Zirconium ferrite incorporated zeolitic imidazolate framework-8: a suitable photocatalyst for degradation of dopamine and sulfamethoxazole in aqueous solution
The complete removal of pharmaceutical wastes from polluted water systems is a global challenge. Therefore, this study incorporates zirconium ferrite (ZrFe 2 O 4 ) into zeolitic imidazolate framework-8 (ZIF-8) to form ZrFe 2 O 4 @ZIF-8. The ZrFe 2 O 4 @ZIF-8 is a photocatalyst for removing dopamine...
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| Veröffentlicht in: | RSC advances 2023-03, Vol.13 (14), p.9563-9575 |
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| creator | Adewuyi, Adewale Ogunkunle, Olaoluwa A Oderinde, Rotimi A |
| description | The complete removal of pharmaceutical wastes from polluted water systems is a global challenge. Therefore, this study incorporates zirconium ferrite (ZrFe
2
O
4
) into zeolitic imidazolate framework-8 (ZIF-8) to form ZrFe
2
O
4
@ZIF-8. The ZrFe
2
O
4
@ZIF-8 is a photocatalyst for removing dopamine (DOP) and sulfamethoxazole (SMX) from an aqueous solution. The scanning electron micrograph revealed the surfaces of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 to be heterogeneous with irregularly shaped and sized particles. The transmission electron micrograph (TEM) images of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 showed an average particle size of 24.32 nm and 32.41 nm, respectively, with a bandgap of 2.10 eV (ZrFe
2
O
4
@ZIF-8) and 2.05 eV (ZrFe
2
O
4
). ZrFe
2
O
4
@ZIF-8 exhibited a better degradation capacity towards DOP and SMX than ZrFe
2
O
4
. ZrFe
2
O
4
@ZIF-8 expressed a complete (100%) degradation of DOP and SMX during the photodegradation process. Interestingly, the process involved both adsorption and photocatalytic degradation simultaneously. ZrFe
2
O
4
@ZIF-8 demonstrated high stability with a consistent regeneration capacity of 98.40% for DOP and 94.00% for SMX at the 10
th
cycle of treatment in a process described by pseudo-first-order kinetics. The study revealed ZrFe
2
O
4
@ZIF-8 as a promising photocatalyst for the purification of DOP and SMX-contaminated water systems.
The complete removal of pharmaceutical wastes from polluted water systems is a global challenge. |
| doi_str_mv | 10.1039/d3ra01055d |
| format | Article |
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2
O
4
) into zeolitic imidazolate framework-8 (ZIF-8) to form ZrFe
2
O
4
@ZIF-8. The ZrFe
2
O
4
@ZIF-8 is a photocatalyst for removing dopamine (DOP) and sulfamethoxazole (SMX) from an aqueous solution. The scanning electron micrograph revealed the surfaces of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 to be heterogeneous with irregularly shaped and sized particles. The transmission electron micrograph (TEM) images of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 showed an average particle size of 24.32 nm and 32.41 nm, respectively, with a bandgap of 2.10 eV (ZrFe
2
O
4
@ZIF-8) and 2.05 eV (ZrFe
2
O
4
). ZrFe
2
O
4
@ZIF-8 exhibited a better degradation capacity towards DOP and SMX than ZrFe
2
O
4
. ZrFe
2
O
4
@ZIF-8 expressed a complete (100%) degradation of DOP and SMX during the photodegradation process. Interestingly, the process involved both adsorption and photocatalytic degradation simultaneously. ZrFe
2
O
4
@ZIF-8 demonstrated high stability with a consistent regeneration capacity of 98.40% for DOP and 94.00% for SMX at the 10
th
cycle of treatment in a process described by pseudo-first-order kinetics. The study revealed ZrFe
2
O
4
@ZIF-8 as a promising photocatalyst for the purification of DOP and SMX-contaminated water systems.
