Copolymerization of l-lactide and ε-caprolactone using aluminum aminobisphenolate as an initiator: a quantum chemical study

The ring-opening homopolymerization and copolymerization of ε-caprolactone (CL) and l -lactide (LA) in the presence of an aluminum complex with aminobisphenolate ligand MeN{CH 2 [(3-Bu t )C 6 H 3 (2-O−)]} 2 Al−OMe (LAl−OMe) was modeled in terms of the density functional theory (DFT). The structures...

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Veröffentlicht in:	Russian chemical bulletin 2023-03, Vol.72 (3), p.602-616
Hauptverfasser:	Zabalov, M. V., Mankaev, B. N., Egorov, M. P., Karlov, S. S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Block copolymers Chemistry Chemistry and Materials Science Chemistry/Food Science Copolymerization Density functional theory Full Articles Initiation (polymerization) Initiators Inorganic Chemistry Organic Chemistry Polymerization Quantum chemistry Ring opening
Online-Zugang:	Volltext
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