Imbuing carbon fibers with electrochemical storage properties without compromising fiber‐to‐matrix adhesion
The application of carbon fiber in structural batteries and capacitors may be advanced by increasing the surface functionality of these materials. Herein, we describe the electrochemical surface modification to attach ferrocene containing polymers to the carbon fiber surface. This was carried out us...
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| Veröffentlicht in: | Polymer composites 2023-03, Vol.44 (3), p.1902-1910 |
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| container_issue | 3 |
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| container_title | Polymer composites |
| container_volume | 44 |
| creator | Stanfield, Melissa K. Dharamasiri, Bhagya Randall, James D. Stojcevski, Filip Qin, Si (Alex) Razal, Joselito M. Eyckens, Daniel J. Henderson, Luke C. |
| description | The application of carbon fiber in structural batteries and capacitors may be advanced by increasing the surface functionality of these materials. Herein, we describe the electrochemical surface modification to attach ferrocene containing polymers to the carbon fiber surface. This was carried out using a ferrocene monomer in isolation, and as part of a blend in acrylamide. The ferrocene‐containing polymers significantly improve the interfacial shear strength (+180%) in an epoxy resin and improves the tensile strength of the fiber by more than 10%, compared to a control sample (modified fiber 3.81 ± 0.08 GPa; pristine fiber 3.56 ± 0.09 GPa, respectively). These polymers also improve the specific capacitance of the fiber (1250 mF g−1) compared to pristine (113 mF g−1). An excellent retention of capacitance (80%) was also found for these modified materials via galvanostatic charge–discharge stability tests after 1000 charge–discharge cycles. |
| doi_str_mv | 10.1002/pc.27214 |
| format | Article |
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Herein, we describe the electrochemical surface modification to attach ferrocene containing polymers to the carbon fiber surface. This was carried out using a ferrocene monomer in isolation, and as part of a blend in acrylamide. The ferrocene‐containing polymers significantly improve the interfacial shear strength (+180%) in an epoxy resin and improves the tensile strength of the fiber by more than 10%, compared to a control sample (modified fiber 3.81 ± 0.08 GPa; pristine fiber 3.56 ± 0.09 GPa, respectively). These polymers also improve the specific capacitance of the fiber (1250 mF g−1) compared to pristine (113 mF g−1). 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An excellent retention of capacitance (80%) was also found for these modified materials via galvanostatic charge–discharge stability tests after 1000 charge–discharge cycles.</description><subject>Acrylamide</subject><subject>Capacitance</subject><subject>carbon fiber</subject><subject>Carbon fiber reinforced plastics</subject><subject>Charge materials</subject><subject>composite</subject><subject>Discharge</subject><subject>Epoxy resins</subject><subject>Fiber-matrix adhesion</subject><subject>interface</subject><subject>Interfacial shear strength</subject><subject>Polymers</subject><subject>Stability tests</subject><subject>surface modification</subject><subject>Tensile strength</subject><issn>0272-8397</issn><issn>1548-0569</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><recordid>eNp10M1KAzEQB_AgCtYq-AgBL162JptssnuU4kehoAc9hySbtCm7zZrsUnvzEXxGn8S069XLDAw__jMMANcYzTBC-V2nZznPMT0BE1zQMkMFq07BBKVhVpKKn4OLGDdJYsbIBPhFqwa3XUEtg_JbaJ0yIcKd69fQNEb3weu1aZ2WDYy9D3JlYBd8Z0LvzOj80EPt2zRtXTxEHTN-vr57n0or--A-oazXJjq_vQRnVjbRXP31KXh_fHibP2fLl6fF_H6ZaZJzmmmjCl3XmGNbI6aZtoyUmhe00FTSqqioolxhYxGvkaGq1tZSVSJSVhVBhJIpuBlz01kfg4m92PghbNNKkfOSEVzmrErqdlQ6-BiDsaILrpVhLzASh3eKTovjOxPNRrpzjdn_68TrfPS_j016Rg</recordid><startdate>202303</startdate><enddate>202303</enddate><creator>Stanfield, Melissa K.