Bulky NHC–Cobalt Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkynes

The hydrosilylation of alkynes is one of the most attractive and, at the same time, most challenging catalytic transformations, usually demanding the use of noble transition metals. We describe a catalytic system, based on cobalt(0) complex and bulky N-heterocyclic carbene (NHC) ligands, permitting...

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Veröffentlicht in:	Catalysts 2023-03, Vol.13 (3), p.510
Hauptverfasser:	Bołt, Małgorzata, Żak, Patrycja
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Catalysts Chemical reactions Cobalt Cobalt compounds Hydrogenation Hydrosilylation Ligands Selectivity Silane Silanes Solvents Steric hindrance Transition metals
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