Concept of hydrophobic Li+-solvated structure for high performances lithium metal batteries
The large-scale application of lithium metal batteries remains a challenge due to the hydrolysis of LiPF 6 , which can induce capacity fade and series of safety issues. Prof. Ma and his co-workers have designed a hydrophobic Li + -solvated structure to obtain high performances lithium metal batterie...
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| Veröffentlicht in: | Rare metals 2023-05, Vol.42 (5), p.1427-1430 |
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| creator | Ma, Bin Zhang, Yu-Long Liu, Xin-Hua |
| description | The large-scale application of lithium metal batteries remains a challenge due to the hydrolysis of LiPF
6
, which can induce capacity fade and series of safety issues. Prof. Ma and his co-workers have designed a hydrophobic Li
+
-solvated structure to obtain high performances lithium metal batteries. The specific functional groups of the additive, hexafluoroisopropyl acrylate, can promote the formation of a hydrophobic surface, which can protect the LiPF
6
from trace H
2
O. The hexafluoroisopropyl acrylate can also promote the formation of a robust and stable solid electrolyte interphase (SEI) with rich polar C–F bonds, which can suppress the dendrite growth and improve battery performances by capturing lithium ions. This work reveals the mechanism that the introduction of hexafluoroisopropyl acrylate can improve lithium anode performances and further feature the innovative design of advanced materials for energy devices beyond lithium. |
| doi_str_mv | 10.1007/s12598-022-02217-5 |
| format | Article |
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6
, which can induce capacity fade and series of safety issues. Prof. Ma and his co-workers have designed a hydrophobic Li
+
-solvated structure to obtain high performances lithium metal batteries. The specific functional groups of the additive, hexafluoroisopropyl acrylate, can promote the formation of a hydrophobic surface, which can protect the LiPF
6
from trace H
2
O. The hexafluoroisopropyl acrylate can also promote the formation of a robust and stable solid electrolyte interphase (SEI) with rich polar C–F bonds, which can suppress the dendrite growth and improve battery performances by capturing lithium ions. This work reveals the mechanism that the introduction of hexafluoroisopropyl acrylate can improve lithium anode performances and further feature the innovative design of advanced materials for energy devices beyond lithium.</description><identifier>ISSN: 1001-0521</identifier><identifier>EISSN: 1867-7185</identifier><identifier>DOI: 10.1007/s12598-022-02217-5</identifier><language>eng</language><publisher>Beijing: Nonferrous Metals Society of China</publisher><subject>Biomaterials ; Chemistry and Materials Science ; Energy ; Functional groups ; Highlight ; Hydrophobicity ; Lithium batteries ; Lithium ions ; Materials Engineering ; Materials Science ; Metallic Materials ; Nanoscale Science and Technology ; Physical Chemistry ; Rechargeable batteries ; Solid electrolytes</subject><ispartof>Rare metals, 2023-05, Vol.42 (5), p.1427-1430</ispartof><rights>Youke Publishing Co.,Ltd 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-f75be40ebe07d015497ba5cd56bb0483a7a83920901842798bc82e537dcda1f13</citedby><cites>FETCH-LOGICAL-c319t-f75be40ebe07d015497ba5cd56bb0483a7a83920901842798bc82e537dcda1f13</cites><orcidid>0000-0002-1159-4719 ; 0000-0002-4111-7235</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12598-022-02217-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12598-022-02217-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Ma, Bin</creatorcontrib><creatorcontrib>Zhang, Yu-Long</creatorcontrib><creatorcontrib>Liu, Xin-Hua</creatorcontrib><title>Concept of hydrophobic Li+-solvated structure for high performances lithium metal batteries</title><title>Rare metals</title><addtitle>Rare Met</addtitle><description>The large-scale application of lithium metal batteries remains a challenge due to the hydrolysis of LiPF
6
, which can induce capacity fade and series of safety issues. Prof. Ma and his co-workers have designed a hydrophobic Li
+
-solvated structure to obtain high performances lithium metal batteries. The specific functional groups of the additive, hexafluoroisopropyl acrylate, can promote the formation of a hydrophobic surface, which can protect the LiPF
6
from trace H
2