The complete removal of pharmaceutical wastes from polluted water systems is a global challenge.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d3ra01055d</identifier><identifier>PMID: 36968036</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Antibiotics ; Aqueous solutions ; Chemistry ; Dopamine ; Electron micrographs ; Ferrites ; Metal-organic frameworks ; Oxidation ; Photocatalysis ; Photocatalysts ; Photodegradation ; Zeolites ; Zirconium</subject><ispartof>RSC advances, 2023-03, Vol.13 (14), p.9563-9575</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2023</rights><rights>This journal is © The Royal Society of Chemistry 2023 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c429t-df5774e150d28ad95c25d30354e04f4fd544ed007c36c97294250269016a79db3</citedby><cites>FETCH-LOGICAL-c429t-df5774e150d28ad95c25d30354e04f4fd544ed007c36c97294250269016a79db3</cites><orcidid>0000-0002-9703-7509</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10035307/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC10035307/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27923,27924,53790,53792</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36968036$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Adewuyi, Adewale</creatorcontrib><creatorcontrib>Ogunkunle, Olaoluwa A</creatorcontrib><creatorcontrib>Oderinde, Rotimi A</creatorcontrib><title>Zirconium ferrite incorporated zeolitic imidazolate framework-8: a suitable photocatalyst for degradation of dopamine and sulfamethoxazole in aqueous solution</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>The complete removal of pharmaceutical wastes from polluted water systems is a global challenge. Therefore, this study incorporates zirconium ferrite (ZrFe
2
O
4
) into zeolitic imidazolate framework-8 (ZIF-8) to form ZrFe
2
O
4
@ZIF-8. The ZrFe
2
O
4
@ZIF-8 is a photocatalyst for removing dopamine (DOP) and sulfamethoxazole (SMX) from an aqueous solution. The scanning electron micrograph revealed the surfaces of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 to be heterogeneous with irregularly shaped and sized particles. The transmission electron micrograph (TEM) images of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 showed an average particle size of 24.32 nm and 32.41 nm, respectively, with a bandgap of 2.10 eV (ZrFe
2
O
4
@ZIF-8) and 2.05 eV (ZrFe
2
O
4
). ZrFe
2
O
4
@ZIF-8 exhibited a better degradation capacity towards DOP and SMX than ZrFe
2
O
4
. ZrFe
2
O
4
@ZIF-8 expressed a complete (100%) degradation of DOP and SMX during the photodegradation process. Interestingly, the process involved both adsorption and photocatalytic degradation simultaneously. ZrFe
2
O
4
@ZIF-8 demonstrated high stability with a consistent regeneration capacity of 98.40% for DOP and 94.00% for SMX at the 10
th
cycle of treatment in a process described by pseudo-first-order kinetics. The study revealed ZrFe
2
O
4
@ZIF-8 as a promising photocatalyst for the purification of DOP and SMX-contaminated water systems.
The complete removal of pharmaceutical wastes from polluted water systems is a global challenge.</description><subject>Antibiotics</subject><subject>Aqueous solutions</subject><subject>Chemistry</subject><subject>Dopamine</subject><subject>Electron micrographs</subject><subject>Ferrites</subject><subject>Metal-organic frameworks</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Zeolites</subject><subject>Zirconium</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkk1v1DAQhi0EotXSC3eQJS4IKeCP2FlzQVXLl1QJCcGFS-T1R9fFyQTbAdofw2_F6Zal4IutmWfemdFrhB5S8pwSrl5YnjShRAh7Bx0y0sqGEanu3nofoKOcL0g9UlAm6X10wKWSa8LlIfr1JSQDY5gH7F1KoTgcRgNpgqSLs_jKQQwlGByGYPUVxBrFPunB_YD0tVm_xBrnORS9iQ5PWyhgdNHxMhfsIWHrzpO2ugQYMXhsYdJDGB3Wo61l0VedsoWfi_DSGOtvs4M54wxxXooeoHtex-yObu4V-vzm9aeTd83Zh7fvT47PGtMyVRrrRde1jgpi2VpbJQwTlhMuWkda33or2tZZQjrDpVEdUy0ThElFqNSdshu-Qq92utO8GZw1bixJx35KYdDpsgcd-n8zY9j25_C9p6R24aSrCk9vFBLUJXLph5CNi1GPy0Y96xTtiKqeVfTJf-gFzGms-11Ta0ZYVV2hZzvKJMg5Ob-fhpJ-sb4_5R-Pr60_rfDj2_Pv0T9GV-DRDkjZ7LN__w7_Dbahtyo</recordid><startdate>20230320</startdate><enddate>20230320</enddate><creator>Adewuyi, Adewale</creator><creator>Ogunkunle, Olaoluwa