Treatment of spent decontamination solutions based on citric acid with composite polyacrylonitrile: transient metal oxidic nanoparticles sorbents
Composite sorbents based on the nanoparticles of NiO, NiO–TiO 2 and ZrO 2 –TiO 2 embedded in polyacrylonitrile were chosen for the treatment of spent decontamination solutions based on citric acid. Active oxidic materials were prepared by photoinduced synthesis (NiO, NiO–TiO 2 ) or hydrolytic method...
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| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2023-05, Vol.332 (5), p.1541-1547 |
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| container_title | Journal of radioanalytical and nuclear chemistry |
| container_volume | 332 |
| creator | Fišera, Ota Kareš, Jaroslav Prouzová Procházková, Lenka Čuba, Václav Vlk, Martin Kozempel, Ján Fialová, Kateřina Palušák, Martin |
| description | Composite sorbents based on the nanoparticles of NiO, NiO–TiO
2
and ZrO
2
–TiO
2
embedded in polyacrylonitrile were chosen for the treatment of spent decontamination solutions based on citric acid. Active oxidic materials were prepared by photoinduced synthesis (NiO, NiO–TiO
2
) or hydrolytic method (ZrO
2
–TiO
2
). Weight distribution ratios for radionuclides
241
Am,
60
Co,
137
Cs and
90
Sr/
90
Y were investigated during the experiments performed in pH range 2–12. High sorption capacities up to 9 mmol g
–1
for
137
Cs were found by sorption isotherm experiments. Dynamic experiments were carried out with simulated spent decontamination solutions containing citric acid. Elution of > 85% radionuclide waste with mineral acids or complexing agents was in 5–6 times lower volume compared to treated spent solution. |
| doi_str_mv | 10.1007/s10967-022-08598-2 |
| format | Article |
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2
and ZrO
2
–TiO
2
embedded in polyacrylonitrile were chosen for the treatment of spent decontamination solutions based on citric acid. Active oxidic materials were prepared by photoinduced synthesis (NiO, NiO–TiO
2
) or hydrolytic method (ZrO
2
–TiO
2
). Weight distribution ratios for radionuclides
241
Am,
60
Co,
137
Cs and
90
Sr/
90
Y were investigated during the experiments performed in pH range 2–12. High sorption capacities up to 9 mmol g
–1
for
137
Cs were found by sorption isotherm experiments. Dynamic experiments were carried out with simulated spent decontamination solutions containing citric acid. Elution of > 85% radionuclide waste with mineral acids or complexing agents was in 5–6 times lower volume compared to treated spent solution.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-022-08598-2</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Cesium 137 ; Cesium isotopes ; Chemistry ; Chemistry and Materials Science ; Citric acid ; Decontamination ; Diagnostic Radiology ; Ethylenediaminetetraacetic acid ; Hadrons ; Heavy Ions ; Inorganic acids ; Inorganic Chemistry ; Nanoparticles ; Nickel oxides ; Nuclear Chemistry ; Nuclear Physics ; Physical Chemistry ; Polyacrylonitrile ; Radioisotopes ; Sorbents ; Sorption ; Strontium 90 ; Titanium dioxide ; Titanium dioxide-Zirconia ; Zirconium dioxide</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2023-05, Vol.332 (5), p.1541-1547</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c309t-ef8eeb561cf1d099e46ea023306c01e33f04042adc32d30a35eb5f1a9bc496013</cites><orcidid>0000-0002-7093-1199</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-022-08598-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-022-08598-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27913,27914,41477,42546,51308</link.rule.ids></links><search><creatorcontrib>Fišera, Ota</creatorcontrib><creatorcontrib>Kareš, Jaroslav</creatorcontrib><creatorcontrib>Prouzová Procházková, Lenka</creatorcontrib><creatorcontrib>Čuba, Václav</creatorcontrib><creatorcontrib>Vlk, Martin</creatorcontrib><creatorcontrib>Kozempel, Ján</creatorcontrib><creatorcontrib>Fialová, Kateřina</creatorcontrib><creatorcontrib>Palušák, Martin</creatorcontrib><title>Treatment of spent decontamination solutions based on citric acid with composite polyacrylonitrile: transient metal oxidic nanoparticles sorbents</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>Composite sorbents based on the nanoparticles of NiO, NiO–TiO
2
and ZrO
2
–TiO
2
embedded in polyacrylonitrile were chosen for the treatment of spent decontamination solutions based on citric acid. Active oxidic materials were prepared by photoinduced synthesis (NiO, NiO–TiO
2
) or hydrolytic method (ZrO
2
–TiO
2
). Weight distribution ratios for radionuclides
241
Am,
60
Co,
137
Cs and
90
Sr/
90
Y were investigated during the experiments performed in pH range 2–12. High sorption capacities up to 9 mmol g
–1
for
137
