Homologous series of layered tetradymite-like compounds in the Sb-Te and GeTe-Sb2Te3 systems
The structures of layered compounds in thenSb2 ·mSb2Te3 andnGeTe ·mSb2Te3 homologous series were studied by x-ray diffraction. GeSb6Te10 (n = 1,m = 3) was shown to have a 51-layer structure (sp. gr.) withc = 10.202(1) nm. In the structure of GeSb6Te10, Sb2Te3 five-layer slabs and GeSb2Te4 sevenlayer...
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Veröffentlicht in: | Inorganic materials 2000-08, Vol.36 (8), p.768-775 |
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creator | Shelimova, L. E. Karpinskii, O. G. Kretova, M. A. Kosyakov, V. I. Shestakov, V. A. Zemskov, V. S. Kuznetsov, F. A. |
description | The structures of layered compounds in thenSb2 ·mSb2Te3 andnGeTe ·mSb2Te3 homologous series were studied by x-ray diffraction. GeSb6Te10 (n = 1,m = 3) was shown to have a 51-layer structure (sp. gr.) withc = 10.202(1) nm. In the structure of GeSb6Te10, Sb2Te3 five-layer slabs and GeSb2Te4 sevenlayer slabs are stacked along thec axis in the ordered sequence -557 557 557-. Crystallographic data for this compound are presented. The specific and common structural features of the layered compounds in thenSb2 ·mSb2Te3 andnGeTe ·mSb2Te3 homologous series are discussed. |
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The specific and common structural features of the layered compounds in thenSb2 ·mSb2Te3 andnGeTe ·mSb2Te3 homologous series are discussed.</description><subject>Antimony telluride</subject><subject>Crystallography</subject><subject>Homology</subject><issn>0020-1685</issn><issn>1608-3172</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNpFkMtKw0AYRgdRsFY3PsGAO2F0LpnbUotthYKLxp0QJpk_mppk6kyyyNu3UsHVtzl8Bw5Ct4w-MEr14_OSci2NtPIMzZiihgim-TmaUcopYcrIS3SV0o5SmkljZ-hjHbrQhs8wJpwgNpBwqHHrJojg8QBDdH7qmgFI23wDrkK3D2PvE256PHwB3pYkB-x6j1eQA9mWPAeB05QG6NI1uqhdm-Dmb-foffmSL9Zk87Z6XTxtSMWlHoiT1tmac--NEibTlfW1clBlqpRGOQ7WC6eBOWs9zSqTOVVCBiVzuq6cFGKO7k6_-xh-RkhDsQtj7I_KgmujrDBc8CN1f6KqGFKKUBf72HQuTgWjxW-94r-eOADGZWHX</recordid><startdate>20000801</startdate><enddate>20000801</enddate><creator>Shelimova, L. E.</creator><creator>Karpinskii, O. G.</creator><creator>Kretova, M. A.</creator><creator>Kosyakov, V. 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E.</creatorcontrib><creatorcontrib>Karpinskii, O. G.</creatorcontrib><creatorcontrib>Kretova, M. A.</creatorcontrib><creatorcontrib>Kosyakov, V. I.</creatorcontrib><creatorcontrib>Shestakov, V. A.</creatorcontrib><creatorcontrib>Zemskov, V. S.</creatorcontrib><creatorcontrib>Kuznetsov, F. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Inorganic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shelimova, L. E.</au><au>Karpinskii, O. G.</au><au>Kretova, M. A.</au><au>Kosyakov, V. I.</au><au>Shestakov, V. A.</au><au>Zemskov, V. S.</au><au>Kuznetsov, F. 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title | Homologous series of layered tetradymite-like compounds in the Sb-Te and GeTe-Sb2Te3 systems |
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