A</creator><creator>Oderinde, Rotimi A</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-9703-7509</orcidid></search><sort><creationdate>20230320</creationdate><title>Zirconium ferrite incorporated zeolitic imidazolate framework-8: a suitable photocatalyst for degradation of dopamine and sulfamethoxazole in aqueous solution</title><author>Adewuyi, Adewale ; Ogunkunle, Olaoluwa A ; Oderinde, Rotimi A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c429t-df5774e150d28ad95c25d30354e04f4fd544ed007c36c97294250269016a79db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Antibiotics</topic><topic>Aqueous solutions</topic><topic>Chemistry</topic><topic>Dopamine</topic><topic>Electron micrographs</topic><topic>Ferrites</topic><topic>Metal-organic frameworks</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Photodegradation</topic><topic>Zeolites</topic><topic>Zirconium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adewuyi, Adewale</creatorcontrib><creatorcontrib>Ogunkunle, Olaoluwa A</creatorcontrib><creatorcontrib>Oderinde, Rotimi A</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adewuyi, Adewale</au><au>Ogunkunle, Olaoluwa A</au><au>Oderinde, Rotimi A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zirconium ferrite incorporated zeolitic imidazolate framework-8: a suitable photocatalyst for degradation of dopamine and sulfamethoxazole in aqueous solution</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2023-03-20</date><risdate>2023</risdate><volume>13</volume><issue>14</issue><spage>9563</spage><epage>9575</epage><pages>9563-9575</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>The complete removal of pharmaceutical wastes from polluted water systems is a global challenge. Therefore, this study incorporates zirconium ferrite (ZrFe
2
O
4
) into zeolitic imidazolate framework-8 (ZIF-8) to form ZrFe
2
O
4
@ZIF-8. The ZrFe
2
O
4
@ZIF-8 is a photocatalyst for removing dopamine (DOP) and sulfamethoxazole (SMX) from an aqueous solution. The scanning electron micrograph revealed the surfaces of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 to be heterogeneous with irregularly shaped and sized particles. The transmission electron micrograph (TEM) images of ZrFe
2
O
4
and ZrFe
2
O
4
@ZIF-8 showed an average particle size of 24.32 nm and 32.41 nm, respectively, with a bandgap of 2.10 eV (ZrFe
2
O
4
@ZIF-8) and 2.05 eV (ZrFe
2
O
4
). ZrFe
2
O
4
@ZIF-8 exhibited a better degradation capacity towards DOP and SMX than ZrFe
2
O
4
. ZrFe
2
O
4
@ZIF-8 expressed a complete (100%) degradation of DOP and SMX during the photodegradation process. Interestingly, the process involved both adsorption and photocatalytic degradation simultaneously. ZrFe
2
O
4
@ZIF-8 demonstrated high stability with a consistent regeneration capacity of 98.40% for DOP and 94.00% for SMX at the 10
th
cycle of treatment in a process described by pseudo-first-order kinetics. The study revealed ZrFe
2
O
4
@ZIF-8 as a promising photocatalyst for the purification of DOP and SMX-contaminated water systems.
The complete removal of pharmaceutical wastes from polluted water systems is a global challenge.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>36968036</pmid><doi>10.1039/d3ra01055d</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-9703-7509</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2023-03, Vol.13 (14), p.9563-9575 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_journals_2791820200 |
| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Antibiotics Aqueous solutions Chemistry Dopamine Electron micrographs Ferrites Metal-organic frameworks Oxidation Photocatalysis Photocatalysts Photodegradation Zeolites Zirconium |
| title | Zirconium ferrite incorporated zeolitic imidazolate framework-8: a suitable photocatalyst for degradation of dopamine and sulfamethoxazole in aqueous solution |
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