Directed Palladium‐Catalyzed pseudo‐Anomeric C−H Functionalization of Glycal‐Type Substrates: Access to Unsymmetrical gem‐Diarylmethyl C‐Glycosides

Pd(II)‐Catalyzed, bidentate directing group (BDG)‐assisted C(sp2)−H functionalization of C2‐amido glycals onto the anomeric position is described as a contemporary method for the construction of various unsymmetrical gem‐diarylmethyl C‐glycosides. Thanks to a bidentate amidoquinoline‐type directing...

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Veröffentlicht in:	Advanced synthesis & catalysis 2023-03, Vol.365 (6), p.820-825
Hauptverfasser:	Dubey, Atul, Singh Chauhan, Neha, Azeem, Zanjila, Kumar Mandal, Pintu
Format:	Artikel
Sprache:	eng
Schlagworte:	Bidentate directing group C-Glycosides C2-Amido glycals Chemical reactions Cross coupling C−H Functionalization Glycosides Palladium Palladium catalysis Quinones Substrates
Online-Zugang:	Volltext
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