Cs were found by sorption isotherm experiments. Dynamic experiments were carried out with simulated spent decontamination solutions containing citric acid. Elution of > 85% radionuclide waste with mineral acids or complexing agents was in 5–6 times lower volume compared to treated spent solution.</description><subject>Cesium 137</subject><subject>Cesium isotopes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Citric acid</subject><subject>Decontamination</subject><subject>Diagnostic Radiology</subject><subject>Ethylenediaminetetraacetic acid</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic acids</subject><subject>Inorganic Chemistry</subject><subject>Nanoparticles</subject><subject>Nickel oxides</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><subject>Polyacrylonitrile</subject><subject>Radioisotopes</subject><subject>Sorbents</subject><subject>Sorption</subject><subject>Strontium 90</subject><subject>Titanium dioxide</subject><subject>Titanium dioxide-Zirconia</subject><subject>Zirconium dioxide</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9UV1rHSEUlNBCbtP-gT4Jfd70qPtl3kLoFwT6kj7Lue4xNezqRr2092f0H9ftFvpWFBxkZo7jMPZWwLUAGN5nAbofGpCygbHTYyMv2EF0YwXDCC_YAaTqm25Q4pK9yvkJAPQ4qgP79ZAIy0Kh8Oh4XjcwkY2h4OIDFh8Dz3E-bSDzI2aaeL2yviRvOVo_8R--fOc2LmvMvhBf43xGm85zDBtpphteEobsN-uFCs48_vRTVQcMccVUvJ0p1ynpWCn5NXvpcM705u95xb59_PBw97m5__rpy93tfWMV6NKQG4mOXS-sExNoTW1PWFMq6C0IUspBC63EySo5KUDVVbYTqI-21T0IdcXe7b5ris8nysU8xVMKdaSRI0jo6u4r63pnPeJMxgcXaxhb10SLr99EriY0t0PbaTlItdnKXWBTzDmRM2vyC6azEWC2rszelaldmT9dGVlFahflSg6PlP695T-q30qum10</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Fišera, Ota</creator><creator>Kareš, Jaroslav</creator><creator>Prouzová Procházková, Lenka</creator><creator>Čuba, Václav</creator><creator>Vlk, Martin</creator><creator>Kozempel, Ján</creator><creator>Fialová, Kateřina</creator><creator>Palušák, Martin</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-7093-1199</orcidid></search><sort><creationdate>20230501</creationdate><title>Treatment of spent decontamination solutions based on citric acid with composite polyacrylonitrile: transient metal oxidic nanoparticles sorbents</title><author>Fišera, Ota ; Kareš, Jaroslav ; Prouzová Procházková, Lenka ; Čuba, Václav ; Vlk, Martin ; Kozempel, Ján ; Fialová, Kateřina ; Palušák, Martin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c309t-ef8eeb561cf1d099e46ea023306c01e33f04042adc32d30a35eb5f1a9bc496013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Cesium 137</topic><topic>Cesium isotopes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Citric acid</topic><topic>Decontamination</topic><topic>Diagnostic Radiology</topic><topic>Ethylenediaminetetraacetic acid</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic acids</topic><topic>Inorganic Chemistry</topic><topic>Nanoparticles</topic><topic>Nickel oxides</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><topic>Polyacrylonitrile</topic><topic>Radioisotopes</topic><topic>Sorbents</topic><topic>Sorption</topic><topic>Strontium 90</topic><topic>Titanium dioxide</topic><topic>Titanium dioxide-Zirconia</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fišera, Ota</creatorcontrib><creatorcontrib>Kareš, Jaroslav</creatorcontrib><creatorcontrib>Prouzová Procházková, Lenka</creatorcontrib><creatorcontrib>Čuba, Václav</creatorcontrib><creatorcontrib>Vlk, Martin</creatorcontrib><creatorcontrib>Kozempel, Ján</creatorcontrib><creatorcontrib>Fialová, Kateřina</creatorcontrib><creatorcontrib>Palušák, Martin</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fišera, Ota</au><au>Kareš, Jaroslav</au><au>Prouzová Procházková, Lenka</au><au>Čuba, Václav</au><au>Vlk, Martin</au><au>Kozempel, Ján</au><au>Fialová, Kateřina</au><au>Palušák, Martin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Treatment of spent decontamination solutions based on citric acid with composite polyacrylonitrile: transient metal oxidic nanoparticles sorbents</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2023-05-01</date><risdate>2023</risdate><volume>332</volume><issue>5</issue><spage>1541</spage><epage>1547</epage><pages>1541-1547</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>Composite sorbents based on the nanoparticles of NiO, NiO–TiO
2
and ZrO
2
–TiO
2
embedded in polyacrylonitrile were chosen for the treatment of spent decontamination solutions based on citric acid. Active oxidic materials were prepared by photoinduced synthesis (NiO, NiO–TiO
2
) or hydrolytic method (ZrO
2
–TiO
2
). Weight distribution ratios for radionuclides
241
Am,
60
Co,
137
Cs and
90
Sr/
90
Y were investigated during the experiments performed in pH range 2–12. High sorption capacities up to 9 mmol g
–1
for
137
Cs were found by sorption isotherm experiments. Dynamic experiments were carried out with simulated spent decontamination solutions containing citric acid. Elution of > 85% radionuclide waste with mineral acids or complexing agents was in 5–6 times lower volume compared to treated spent solution.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10967-022-08598-2</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-7093-1199</orcidid></addata></record> |
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| issn | 0236-5731 1588-2780 |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Cesium 137 Cesium isotopes Chemistry Chemistry and Materials Science Citric acid Decontamination Diagnostic Radiology Ethylenediaminetetraacetic acid Hadrons Heavy Ions Inorganic acids Inorganic Chemistry Nanoparticles Nickel oxides Nuclear Chemistry Nuclear Physics Physical Chemistry Polyacrylonitrile Radioisotopes Sorbents Sorption Strontium 90 Titanium dioxide Titanium dioxide-Zirconia Zirconium dioxide |
| title | Treatment of spent decontamination solutions based on citric acid with composite polyacrylonitrile: transient metal oxidic nanoparticles sorbents |
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