Plastic-derived sandwich-like porous carbon nanosheet-supported hexagonal carbon micro-flakes for K-ion storage

Novel sandwich-like porous carbon nanosheet-supported hexagonal carbon micro-flakes (WPWMC) are fabricated via a one-step hydrothermal route at 700 °C with polyethylene as the precursor and magnesium as the inducer. Through various characterizations, it is confirmed that the hexagonal carbon micro-f...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-04, Vol.59 (28), p.4169-4172
Hauptverfasser: Kong, Tianci, Qian, Yong, Li, Yang, Lin, Ning, Qian, Yitai
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container_issue 28
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container_title Chemical communications (Cambridge, England)
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creator Kong, Tianci
Qian, Yong
Li, Yang
Lin, Ning
Qian, Yitai
description Novel sandwich-like porous carbon nanosheet-supported hexagonal carbon micro-flakes (WPWMC) are fabricated via a one-step hydrothermal route at 700 °C with polyethylene as the precursor and magnesium as the inducer. Through various characterizations, it is confirmed that the hexagonal carbon micro-flakes exhibit (002) orientation, which exposes abundant edge active sites and shortens the K + transmission path. Moreover, the inside cross-linked carbon nanosheets with abundant pores can accelerate ion diffusion and increase the capacitive contribution. The WPWMC anode displays a high reversible capacity (528.7 mA h g −1 at 0.2 A g −1 ), good rate capability (152.7 mA h g −1 at 10 A g −1 ) and long-term cycle stability (112.1 mA h g −1 at 5 A g −1 after 10 000 cycles). Furthermore, the WPWMC//CMK-3 hybrid capacitor exhibits an energy density of 222.7 W h kg −1 at 446.2 W kg −1 . This work provides an idea for transforming waste plastic into value-added materials. Novel sandwich-like porous carbon nanosheet-supported hexagonal carbon micro-flakes are fabricated via a one-step hydrothermal route with waste polyethylene plastic.
doi_str_mv 10.1039/d3cc00473b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Carbon
Flakes
Ion diffusion
Ion storage
Magnesium
Nanosheets
Polyethylenes
title Plastic-derived sandwich-like porous carbon nanosheet-supported hexagonal carbon micro-flakes for K-ion storage
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