A Pair of Interconverting Cages Formed from Achiral Precursors Spontaneously Resolve into Homochiral Conformers

Without chiral induction the emergence of homochirality from achiral molecules is rather serendipitous, as the rationale is somewhat ambiguous. We herein provide a plausible solution. From achiral precursors are formed a pair of interconverting cage conformers that exhibit a C3‐axis as the only symm...

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Veröffentlicht in:	Angewandte Chemie 2023-03, Vol.135 (14), p.n/a
Hauptverfasser:	Zuo, Yong, Liu, Xiaoning, Fu, Enguang, Zhang, Shaodong
Format:	Artikel
Sprache:	eng
Schlagworte:	Cage Cages Chemistry Chirality Precursors Racemization Self-Assembly Superstructures Symmetry Symmetry Breaking
Online-Zugang:	Volltext
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