Kinetics of the liquid-phase oxidation of cyclooctene in the presence of MnO2

The kinetics of the liquid-phase oxidation of cyclooctene by molecular oxygen in the presence of a MnC2 catalyst is studied. It is found that MnC2 is an initiator of this reaction and has no effect on the steps of chain propagation and termination. The oxidation occurs by a radical chain mechanism w...

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Veröffentlicht in:	Kinetics and catalysis 2000-07, Vol.41 (4), p.457-461
Hauptverfasser:	Chernyak, B. I., Nikipanchuk, M. V., Mishchenko, G. M., Trach, Yu. B., Pyrig, I. Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Chains Kinetics Liquid phase oxidation Liquid phases Manganese dioxide Oxygen Reaction kinetics
Online-Zugang:	Volltext
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