Spectral study of the complexation of Nd(III) with glutathione reduced (GSH) in the presence and absence of Zn(II) in aquated organic solvents
Studies on the difference in energy parameters and comparative absorption spectrophotometry involving 4f-4f transitions on Nd(III) and glutathione reduced (GSH) in the absence and presence of Zn(II) have been carried out in aquated organic solvents (50 : 50) like methanol, dioxane, acetonitrile and...
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| Veröffentlicht in: | Journal of Chemical Sciences 2004-11, Vol.116 (6), p.303-309 |
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| container_issue | 6 |
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| container_title | Journal of Chemical Sciences |
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| creator | Singh, Th. David Sumitra, Ch Rajmuhon Singh, N. Indira Devi, M. |
| description | Studies on the difference in energy parameters and comparative absorption spectrophotometry involving 4f-4f transitions on Nd(III) and glutathione reduced (GSH) in the absence and presence of Zn(II) have been carried out in aquated organic solvents (50 : 50) like methanol, dioxane, acetonitrile and dimethylformamide. Variations in the spectral energy parameters — Slater-Condon (Fk) factor, Lande spin-orbit coupling constant (ξ4f), nephelauxetic ratio (β), bonding parameter (b1/2) and percent covalency (δ) — are calculated and correlated with binding of Nd(III) with GSH in presence and absence of Zn(II). |
| doi_str_mv | 10.1007/BF02711430 |
| format | Article |
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Variations in the spectral energy parameters — Slater-Condon (Fk) factor, Lande spin-orbit coupling constant (ξ4f), nephelauxetic ratio (β), bonding parameter (b1/2) and percent covalency (δ) — are calculated and correlated with binding of Nd(III) with GSH in presence and absence of Zn(II).</description><identifier>ISSN: 0253-4134</identifier><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/BF02711430</identifier><language>eng</language><publisher>Dordrecht: Springer Nature B.V</publisher><subject>Acetonitrile ; Dimethylformamide ; Glutathione ; Mathematical analysis ; Parameters ; Solvents ; Spectrophotometry ; Spin-orbit interactions</subject><ispartof>Journal of Chemical Sciences, 2004-11, Vol.116 (6), p.303-309</ispartof><rights>Indian Academy of Sciences 2004.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c295t-9e48ada086738ea32f392a3081a3be3455b7db733ef0aca3b82c5b1b0e87c8123</citedby><cites>FETCH-LOGICAL-c295t-9e48ada086738ea32f392a3081a3be3455b7db733ef0aca3b82c5b1b0e87c8123</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27915,27916</link.rule.ids></links><search><creatorcontrib>Singh, Th. 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Variations in the spectral energy parameters — Slater-Condon (Fk) factor, Lande spin-orbit coupling constant (ξ4f), nephelauxetic ratio (β), bonding parameter (b1/2) and percent covalency (δ) — are calculated and correlated with binding of Nd(III) with GSH in presence and absence of Zn(II).</description><subject>Acetonitrile</subject><subject>Dimethylformamide</subject><subject>Glutathione</subject><subject>Mathematical analysis</subject><subject>Parameters</subject><subject>Solvents</subject><subject>Spectrophotometry</subject><subject>Spin-orbit interactions</subject><issn>0253-4134</issn><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNpFUF1PwjAUbYwmIvriL2jiC5hM296NlkclAkuIPqAvvixddwcjYxttp_In_M0OMfHpnpx7PpJDyDVnd5wxef84ZUJyHgI7IT02lhBIzuC0wyKCIOQQnpML5zaMgQol9Mj3skHjrS6p8222p3VO_RqpqbdNiV_aF3V14J6zQRzHQ_pZ-DVdla3Xft29kFrMWoMZHcyW8yEtql93Y9FhZZDqKqM6PeIu5b0aHEI6ld612ne22q50VRjq6vIDK-8uyVmuS4dXf7dP3qZPr5N5sHiZxZOHRWDEOPLBGEOlM83USIJCDSKHsdDAFNeQIoRRlMoslQCYM206TgkTpTxlqKRRXECf3BxzG1vvWnQ-2dStrbrKREg1iiIQnbtPbo8qY2vnLOZJY4uttvuEs-Swd_K_N_wAyedx3A</recordid><startdate>20041101</startdate><enddate>20041101</enddate><creator>Singh, Th. 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David ; Sumitra, Ch ; Rajmuhon Singh, N. ; Indira Devi, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c295t-9e48ada086738ea32f392a3081a3be3455b7db733ef0aca3b82c5b1b0e87c8123</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Acetonitrile</topic><topic>Dimethylformamide</topic><topic>Glutathione</topic><topic>Mathematical analysis</topic><topic>Parameters</topic><topic>Solvents</topic><topic>Spectrophotometry</topic><topic>Spin-orbit interactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Th. David</creatorcontrib><creatorcontrib>Sumitra, Ch</creatorcontrib><creatorcontrib>Rajmuhon Singh, N.</creatorcontrib><creatorcontrib>Indira Devi, M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of Chemical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Th. 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Variations in the spectral energy parameters — Slater-Condon (Fk) factor, Lande spin-orbit coupling constant (ξ4f), nephelauxetic ratio (β), bonding parameter (b1/2) and percent covalency (δ) — are calculated and correlated with binding of Nd(III) with GSH in presence and absence of Zn(II).</abstract><cop>Dordrecht</cop><pub>Springer Nature B.V</pub><doi>10.1007/BF02711430</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 0253-4134 |
| ispartof | Journal of Chemical Sciences, 2004-11, Vol.116 (6), p.303-309 |
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| language | eng |
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| source | Alma/SFX Local Collection; Free Full-Text Journals in Chemistry; EZB Electronic Journals Library; SpringerLink Journals - AutoHoldings |
| subjects | Acetonitrile Dimethylformamide Glutathione Mathematical analysis Parameters Solvents Spectrophotometry Spin-orbit interactions |
| title | Spectral study of the complexation of Nd(III) with glutathione reduced (GSH) in the presence and absence of Zn(II) in aquated organic solvents |
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