Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H2O2 over Defective Zn3In2S6
One of the most sustainable and promising approaches for hydrogen peroxide (H2O2) production in a low‐cost and environment‐friendly way is photosynthesis, which, however, suffers from poor carrier utilization and low H2O2 productivity. The addition of proton donors such as isopropanol or ethanol can...
Gespeichert in:
Veröffentlicht in: | Advanced materials (Weinheim) 2023-03, Vol.35 (10), p.n/a |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | n/a |
---|---|
container_issue | 10 |
container_start_page | |
container_title | Advanced materials (Weinheim) |
container_volume | 35 |
creator | Luo, Juanjuan Wei, Xinfa Qiao, Yang Wu, Chenyao Li, Lanxin Chen, Lisong Shi, Jianlin |
description | One of the most sustainable and promising approaches for hydrogen peroxide (H2O2) production in a low‐cost and environment‐friendly way is photosynthesis, which, however, suffers from poor carrier utilization and low H2O2 productivity. The addition of proton donors such as isopropanol or ethanol can increase H2O2 production, which, unfortunately, will inevitably elevate the entire cost while wasting the oxidizing power of holes (h+). Herein, the tetrahydroisoquinolines (THIQs) is employed as a distinctive proton donor for the thermodynamically feasible and selective semi‐dehydrogenation reaction to highly valuable dihydroisoquinolines (DHIQs), and meanwhile, to couple with and promote H2O2 generation in one photoredox reaction under the photocatalysis by dual‐functional Zn3In2S6 photocatalyst. Surprisingly, the suitably defective Zn3In2S6 offers an excellent and near‐stoichiometric co‐production performance of H2O2 and DHIQs at unprecedentedly high rates of 66.4 and 62.1 mmol h‐1 g‐1 under visible light (λ ≥ 400 nm), respectively, which outperforms all the previously available reports even though sacrificial agents were employed in those reports. Additionally, photocatalytic redox reaction mechanism demonstrates that H2O2 can be generated through multiple pathways, highlighting the synergistic effect among ROS (·O2‐ and 1O2), h+ and proton donor, which has been ignored in previous studies.
A dual‐functional and defective Zn3In2S6 photocatalyst is developed for the simultaneous efficient photocatalytic co‐syntheses of dihydroisoquinoline and H2O2, which shows the highest rate for both reactions up to date. |
doi_str_mv | 10.1002/adma.202210110 |
format | Article |
fullrecord | <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_2785215048</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2785215048</sourcerecordid><originalsourceid>FETCH-LOGICAL-p2330-f5b85b8686e5129323d645944d55ebb2b5e26e94ca265f450cb9519ab57a08aa3</originalsourceid><addsrcrecordid>eNo9kF1LAkEUhocoyKzbrge6Xjtz5sOdS9FKwVCoboIYZp1ZXNEdm1017_oJ_cZ-SSuGcODwwsN7Dg8htww6DADvrVvZDgIiA8bgjLSYRJYI0PKctEBzmWgl0ktyVVULANAKVIt8TOehDtG78PX7_TONYRVq72g_HJPbzOoilDTkdFDM9y6Gogqfm6IMy6L01JaODnGCNGx9pAOf-wbfevpe8lGJL-qaXOR2Wfmb_90mb48Pr_1hMp48jfq9cbJGziHJZZY2o1LlJUPNkTslpBbCSemzDDPpUXktZhaVzIWEWaYl0zaTXQuptbxN7o6969h856vaLMImls1Jg9200SBBpA2lj9SuWPq9WcdiZePeMDAHf-bgz5z8md7guXdK_A9Ag2db</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2785215048</pqid></control><display><type>article</type><title>Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H2O2 over Defective Zn3In2S6</title><source>Access via Wiley Online Library</source><creator>Luo, Juanjuan ; Wei, Xinfa ; Qiao, Yang ; Wu, Chenyao ; Li, Lanxin ; Chen, Lisong ; Shi, Jianlin</creator><creatorcontrib>Luo, Juanjuan ; Wei, Xinfa ; Qiao, Yang ; Wu, Chenyao ; Li, Lanxin ; Chen, Lisong ; Shi, Jianlin</creatorcontrib><description>One of the most sustainable and promising approaches for hydrogen peroxide (H2O2) production in a low‐cost and environment‐friendly way is photosynthesis, which, however, suffers from poor carrier utilization and low H2O2 productivity. The addition of proton donors such as isopropanol or ethanol can increase H2O2 production, which, unfortunately, will inevitably elevate the entire cost while wasting the oxidizing power of holes (h+). Herein, the tetrahydroisoquinolines (THIQs) is employed as a distinctive proton donor for the thermodynamically feasible and selective semi‐dehydrogenation reaction to highly valuable dihydroisoquinolines (DHIQs), and meanwhile, to couple with and promote H2O2 generation in one photoredox reaction under the photocatalysis by dual‐functional Zn3In2S6 photocatalyst. Surprisingly, the suitably defective Zn3In2S6 offers an excellent and near‐stoichiometric co‐production performance of H2O2 and DHIQs at unprecedentedly high rates of 66.4 and 62.1 mmol h‐1 g‐1 under visible light (λ ≥ 400 nm), respectively, which outperforms all the previously available reports even though sacrificial agents were employed in those reports. Additionally, photocatalytic redox reaction mechanism demonstrates that H2O2 can be generated through multiple pathways, highlighting the synergistic effect among ROS (·O2‐ and 1O2), h+ and proton donor, which has been ignored in previous studies.