</creator><creator>Dharamasiri, Bhagya</creator><creator>Randall, James D.</creator><creator>Stojcevski, Filip</creator><creator>Qin, Si (Alex)</creator><creator>Razal, Joselito M.</creator><creator>Eyckens, Daniel J.</creator><creator>Henderson, Luke C.</creator><general>John Wiley & Sons, Inc</general><general>Blackwell Publishing Ltd</general><scope>24P</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-4244-2056</orcidid></search><sort><creationdate>202303</creationdate><title>Imbuing carbon fibers with electrochemical storage properties without compromising fiber‐to‐matrix adhesion</title><author>Stanfield, Melissa K. ; Dharamasiri, Bhagya ; Randall, James D. ; Stojcevski, Filip ; Qin, Si (Alex) ; Razal, Joselito M. ; Eyckens, Daniel J. ; Henderson, Luke C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3274-ceb5cdd171fd06c6cf638c7545c4a49594b47b1ef07d0e4bdcff4b80389930343</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Acrylamide</topic><topic>Capacitance</topic><topic>carbon fiber</topic><topic>Carbon fiber reinforced plastics</topic><topic>Charge materials</topic><topic>composite</topic><topic>Discharge</topic><topic>Epoxy resins</topic><topic>Fiber-matrix adhesion</topic><topic>interface</topic><topic>Interfacial shear strength</topic><topic>Polymers</topic><topic>Stability tests</topic><topic>surface modification</topic><topic>Tensile strength</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Stanfield, Melissa K.</creatorcontrib><creatorcontrib>Dharamasiri, Bhagya</creatorcontrib><creatorcontrib>Randall, James D.</creatorcontrib><creatorcontrib>Stojcevski, Filip</creatorcontrib><creatorcontrib>Qin, Si (Alex)</creatorcontrib><creatorcontrib>Razal, Joselito M.</creatorcontrib><creatorcontrib>Eyckens, Daniel J.</creatorcontrib><creatorcontrib>Henderson, Luke C.</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer composites</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Stanfield, Melissa K.</au><au>Dharamasiri, Bhagya</au><au>Randall, James D.</au><au>Stojcevski, Filip</au><au>Qin, Si (Alex)</au><au>Razal, Joselito M.</au><au>Eyckens, Daniel J.</au><au>Henderson, Luke C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Imbuing carbon fibers with electrochemical storage properties without compromising fiber‐to‐matrix adhesion</atitle><jtitle>Polymer composites</jtitle><date>2023-03</date><risdate>2023</risdate><volume>44</volume><issue>3</issue><spage>1902</spage><epage>1910</epage><pages>1902-1910</pages><issn>0272-8397</issn><eissn>1548-0569</eissn><abstract>The application of carbon fiber in structural batteries and capacitors may be advanced by increasing the surface functionality of these materials. Herein, we describe the electrochemical surface modification to attach ferrocene containing polymers to the carbon fiber surface. This was carried out using a ferrocene monomer in isolation, and as part of a blend in acrylamide. The ferrocene‐containing polymers significantly improve the interfacial shear strength (+180%) in an epoxy resin and improves the tensile strength of the fiber by more than 10%, compared to a control sample (modified fiber 3.81 ± 0.08 GPa; pristine fiber 3.56 ± 0.09 GPa, respectively). These polymers also improve the specific capacitance of the fiber (1250 mF g−1) compared to pristine (113 mF g−1). 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acrylamide Capacitance carbon fiber Carbon fiber reinforced plastics Charge materials composite Discharge Epoxy resins Fiber-matrix adhesion interface Interfacial shear strength Polymers Stability tests surface modification Tensile strength |
| title | Imbuing carbon fibers with electrochemical storage properties without compromising fiber‐to‐matrix adhesion |
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