Nucleophilic activation of the sulfur S8 cyclic form as a green chemistry tool
The review summarizes data on reactions with participation of the elemental cyclic form of sulfur S 8 , the key step of which is activation the eight-membered cycle S 8 by its opening under the action of various nucleophiles. This approach of involving sulfur in synthetic processes is promising from...
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| Veröffentlicht in: | Russian chemical bulletin 2023-02, Vol.72 (2), p.415-424 |
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| container_title | Russian chemical bulletin |
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| creator | Tarasova, N. P. Krivoborodov, E. G. Mezhuev, Ya. O. |
| description | The review summarizes data on reactions with participation of the elemental cyclic form of sulfur S
8
, the key step of which is activation the eight-membered cycle S
8
by its opening under the action of various nucleophiles. This approach of involving sulfur in synthetic processes is promising from the point of view of green chemistry, as it is an alternative to the energy-intensive method of thermal treatment with the formation of sulfur diradicals. Special attention is paid to the creation of reactive systems by the reaction of elemental sulfur with dimethyl phosphate ionic liquids. |
| doi_str_mv | 10.1007/s11172-023-3809-9 |
| format | Article |
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8
, the key step of which is activation the eight-membered cycle S
8
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, the key step of which is activation the eight-membered cycle S
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8
by its opening under the action of various nucleophiles. This approach of involving sulfur in synthetic processes is promising from the point of view of green chemistry, as it is an alternative to the energy-intensive method of thermal treatment with the formation of sulfur diradicals. Special attention is paid to the creation of reactive systems by the reaction of elemental sulfur with dimethyl phosphate ionic liquids.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11172-023-3809-9</doi><tpages>10</tpages></addata></record> |
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| ispartof | Russian chemical bulletin, 2023-02, Vol.72 (2), p.415-424 |
| issn | 1066-5285 1573-9171 |
| language | eng |
| recordid | cdi_proquest_journals_2800198627 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Heat treatment Inorganic Chemistry Ionic liquids Nucleophiles Organic Chemistry Review Sulfur |
| title | Nucleophilic activation of the sulfur S8 cyclic form as a green chemistry tool |
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