O. The hexafluoroisopropyl acrylate can also promote the formation of a robust and stable solid electrolyte interphase (SEI) with rich polar C–F bonds, which can suppress the dendrite growth and improve battery performances by capturing lithium ions. This work reveals the mechanism that the introduction of hexafluoroisopropyl acrylate can improve lithium anode performances and further feature the innovative design of advanced materials for energy devices beyond lithium.</description><subject>Biomaterials</subject><subject>Chemistry and Materials Science</subject><subject>Energy</subject><subject>Functional groups</subject><subject>Highlight</subject><subject>Hydrophobicity</subject><subject>Lithium batteries</subject><subject>Lithium ions</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Nanoscale Science and Technology</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Solid electrolytes</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-AU8BjxKdpE2THmXxCxa86MlDSNJ026Xd1CQV_PdmXcGbh2Hm8D7vwIPQJYUbCiBuI2W8lgQY2w8VhB-hBZWVIIJKfpxvAEqAM3qKzmLcApRlVcECva_8zropYd_i7qsJfuq86S1e99ck-uFTJ9fgmMJs0xwcbn3AXb_p8ORCvked4YiHPnX9POLRJT1go1NyoXfxHJ20eoju4ncv0dvD_evqiaxfHp9Xd2tiC1on0gpuXAnOOBANUF7WwmhuG14ZA6UstNCyqBnUQGXJRC2NlczxQjS20bSlxRJdHXqn4D9mF5Pa-jns8kvFJJQF1FlJTrFDygYfY3CtmkI_6vClKKi9RHWQqLJA9SNR8QwVByjm8G7jwl_1P9Q3XZN1Tw</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Ma, Bin</creator><creator>Zhang, Yu-Long</creator><creator>Liu, Xin-Hua</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1159-4719</orcidid><orcidid>https://orcid.org/0000-0002-4111-7235</orcidid></search><sort><creationdate>20230501</creationdate><title>Concept of hydrophobic Li+-solvated structure for high performances lithium metal batteries</title><author>Ma, Bin ; Zhang, Yu-Long ; Liu, Xin-Hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-f75be40ebe07d015497ba5cd56bb0483a7a83920901842798bc82e537dcda1f13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Biomaterials</topic><topic>Chemistry and Materials Science</topic><topic>Energy</topic><topic>Functional groups</topic><topic>Highlight</topic><topic>Hydrophobicity</topic><topic>Lithium batteries</topic><topic>Lithium ions</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Nanoscale Science and Technology</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Solid electrolytes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Bin</creatorcontrib><creatorcontrib>Zhang, Yu-Long</creatorcontrib><creatorcontrib>Liu, Xin-Hua</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Rare metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Bin</au><au>Zhang, Yu-Long</au><au>Liu, Xin-Hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Concept of hydrophobic Li+-solvated structure for high performances lithium metal batteries</atitle><jtitle>Rare metals</jtitle><stitle>Rare Met</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>42</volume><issue>5</issue><spage>1427</spage><epage>1430</epage><pages>1427-1430</pages><issn>1001-0521</issn><eissn>1867-7185</eissn><abstract>The large-scale application of lithium metal batteries remains a challenge due to the hydrolysis of LiPF
6
, which can induce capacity fade and series of safety issues. Prof. Ma and his co-workers have designed a hydrophobic Li
+
-solvated structure to obtain high performances lithium metal batteries. The specific functional groups of the additive, hexafluoroisopropyl acrylate, can promote the formation of a hydrophobic surface, which can protect the LiPF
6
from trace H
2
O. The hexafluoroisopropyl acrylate can also promote the formation of a robust and stable solid electrolyte interphase (SEI) with rich polar C–F bonds, which can suppress the dendrite growth and improve battery performances by capturing lithium ions. This work reveals the mechanism that the introduction of hexafluoroisopropyl acrylate can improve lithium anode performances and further feature the innovative design of advanced materials for energy devices beyond lithium.</abstract><cop>Beijing</cop><pub>Nonferrous Metals Society of China</pub><doi>10.1007/s12598-022-02217-5</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-1159-4719</orcidid><orcidid>https://orcid.org/0000-0002-4111-7235</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Rare metals, 2023-05, Vol.42 (5), p.1427-1430 |
| issn | 1001-0521 1867-7185 |
| language | eng |
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| source | Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings |
| subjects | Biomaterials Chemistry and Materials Science Energy Functional groups Highlight Hydrophobicity Lithium batteries Lithium ions Materials Engineering Materials Science Metallic Materials Nanoscale Science and Technology Physical Chemistry Rechargeable batteries Solid electrolytes |
| title | Concept of hydrophobic Li+-solvated structure for high performances lithium metal batteries |
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