Improved synthesis enables assessment of the electrochemical window of monocarborate solid state electrolytes

Improved synthesis enables assessment of the electrochemical window of monocarborate solid state electrolytes

We synthesized Li and Na monocarborate salts with minimal protic impurities and reassessed their electrochemical windows. Na salts display higher efficiency for metal deposition/stripping and are more oxidatively stable than Li salts. This strong cation effect is rationalized in terms of differences...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-04, Vol.59 (32), p.4746-4749
Hauptverfasser: Tutusaus, Oscar, Kuwata, Hiroko, Counihan, Michael J, Mohtadi, Rana
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Sprache:eng
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Cations
Charge density
Electrolytes
Molten salt electrolytes
Sodium
Solid electrolytes
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container_title Chemical communications (Cambridge, England)
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creator Tutusaus, Oscar
Kuwata, Hiroko
Counihan, Michael J
Mohtadi, Rana
description We synthesized Li and Na monocarborate salts with minimal protic impurities and reassessed their electrochemical windows. Na salts display higher efficiency for metal deposition/stripping and are more oxidatively stable than Li salts. This strong cation effect is rationalized in terms of differences in charge density between Li + and Na + cations. New insights into the electrochemical stability properties of monocarborate solid state electrolytes are enabled through a facile synthetic approach aimed to minimize parasitic side effects of impurities.
doi_str_mv 10.1039/d2cc06938e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Cations
Charge density
Electrolytes
Molten salt electrolytes
Sodium
Solid electrolytes
title Improved synthesis enables assessment of the electrochemical window of monocarborate solid state electrolytes
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