopy of intermediate products of gas-phase reactions (OH* and BO
radicals) from the ignition region made it possible to characterize the spatio-temporal dynamics of this process. The variations in the temperature field and ignition dynamics due to the addition of boron nanoparticles are explained based on an analysis of the obtained data. In particular, it is assumed that the characteristic rise in temperature in the region of the flame front is primarily due to an increase in the burning rate of the fuel with nanoparticles. |
doi_str_mv | 10.1134/S0010508223020077 |
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molecules. Chemiluminescence spectroscopy of intermediate products of gas-phase reactions (OH* and BO
radicals) from the ignition region made it possible to characterize the spatio-temporal dynamics of this process. The variations in the temperature field and ignition dynamics due to the addition of boron nanoparticles are explained based on an analysis of the obtained data. In particular, it is assumed that the characteristic rise in temperature in the region of the flame front is primarily due to an increase in the burning rate of the fuel with nanoparticles.</description><identifier>ISSN: 0010-5082</identifier><identifier>EISSN: 1573-8345</identifier><identifier>DOI: 10.1134/S0010508223020077</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Boron ; Burning rate ; Chemiluminescence ; Classical and Continuum Physics ; Classical Mechanics ; Coherent scattering ; Combustion ; Control ; Diffusion ; Dynamical Systems ; Engineering ; Excitation spectra ; Flame propagation ; Flame temperature ; Fuels ; Ignition ; Isopropanol ; Laser induced fluorescence ; Lasers ; Nanoparticles ; Oxygen ; Physical Chemistry ; Physics ; Physics and Astronomy ; Pulsed lasers ; Raman spectra ; Spectrum analysis ; Temperature distribution ; Vibration</subject><ispartof>Combustion, explosion, and shock waves, 2023-04, Vol.59 (2), p.167-179</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-21099d7a3c94eb2e15a03df8580a9a5d0803b1a588018b6749e307f1bf2fbecd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0010508223020077$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0010508223020077$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Aiyyzhy, K. O.</creatorcontrib><creatorcontrib>Barmina, E. V.</creatorcontrib><creatorcontrib>Kobtsev, V. D.</creatorcontrib><creatorcontrib>Kozlov, D. N.</creatorcontrib><creatorcontrib>Kostritsa, S. A.</creatorcontrib><creatorcontrib>Orlov, S. N.</creatorcontrib><creatorcontrib>Savel’ev, A. M.</creatorcontrib><creatorcontrib>Smirnov, V. V.</creatorcontrib><creatorcontrib>Titova, N. S.</creatorcontrib><creatorcontrib>Shafeev, G. A.</creatorcontrib><title>Optical Spectroscopic Study of Diffusion Combustion of a Suspension of Boron Nanoparticles in Isopropanol in Oxygen Coflow</title><title>Combustion, explosion, and shock waves</title><addtitle>Combust Explos Shock Waves</addtitle><description>The stationary diffusion combustion of a boron nanoparticle suspension in isopropanol in oxygen coflow and the pulsed laser photolytic initiation of this combustion were studied. Experiments were carried out using a number of spectroscopic methods. Coherent anti-Stokes Raman scattering spectroscopy was used to determine the transverse distributions and concentrations of oxygen molecules diffusing into the fuel jet and the flame temperature variation at different distances from the edge of the burner nozzle due to the addition of boron nanoparticles into the fuel. The dimensions of the region of laser ignition of the combustible mixture were determined by laser-induced fluorescence spectroscopy of electronically excited O
molecules. Chemiluminescence spectroscopy of intermediate products of gas-phase reactions (OH* and BO
radicals) from the ignition region made it possible to characterize the spatio-temporal dynamics of this process. The variations in the temperature field and ignition dynamics due to the addition of boron nanoparticles are explained based on an analysis of the obtained data. In particular, it is assumed that the characteristic rise in temperature in the region of the flame front is primarily due to an increase in the burning rate of the fuel with nanoparticles.