Evidence of AlII Radical Addition to Benzene

Electrophilic AlIII species have long dominated the aluminum reactivity towards arenes. Recently, nucleophilic low‐valent AlI aluminyl anions have showcased oxidative additions towards arenes C−C and/or C−H bonds. Herein, we communicate compelling evidence of an AlII radical addition reaction to the...

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Veröffentlicht in:	Angewandte Chemie 2023-03, Vol.135 (13), p.n/a
Hauptverfasser:	Mandal, Debdeep, Demirer, T. Ilgin, Sergeieva, Tetiana, Morgenstern, Bernd, Wiedemann, Haakon T. A., Kay, Christopher W. M., Andrada, Diego M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Anions Aromatic compounds Benzene Chemistry Crystallography Dienes EPR Spectroscopy Hydrogen bonds Low-Valent Compounds Radicals Reduction Spectroscopy Structure Elucidation
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