Synthesis and properties of Bi1.6Pb2-xSr2-xCa2Cu3Oy

Bi1.6Pb0.4Sr2-xCa2Cu3Oy (x = 0, 0.2, 0.4) high-Tc materials were prepared from oxide-carbonate mixtures and presynthesized mixed oxides. The 2223 superconducting phase was found to be formed most rapidly in thex = 0.4 sample if the Pb-and Ca-containing starting reagents were separated in the initial...

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Veröffentlicht in:Inorganic materials 2000-02, Vol.36 (2), p.176-179
Hauptverfasser: Sokolov, V. V., Trushnikova, L. N., Blinov, A. G., Starikov, M. A., Uskov, E. M., Lisoivan, V. I.
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container_end_page 179
container_issue 2
container_start_page 176
container_title Inorganic materials
container_volume 36
creator Sokolov, V. V.
Trushnikova, L. N.
Blinov, A. G.
Starikov, M. A.
Uskov, E. M.
Lisoivan, V. I.
description Bi1.6Pb0.4Sr2-xCa2Cu3Oy (x = 0, 0.2, 0.4) high-Tc materials were prepared from oxide-carbonate mixtures and presynthesized mixed oxides. The 2223 superconducting phase was found to be formed most rapidly in thex = 0.4 sample if the Pb-and Ca-containing starting reagents were separated in the initial stage of synthesis. The highest superconducting transition temperature, Tc(R = 0) = 104.3 K, was attained in the stoichiometric 2223 material. The materials were characterized by electrical resistivity, magnetic susceptibility, and Hall effect measurements. The Hall data were used to evaluate carrier concentration and mobility. The 77-K resistivity of the materials was measured as a function of magnetic field.
doi_str_mv 10.1007/BF02758023
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subjects Carrier density
Chemical synthesis
Electrical resistivity
Hall effect
Magnetic permeability
Mixed oxides
Reagents
Superconductivity
Transition temperature
title Synthesis and properties of Bi1.6Pb2-xSr2-xCa2Cu3Oy
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