</description><subject>Boron</subject><subject>Burning rate</subject><subject>Chemiluminescence</subject><subject>Classical and Continuum Physics</subject><subject>Classical Mechanics</subject><subject>Coherent scattering</subject><subject>Combustion</subject><subject>Control</subject><subject>Diffusion</subject><subject>Dynamical Systems</subject><subject>Engineering</subject><subject>Excitation spectra</subject><subject>Flame propagation</subject><subject>Flame temperature</subject><subject>Fuels</subject><subject>Ignition</subject><subject>Isopropanol</subject><subject>Laser induced fluorescence</subject><subject>Lasers</subject><subject>Nanoparticles</subject><subject>Oxygen</subject><subject>Physical Chemistry</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Pulsed lasers</subject><subject>Raman spectra</subject><subject>Spectrum analysis</subject><subject>Temperature distribution</subject><subject>Vibration</subject><issn>0010-5082</issn><issn>1573-8345</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1UMtOwzAQtBBIlMIHcLPEObC2k9g5QnlVQvQQOEeOY1epUjvYiaB8PY5aiQPitLuzM7OrQeiSwDUhLL0pAQhkIChlQAE4P0IzknGWCJZmx2g2rZNpf4rOQtgAAKVpPkPfq35olexw2Ws1eBeU61uFy2FsdtgZfN8aM4bWWbxw23oMw9RGXOJyDL224TDfOR-bV2ldL3107HTArcXL4HofIeu6aVx97dZ6sjKd-zxHJ0Z2QV8c6hy9Pz68LZ6Tl9XTcnH7kiiaiyGhBIqi4ZKpItU11SSTwBojMgGykFkDAlhNZCYEEFHnPC00A25IbaiptWrYHF3tfeMnH6MOQ7Vxo7fxZEUFiDxNKeGRRfYsFUMIXpuq9-1W-l1FoJoirv5EHDV0rwmRa9fa_zr_L_oB4xd-jA</recordid><startdate>20230401</startdate><enddate>20230401</enddate><creator>Aiyyzhy, K. O.</creator><creator>Barmina, E. V.</creator><creator>Kobtsev, V. D.</creator><creator>Kozlov, D. N.</creator><creator>Kostritsa, S. A.</creator><creator>Orlov, S. N.</creator><creator>Savel’ev, A. M.</creator><creator>Smirnov, V. V.</creator><creator>Titova, N. S.</creator><creator>Shafeev, G. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230401</creationdate><title>Optical Spectroscopic Study of Diffusion Combustion of a Suspension of Boron Nanoparticles in Isopropanol in Oxygen Coflow</title><author>Aiyyzhy, K. O. ; Barmina, E. V. ; Kobtsev, V. D. ; Kozlov, D. N. ; Kostritsa, S. A. ; Orlov, S. N. ; Savel’ev, A. M. ; Smirnov, V. V. ; Titova, N. S. ; Shafeev, G. 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O.</creatorcontrib><creatorcontrib>Barmina, E. V.</creatorcontrib><creatorcontrib>Kobtsev, V. D.</creatorcontrib><creatorcontrib>Kozlov, D. N.</creatorcontrib><creatorcontrib>Kostritsa, S. A.</creatorcontrib><creatorcontrib>Orlov, S. N.</creatorcontrib><creatorcontrib>Savel’ev, A. M.</creatorcontrib><creatorcontrib>Smirnov, V. V.</creatorcontrib><creatorcontrib>Titova, N. S.</creatorcontrib><creatorcontrib>Shafeev, G. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Combustion, explosion, and shock waves</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aiyyzhy, K. O.</au><au>Barmina, E. V.</au><au>Kobtsev, V. D.</au><au>Kozlov, D. N.</au><au>Kostritsa, S. A.</au><au>Orlov, S. N.</au><au>Savel’ev, A. M.</au><au>Smirnov, V. V.</au><au>Titova, N. S.</au><au>Shafeev, G. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optical Spectroscopic Study of Diffusion Combustion of a Suspension of Boron Nanoparticles in Isopropanol in Oxygen Coflow</atitle><jtitle>Combustion, explosion, and shock waves</jtitle><stitle>Combust Explos Shock Waves</stitle><date>2023-04-01</date><risdate>2023</risdate><volume>59</volume><issue>2</issue><spage>167</spage><epage>179</epage><pages>167-179</pages><issn>0010-5082</issn><eissn>1573-8345</eissn><abstract>The stationary diffusion combustion of a boron nanoparticle suspension in isopropanol in oxygen coflow and the pulsed laser photolytic initiation of this combustion were studied. Experiments were carried out using a number of spectroscopic methods. Coherent anti-Stokes Raman scattering spectroscopy was used to determine the transverse distributions and concentrations of oxygen molecules diffusing into the fuel jet and the flame temperature variation at different distances from the edge of the burner nozzle due to the addition of boron nanoparticles into the fuel. The dimensions of the region of laser ignition of the combustible mixture were determined by laser-induced fluorescence spectroscopy of electronically excited O
molecules. Chemiluminescence spectroscopy of intermediate products of gas-phase reactions (OH* and BO
radicals) from the ignition region made it possible to characterize the spatio-temporal dynamics of this process. The variations in the temperature field and ignition dynamics due to the addition of boron nanoparticles are explained based on an analysis of the obtained data. In particular, it is assumed that the characteristic rise in temperature in the region of the flame front is primarily due to an increase in the burning rate of the fuel with nanoparticles.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0010508223020077</doi><tpages>13</tpages></addata></record> |
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subjects | Boron Burning rate Chemiluminescence Classical and Continuum Physics Classical Mechanics Coherent scattering Combustion Control Diffusion Dynamical Systems Engineering Excitation spectra Flame propagation Flame temperature Fuels Ignition Isopropanol Laser induced fluorescence Lasers Nanoparticles Oxygen Physical Chemistry Physics Physics and Astronomy Pulsed lasers Raman spectra Spectrum analysis Temperature distribution Vibration |
title | Optical Spectroscopic Study of Diffusion Combustion of a Suspension of Boron Nanoparticles in Isopropanol in Oxygen Coflow |
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