Rhenium recovery from roasting leachate of molybdenum concentrate by N-methylimidazole functionalized anion exchange resin
Developing the recovery technology of rhenium under the background of high molybdenum is of great significance to the recovery of rhenium resources in the leaching solution of molybdenum concentrate roasting. Herein, the resin LSL-N with adsorption capacity for rhenium and molybdenum was synthesized...
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| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2023-03, Vol.332 (3), p.747-760 |
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| container_title | Journal of radioanalytical and nuclear chemistry |
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| creator | Feng, Jiahui Li, Junhan Liao, Yuxin Liu, Fuping Li, Haonan Jiang, Qifeng Huang, Bin Wang, Yingcai Xiao, Lili Liu, Heng Su, Xuebin Hua, Rong |
| description | Developing the recovery technology of rhenium under the background of high molybdenum is of great significance to the recovery of rhenium resources in the leaching solution of molybdenum concentrate roasting. Herein, the resin LSL-N with adsorption capacity for rhenium and molybdenum was synthesized with
N
-methylimidazole as the functional group. The results of the batch adsorption test show that LSL-N resin has a good adsorption capacity for Re(VII) and Mo(VI), and the saturated adsorption capacity is 342.26 mg/g and 185.06 mg/g. The existing form of molybdenum (MO
4
2–
) in the solution was calculated by PHREEQC. The shorter hydrogen bond distance of MO
4
2–
@2LSL-N indicates that LSL-N resin has a stronger adsorption capacity for Mo(VI) when the active sites are sufficient, which is revealed by density functional theory (DFT) calculation. LSL-N resin can enrich Re(VII) and Mo(VI) in the eluent at the same time, with the maximum enrichment factors of 134.8 and 38.6. Re(VII) and Mo(VI) can be desorbed step by step with different desorbents, and molybdenum can be recovered as well as rhenium. |
| doi_str_mv | 10.1007/s10967-022-08755-7 |
| format | Article |
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N
-methylimidazole as the functional group. The results of the batch adsorption test show that LSL-N resin has a good adsorption capacity for Re(VII) and Mo(VI), and the saturated adsorption capacity is 342.26 mg/g and 185.06 mg/g. The existing form of molybdenum (MO
4
2–
) in the solution was calculated by PHREEQC. The shorter hydrogen bond distance of MO
4
2–
@2LSL-N indicates that LSL-N resin has a stronger adsorption capacity for Mo(VI) when the active sites are sufficient, which is revealed by density functional theory (DFT) calculation. LSL-N resin can enrich Re(VII) and Mo(VI) in the eluent at the same time, with the maximum enrichment factors of 134.8 and 38.6. Re(VII) and Mo(VI) can be desorbed step by step with different desorbents, and molybdenum can be recovered as well as rhenium.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-022-08755-7</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Adsorption ; Anion exchanging ; Chemistry ; Chemistry and Materials Science ; Density functional theory ; Density functionals ; Diagnostic Radiology ; Functional groups ; Hadrons ; Heavy Ions ; Hydrogen bonds ; Inorganic Chemistry ; Leaching ; Mathematical analysis ; Molybdenum ; Nuclear Chemistry ; Nuclear Physics ; Physical Chemistry ; Recovery ; Resins ; Rhenium ; Roasting</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2023-03, Vol.332 (3), p.747-760</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-66da27343b1d959d1312b294012475983a47005c3ad0c8c07e9dbf1b07ce7d4c3</citedby><cites>FETCH-LOGICAL-c358t-66da27343b1d959d1312b294012475983a47005c3ad0c8c07e9dbf1b07ce7d4c3</cites><orcidid>0000-0003-4594-493X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-022-08755-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-022-08755-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Feng, Jiahui</creatorcontrib><creatorcontrib>Li, Junhan</creatorcontrib><creatorcontrib>Liao, Yuxin</creatorcontrib><creatorcontrib>Liu, Fuping</creatorcontrib><creatorcontrib>Li, Haonan</creatorcontrib><creatorcontrib>Jiang, Qifeng</creatorcontrib><creatorcontrib>Huang, Bin</creatorcontrib><creatorcontrib>Wang, Yingcai</creatorcontrib><creatorcontrib>Xiao, Lili</creatorcontrib><creatorcontrib>Liu, Heng</creatorcontrib><creatorcontrib>Su, Xuebin</creatorcontrib><creatorcontrib>Hua, Rong</creatorcontrib><title>Rhenium recovery from roasting leachate of molybdenum concentrate by N-methylimidazole functionalized anion exchange resin</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>Developing the recovery technology of rhenium under the background of high molybdenum is of great significance to the recovery of rhenium resources in the leaching solution of molybdenum concentrate roasting. Herein, the resin LSL-N with adsorption capacity for rhenium and molybdenum was synthesized with
N
-methylimidazole as the functional group. The results of the batch adsorption test show that LSL-N resin has a good adsorption capacity for Re(VII) and Mo(VI), and the saturated adsorption capacity is 342.26 mg/g and 185.06 mg/g. The existing form of molybdenum (MO
4
2–
) in the solution was calculated by PHREEQC. The shorter hydrogen bond distance of MO
4
2–
@2LSL-N indicates that LSL-N resin has a stronger adsorption capacity for Mo(VI) when the active sites are sufficient, which is revealed by density functional theory (DFT) calculation. LSL-N resin can enrich Re(VII) and Mo(VI) in the eluent at the same time, with the maximum enrichment factors of 134.8 and 38.6. Re(VII) and Mo(VI) can be desorbed step by step with different desorbents, and molybdenum can be recovered as well as rhenium.</description><subject>Adsorption</subject><subject>Anion exchanging</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Density functional theory</subject><subject>Density functionals</subject><subject>Diagnostic Radiology</subject><subject>Functional groups</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Hydrogen bonds</subject><subject>Inorganic Chemistry</subject><subject>Leaching</subject><subject>Mathematical analysis</subject><subject>Molybdenum</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><subject>Recovery</subject><subject>Resins</subject><subject>Rhenium</subject><subject>Roasting</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU2PFCEQhonRxHH1D3gi8dwrH00XHDcbv5KNJkbPhIbqGTbdsEKPsefXy9om3gwHKHifoqpeQl5zds0Zg7eVMzNAx4TomAalOnhCDlxp3QnQ7Ck5MCGHToHkz8mLWu8ZY0ZreSCXrydM8bzQgj7_xLLRqeQWZVfXmI50RudPbkWaJ7rkeRsDpqb2OXlMa3l8GTf6uVtwPW1zXGJwlzwjnc7JrzEnN8cLBupSO1P81XKlI7bPakwvybPJzRVf_d2vyPf3777dfuzuvnz4dHtz13mp9NoNQ3ACZC9HHowygUsuRmF6xkUPymjpemBMeekC89ozQBPGiY8MPELovbwib_a8DyX_OGNd7X0-l1ZZtW04MEgDvWmq6111dDPamKbcuvNtBVxiaxen2O5voOeDAVC6AWIHfMm1FpzsQ4mLK5vlzD6aYndTbDPF_jHFQoPkDtUmbpMo_2r5D_Ub5o6RhA</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Feng, Jiahui</creator><creator>Li, Junhan</creator><creator>Liao, Yuxin</creator><creator>Liu, Fuping</creator><creator>Li, Haonan</creator><creator>Jiang, Qifeng</creator><creator>Huang, Bin</creator><creator>Wang, Yingcai</creator><creator>Xiao, Lili</creator><creator>Liu, Heng</creator><creator>Su, Xuebin</creator><creator>Hua, Rong</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4594-493X</orcidid></search><sort><creationdate>20230301</creationdate><title>Rhenium recovery from roasting leachate of molybdenum concentrate by N-methylimidazole functionalized anion exchange resin</title><author>Feng, Jiahui ; Li, Junhan ; Liao, Yuxin ; Liu, Fuping ; Li, Haonan ; Jiang, Qifeng ; Huang, Bin ; Wang, Yingcai ; Xiao, Lili ; Liu, Heng ; Su, Xuebin ; Hua, Rong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-66da27343b1d959d1312b294012475983a47005c3ad0c8c07e9dbf1b07ce7d4c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorption</topic><topic>Anion exchanging</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Density functional theory</topic><topic>Density functionals</topic><topic>Diagnostic Radiology</topic><topic>Functional groups</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Hydrogen bonds</topic><topic>Inorganic Chemistry</topic><topic>Leaching</topic><topic>Mathematical analysis</topic><topic>Molybdenum</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><topic>Recovery</topic><topic>Resins</topic><topic>Rhenium</topic><topic>Roasting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Jiahui</creatorcontrib><creatorcontrib>Li, Junhan</creatorcontrib><creatorcontrib>Liao, Yuxin</creatorcontrib><creatorcontrib>Liu, Fuping</creatorcontrib><creatorcontrib>Li, Haonan</creatorcontrib><creatorcontrib>Jiang, Qifeng</creatorcontrib><creatorcontrib>Huang, Bin</creatorcontrib><creatorcontrib>Wang, Yingcai</creatorcontrib><creatorcontrib>Xiao, Lili</creatorcontrib><creatorcontrib>Liu, Heng</creatorcontrib><creatorcontrib>Su, Xuebin</creatorcontrib><creatorcontrib>Hua, Rong</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Jiahui</au><au>Li, Junhan</au><au>Liao, Yuxin</au><au>Liu, Fuping</au><au>Li, Haonan</au><au>Jiang, Qifeng</au><au>Huang, Bin</au><au>Wang, Yingcai</au><au>Xiao, Lili</au><au>Liu, Heng</au><au>Su, Xuebin</au><au>Hua, Rong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rhenium recovery from roasting leachate of molybdenum concentrate by N-methylimidazole functionalized anion exchange resin</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>332</volume><issue>3</issue><spage>747</spage><epage>760</epage><pages>747-760</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>Developing the recovery technology of rhenium under the background of high molybdenum is of great significance to the recovery of rhenium resources in the leaching solution of molybdenum concentrate roasting. Herein, the resin LSL-N with adsorption capacity for rhenium and molybdenum was synthesized with
N
-methylimidazole as the functional group. The results of the batch adsorption test show that LSL-N resin has a good adsorption capacity for Re(VII) and Mo(VI), and the saturated adsorption capacity is 342.26 mg/g and 185.06 mg/g. The existing form of molybdenum (MO
4
2–
) in the solution was calculated by PHREEQC. The shorter hydrogen bond distance of MO
4
2–
@2LSL-N indicates that LSL-N resin has a stronger adsorption capacity for Mo(VI) when the active sites are sufficient, which is revealed by density functional theory (DFT) calculation. LSL-N resin can enrich Re(VII) and Mo(VI) in the eluent at the same time, with the maximum enrichment factors of 134.8 and 38.6. Re(VII) and Mo(VI) can be desorbed step by step with different desorbents, and molybdenum can be recovered as well as rhenium.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10967-022-08755-7</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0003-4594-493X</orcidid></addata></record> |
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| subjects | Adsorption Anion exchanging Chemistry Chemistry and Materials Science Density functional theory Density functionals Diagnostic Radiology Functional groups Hadrons Heavy Ions Hydrogen bonds Inorganic Chemistry Leaching Mathematical analysis Molybdenum Nuclear Chemistry Nuclear Physics Physical Chemistry Recovery Resins Rhenium Roasting |
| title | Rhenium recovery from roasting leachate of molybdenum concentrate by N-methylimidazole functionalized anion exchange resin |
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