WO3:AgInS2 quantum dot electron transport layers in enhanced perovskite solar cells

The development of the electron transport layers (ETL) was crucially important for the improvement of charge extraction and transportation in perovskite solar cells (PSCs). Here, dual electron transport layers of TiO 2 and WO 3 mixed with different sizes of AgInS 2 quantum dots (TiO 2 /WO 3 :AgInS 2...

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Veröffentlicht in:Journal of materials research 2023-04, Vol.38 (7), p.1882-1893
Hauptverfasser: Seriwattanachai, Chaowaphat, Kaewprajak, Anusit, Sukgorn, Nuttaya, Kumnorkaew, Pisist, Nukeaw, Jiti, Kayunkid, Navaphun
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container_issue 7
container_start_page 1882
container_title Journal of materials research
container_volume 38
creator Seriwattanachai, Chaowaphat
Kaewprajak, Anusit
Sukgorn, Nuttaya
Kumnorkaew, Pisist
Nukeaw, Jiti
Kayunkid, Navaphun
description The development of the electron transport layers (ETL) was crucially important for the improvement of charge extraction and transportation in perovskite solar cells (PSCs). Here, dual electron transport layers of TiO 2 and WO 3 mixed with different sizes of AgInS 2 quantum dots (TiO 2 /WO 3 :AgInS 2 QDs) were fabricated for planar perovskite solar cells. The peak intensity of the photoluminescence (PL) of the synthesized AgInS 2 QDs were redshifted from 554 to 655 nm with an increased radius of AgInS 2 QDs from 3.82 ± 0.52 to 7.78 ± 1.37 nm. The PL intensity of the perovskite film on TiO 2 /WO 3 :AgInS 2 QDs was quenched by the addition of AgInS 2 QDs. The improved device stability was probably caused by the WO 3 :AgInS 2 QDs layer protecting the interface of perovskite layers from direct contact with TiO 2 to prevent UV decomposing. Therefore, the TiO 2 /WO 3 :AgInS 2 QDs as electron transport layers promoted the perovskite solar cell performance and enhanced the long-term stability. Graphical abstract
doi_str_mv 10.1557/s43578-023-00967-1
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subjects Applied and Technical Physics
Biomaterials
Chemistry and Materials Science
Electron transport
Inorganic Chemistry
Materials Engineering
Materials research
Materials Science
Nanotechnology
Perovskites
Photoluminescence
Photovoltaic cells
Quantum dots
Solar cells
Stability
Titanium dioxide
Tungsten oxides
title WO3:AgInS2 quantum dot electron transport layers in enhanced perovskite solar cells
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