A dual‐functional and defective Zn3In2S6 photocatalyst is developed for the simultaneous efficient photocatalytic co‐syntheses of dihydroisoquinoline and H2O2, which shows the highest rate for both reactions up to date.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.202210110</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Dehydrogenation ; dual‐functional semiconductors ; Ethanol ; Hydrogen peroxide ; hydrogen peroxide evolution ; Materials science ; Oxidation ; Photocatalysis ; Photosynthesis ; Protons ; Reaction mechanisms ; reactive oxygen species ; Reagents ; Redox reactions ; Synergistic effect ; value‐added chemicals</subject><ispartof>Advanced materials (Weinheim), 2023-03, Vol.35 (10), p.n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-8790-195X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.202210110$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.202210110$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Luo, Juanjuan</creatorcontrib><creatorcontrib>Wei, Xinfa</creatorcontrib><creatorcontrib>Qiao, Yang</creatorcontrib><creatorcontrib>Wu, Chenyao</creatorcontrib><creatorcontrib>Li, Lanxin</creatorcontrib><creatorcontrib>Chen, Lisong</creatorcontrib><creatorcontrib>Shi, Jianlin</creatorcontrib><title>Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H2O2 over Defective Zn3In2S6</title><title>Advanced materials (Weinheim)</title><description>One of the most sustainable and promising approaches for hydrogen peroxide (H2O2) production in a low‐cost and environment‐friendly way is photosynthesis, which, however, suffers from poor carrier utilization and low H2O2 productivity. The addition of proton donors such as isopropanol or ethanol can increase H2O2 production, which, unfortunately, will inevitably elevate the entire cost while wasting the oxidizing power of holes (h+). Herein, the tetrahydroisoquinolines (THIQs) is employed as a distinctive proton donor for the thermodynamically feasible and selective semi‐dehydrogenation reaction to highly valuable dihydroisoquinolines (DHIQs), and meanwhile, to couple with and promote H2O2 generation in one photoredox reaction under the photocatalysis by dual‐functional Zn3In2S6 photocatalyst. Surprisingly, the suitably defective Zn3In2S6 offers an excellent and near‐stoichiometric co‐production performance of H2O2 and DHIQs at unprecedentedly high rates of 66.4 and 62.1 mmol h‐1 g‐1 under visible light (λ ≥ 400 nm), respectively, which outperforms all the previously available reports even though sacrificial agents were employed in those reports. Additionally, photocatalytic redox reaction mechanism demonstrates that H2O2 can be generated through multiple pathways, highlighting the synergistic effect among ROS (·O2‐ and 1O2), h+ and proton donor, which has been ignored in previous studies.
A dual‐functional and defective Zn3In2S6 photocatalyst is developed for the simultaneous efficient photocatalytic co‐syntheses of dihydroisoquinoline and H2O2, which shows the highest rate for both reactions up to date.</description><subject>Dehydrogenation</subject><subject>dual‐functional semiconductors</subject><subject>Ethanol</subject><subject>Hydrogen peroxide</subject><subject>hydrogen peroxide evolution</subject><subject>Materials science</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Photosynthesis</subject><subject>Protons</subject><subject>Reaction mechanisms</subject><subject>reactive oxygen species</subject><subject>Reagents</subject><subject>Redox reactions</subject><subject>Synergistic effect</subject><subject>value‐added chemicals</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kF1LAkEUhocoyKzbrge6Xjtz5sOdS9FKwVCoboIYZp1ZXNEdm1017_oJ_cZ-SSuGcODwwsN7Dg8htww6DADvrVvZDgIiA8bgjLSYRJYI0PKctEBzmWgl0ktyVVULANAKVIt8TOehDtG78PX7_TONYRVq72g_HJPbzOoilDTkdFDM9y6Gogqfm6IMy6L01JaODnGCNGx9pAOf-wbfevpe8lGJL-qaXOR2Wfmb_90mb48Pr_1hMp48jfq9cbJGziHJZZY2o1LlJUPNkTslpBbCSemzDDPpUXktZhaVzIWEWaYl0zaTXQuptbxN7o6969h856vaLMImls1Jg9200SBBpA2lj9SuWPq9WcdiZePeMDAHf-bgz5z8md7guXdK_A9Ag2db</recordid><startdate>20230309</startdate><enddate>20230309</enddate><creator>Luo, Juanjuan</creator><creator>Wei, Xinfa</creator><creator>Qiao, Yang</creator><creator>Wu, Chenyao</creator><creator>Li, Lanxin</creator><creator>Chen, Lisong</creator><creator>Shi, Jianlin</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8790-195X</orcidid></search><sort><creationdate>20230309</creationdate><title>Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H2O2 over Defective Zn3In2S6</title><author>Luo, Juanjuan ; Wei, Xinfa ; Qiao, Yang ; Wu, Chenyao ; Li, Lanxin ; Chen, Lisong ; Shi, Jianlin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2330-f5b85b8686e5129323d645944d55ebb2b5e26e94ca265f450cb9519ab57a08aa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Dehydrogenation</topic><topic>dual‐functional semiconductors</topic><topic>Ethanol</topic><topic>Hydrogen peroxide</topic><topic>hydrogen peroxide evolution</topic><topic>Materials science</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Photosynthesis</topic><topic>Protons</topic><topic>Reaction mechanisms</topic><topic>reactive oxygen species</topic><topic>Reagents</topic><topic>Redox reactions</topic><topic>Synergistic effect</topic><topic>value‐added chemicals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luo, Juanjuan</creatorcontrib><creatorcontrib>Wei, Xinfa</creatorcontrib><creatorcontrib>Qiao, Yang</creatorcontrib><creatorcontrib>Wu, Chenyao</creatorcontrib><creatorcontrib>Li, Lanxin</creatorcontrib><creatorcontrib>Chen, Lisong</creatorcontrib><creatorcontrib>Shi, Jianlin</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luo, Juanjuan</au><au>Wei, Xinfa</au><au>Qiao, Yang</au><au>Wu, Chenyao</au><au>Li, Lanxin</au><au>Chen, Lisong</au><au>Shi, Jianlin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H2O2 over Defective Zn3In2S6</atitle><jtitle>Advanced materials (Weinheim)</jtitle><date>2023-03-09</date><risdate>2023</risdate><volume>35</volume><issue>10</issue><epage>n/a</epage><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>One of the most sustainable and promising approaches for hydrogen peroxide (H2O2) production in a low‐cost and environment‐friendly way is photosynthesis, which, however, suffers from poor carrier utilization and low H2O2 productivity. The addition of proton donors such as isopropanol or ethanol can increase H2O2 production, which, unfortunately, will inevitably elevate the entire cost while wasting the oxidizing power of holes (h+). Herein, the tetrahydroisoquinolines (THIQs) is employed as a distinctive proton donor for the thermodynamically feasible and selective semi‐dehydrogenation reaction to highly valuable dihydroisoquinolines (DHIQs), and meanwhile, to couple with and promote H2O2 generation in one photoredox reaction under the photocatalysis by dual‐functional Zn3In2S6 photocatalyst. Surprisingly, the suitably defective Zn3In2S6 offers an excellent and near‐stoichiometric co‐production performance of H2O2 and DHIQs at unprecedentedly high rates of 66.4 and 62.1 mmol h‐1 g‐1 under visible light (λ ≥ 400 nm), respectively, which outperforms all the previously available reports even though sacrificial agents were employed in those reports. Additionally, photocatalytic redox reaction mechanism demonstrates that H2O2 can be generated through multiple pathways, highlighting the synergistic effect among ROS (·O2‐ and 1O2), h+ and proton donor, which has been ignored in previous studies.
A dual‐functional and defective Zn3In2S6 photocatalyst is developed for the simultaneous efficient photocatalytic co‐syntheses of dihydroisoquinoline and H2O2, which shows the highest rate for both reactions up to date.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adma.202210110</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0001-8790-195X</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0935-9648 |
ispartof | Advanced materials (Weinheim), 2023-03, Vol.35 (10), p.n/a |
issn | 0935-9648 1521-4095 |
language | eng |
recordid | cdi_proquest_journals_2785215048 |
source | Access via Wiley Online Library |
subjects | Dehydrogenation dual‐functional semiconductors Ethanol Hydrogen peroxide hydrogen peroxide evolution Materials science Oxidation Photocatalysis Photosynthesis Protons Reaction mechanisms reactive oxygen species Reagents Redox reactions Synergistic effect value‐added chemicals |
title | Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H2O2 over Defective Zn3In2S6 |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T04%3A22%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photoredox%E2%80%90Promoted%20Co%E2%80%90Production%20of%20Dihydroisoquinoline%20and%20H2O2%20over%20Defective%20Zn3In2S6&rft.jtitle=Advanced%20materials%20(Weinheim)&rft.au=Luo,%20Juanjuan&rft.date=2023-03-09&rft.volume=35&rft.issue=10&rft.epage=n/a&rft.issn=0935-9648&rft.eissn=1521-4095&rft_id=info:doi/10.1002/adma.202210110&rft_dat=%3Cproquest_wiley%3E2785215048%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2785215048&rft_id=info:pmid/&rfr_iscdi=true |